
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
7th Edition
ISBN: 9781305081086
Author: STOKER, H. Stephen
Publisher: Brooks Cole
expand_more
expand_more
format_list_bulleted
Question
Chapter 17, Problem 17.154EP
Interpretation Introduction
Interpretation:
Two types of monomers that are used to produce polyurethane has to be given.
Concept Introduction:
When alcohol reacts with isocyanate, urethane is obtained. Urethane is a hydrocarbon derivative. This contains a carbonyl group that is bonded to
If the monomer considered is a diisocyanate and dialcohol,
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
(racemic)
19.84 Using your reaction roadmaps as a guide, show how to convert 2-oxepanone and ethanol
into 1-cyclopentenecarbaldehyde. You must use 2-oxepanone as the source of all carbon
atoms in the target molecule. Show all reagents and all molecules synthesized along
the way.
&
+ EtOH
H
2-Oxepanone
1-Cyclopentenecarbaldehyde
R₂
R₁
R₁
a
R
Rg
Nu
R₂
Rg
R₁
R
R₁₂
R3
R
R
Nu enolate forming
R₁ R
B-Alkylated carbonyl
species or amines
Cyclic B-Ketoester
R₁₁
HOB
R
R₁B
R
R₁₂
B-Hydroxy carbonyl
R
diester
R2 R3
R₁
RB
OR
R₂ 0
aB-Unsaturated carbonyl
NaOR
Aldol
HOR
reaction
1) LDA
2) R-X
3) H₂O/H₂O
ketone,
aldehyde
1) 2°-amine
2) acid chloride
3) H₂O'/H₂O
0
O
R₁
R₁
R
R₁
R₁₂
Alkylated a-carbon
R₁
H.C
R₁
H.C
Alkylated methyl ketone
acetoacetic
ester
B-Ketoester
ester
R₁
HO
R₂ R
B-Dicarbonyl
HO
Alkylated carboxylic acid
malonic ester
Write the reagents required to bring about each reaction next to the arrows shown.
Next, record any regiochemistry or stereochemistry considerations relevant to the
reaction. You should also record any key aspects of the mechanism, such as forma-
tion of an important intermediate, as a helpful reminder. You may want to keep
track of all reactions that make carbon-carbon bonds, because these help you build
large molecules from smaller fragments. This especially applies to the reactions in…
Provide the reasonable steps to achieve the following synthesis.
Chapter 17 Solutions
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
Ch. 17.1 - Prob. 1QQCh. 17.1 - Prob. 2QQCh. 17.2 - Prob. 1QQCh. 17.2 - Prob. 2QQCh. 17.2 - Prob. 3QQCh. 17.2 - Prob. 4QQCh. 17.3 - Prob. 1QQCh. 17.3 - Prob. 2QQCh. 17.3 - Prob. 3QQCh. 17.3 - Prob. 4QQ
Ch. 17.4 - Prob. 1QQCh. 17.4 - Prob. 2QQCh. 17.5 - Prob. 1QQCh. 17.5 - Prob. 2QQCh. 17.5 - Prob. 3QQCh. 17.6 - Prob. 1QQCh. 17.6 - Prob. 2QQCh. 17.6 - Prob. 3QQCh. 17.7 - Prob. 1QQCh. 17.7 - Prob. 2QQCh. 17.7 - Prob. 3QQCh. 17.8 - Prob. 1QQCh. 17.8 - Prob. 2QQCh. 17.8 - Prob. 3QQCh. 17.8 - Prob. 4QQCh. 17.9 - Prob. 1QQCh. 17.9 - Prob. 2QQCh. 17.10 - Prob. 1QQCh. 17.10 - Prob. 2QQCh. 17.10 - Prob. 3QQCh. 17.10 - Prob. 4QQCh. 17.11 - Prob. 1QQCh. 17.11 - Prob. 2QQCh. 17.11 - Prob. 3QQCh. 17.12 - Prob. 1QQCh. 17.12 - Prob. 2QQCh. 17.12 - Prob. 3QQCh. 17.12 - Prob. 4QQCh. 17.13 - Prob. 1QQCh. 17.13 - Prob. 2QQCh. 17.13 - Prob. 3QQCh. 17.13 - Prob. 4QQCh. 17.14 - Prob. 1QQCh. 17.14 - Prob. 2QQCh. 17.14 - Prob. 3QQCh. 17.15 - Prob. 1QQCh. 17.15 - Prob. 2QQCh. 17.16 - Prob. 1QQCh. 17.16 - Prob. 2QQCh. 17.16 - Prob. 3QQCh. 17.17 - Prob. 1QQCh. 17.17 - Prob. 2QQCh. 17.17 - Prob. 3QQCh. 17.18 - Prob. 1QQCh. 17.18 - Prob. 2QQCh. 17.18 - Prob. 3QQCh. 17.19 - Prob. 1QQCh. 17.19 - Prob. 2QQCh. 17.19 - Prob. 3QQCh. 17.19 - Prob. 4QQCh. 17 - Prob. 17.1EPCh. 17 - Prob. 17.2EPCh. 17 - Prob. 17.3EPCh. 17 - Prob. 17.4EPCh. 17 - Prob. 17.5EPCh. 17 - Prob. 17.6EPCh. 17 - Indicate whether or not each of the following...Ch. 17 - Indicate whether or not each of the following...Ch. 17 - Prob. 17.9EPCh. 17 - Prob. 17.10EPCh. 17 - Prob. 17.11EPCh. 17 - Prob. 17.12EPCh. 17 - Prob. 17.13EPCh. 17 - Prob. 17.14EPCh. 17 - Prob. 17.15EPCh. 17 - Assign a common name to each of the following...Ch. 17 - Prob. 17.17EPCh. 17 - Prob. 17.18EPCh. 17 - Prob. 17.19EPCh. 17 - Prob. 17.20EPCh. 17 - Prob. 17.21EPCh. 17 - Prob. 17.22EPCh. 17 - Prob. 17.23EPCh. 17 - Prob. 17.24EPCh. 17 - Prob. 17.25EPCh. 17 - Prob. 17.26EPCh. 17 - Prob. 17.27EPCh. 17 - Prob. 17.28EPCh. 17 - Prob. 17.29EPCh. 17 - Prob. 17.30EPCh. 17 - Prob. 17.31EPCh. 17 - Prob. 17.32EPCh. 17 - Prob. 17.33EPCh. 17 - Prob. 17.34EPCh. 17 - Determine the maximum number of hydrogen bonds...Ch. 17 - Prob. 17.36EPCh. 17 - Prob. 17.37EPCh. 17 - Prob. 17.38EPCh. 17 - Prob. 17.39EPCh. 17 - Prob. 17.40EPCh. 17 - Prob. 17.41EPCh. 17 - Prob. 17.42EPCh. 17 - Prob. 17.43EPCh. 17 - Prob. 17.44EPCh. 17 - Prob. 17.45EPCh. 17 - Prob. 17.46EPCh. 17 - Prob. 17.47EPCh. 17 - Prob. 17.48EPCh. 17 - Prob. 17.49EPCh. 17 - Prob. 17.50EPCh. 17 - Prob. 17.51EPCh. 17 - Prob. 17.52EPCh. 17 - Prob. 17.53EPCh. 17 - Prob. 17.54EPCh. 17 - Prob. 17.55EPCh. 17 - Prob. 17.56EPCh. 17 - Prob. 17.57EPCh. 17 - Prob. 17.58EPCh. 17 - Prob. 17.59EPCh. 17 - Prob. 17.60EPCh. 17 - Prob. 17.61EPCh. 17 - Prob. 17.62EPCh. 17 - Prob. 17.63EPCh. 17 - Prob. 17.64EPCh. 17 - Prob. 17.65EPCh. 17 - Prob. 17.66EPCh. 17 - Prob. 17.67EPCh. 17 - Prob. 17.68EPCh. 17 - Prob. 17.69EPCh. 17 - Prob. 17.70EPCh. 17 - Prob. 17.71EPCh. 17 - Prob. 17.72EPCh. 17 - Prob. 17.73EPCh. 17 - Prob. 17.74EPCh. 17 - Prob. 17.75EPCh. 17 - Prob. 17.76EPCh. 17 - Prob. 17.77EPCh. 17 - Prob. 17.78EPCh. 17 - Prob. 17.79EPCh. 17 - Prob. 17.80EPCh. 17 - Prob. 17.81EPCh. 17 - Prob. 17.82EPCh. 17 - Prob. 17.83EPCh. 17 - Prob. 17.84EPCh. 17 - Prob. 17.85EPCh. 17 - Prob. 17.86EPCh. 17 - Prob. 17.87EPCh. 17 - Prob. 17.88EPCh. 17 - Prob. 17.89EPCh. 17 - Prob. 17.90EPCh. 17 - Prob. 17.91EPCh. 17 - Prob. 17.92EPCh. 17 - Prob. 17.93EPCh. 17 - Prob. 17.94EPCh. 17 - Prob. 17.95EPCh. 17 - Prob. 17.96EPCh. 17 - Prob. 17.97EPCh. 17 - Prob. 17.98EPCh. 17 - Indicate whether or not each of the following...Ch. 17 - Indicate whether or not each of the following...Ch. 17 - Classify each of the following amides as...Ch. 17 - Classify each of the following amides as...Ch. 17 - Classify each of the amides in Problem 17-101 as a...Ch. 17 - Prob. 17.104EPCh. 17 - Prob. 17.105EPCh. 17 - Prob. 17.106EPCh. 17 - Prob. 17.107EPCh. 17 - Prob. 17.108EPCh. 17 - Prob. 17.109EPCh. 17 - Prob. 17.110EPCh. 17 - Assign an IUPAC name to each of the following...Ch. 17 - Assign an IUPAC name to each of the following...Ch. 17 - Prob. 17.113EPCh. 17 - Prob. 17.114EPCh. 17 - Prob. 17.115EPCh. 17 - Prob. 17.116EPCh. 17 - Prob. 17.117EPCh. 17 - Prob. 17.118EPCh. 17 - Prob. 17.119EPCh. 17 - What is the relationship between the acronym DEET...Ch. 17 - Prob. 17.121EPCh. 17 - Prob. 17.122EPCh. 17 - Prob. 17.123EPCh. 17 - Prob. 17.124EPCh. 17 - Prob. 17.125EPCh. 17 - Prob. 17.126EPCh. 17 - Prob. 17.127EPCh. 17 - Prob. 17.128EPCh. 17 - Prob. 17.129EPCh. 17 - Prob. 17.130EPCh. 17 - Prob. 17.131EPCh. 17 - Prob. 17.132EPCh. 17 - Prob. 17.133EPCh. 17 - Prob. 17.134EPCh. 17 - Prob. 17.135EPCh. 17 - Prob. 17.136EPCh. 17 - Prob. 17.137EPCh. 17 - Prob. 17.138EPCh. 17 - Prob. 17.139EPCh. 17 - Prob. 17.140EPCh. 17 - Prob. 17.141EPCh. 17 - Prob. 17.142EPCh. 17 - Prob. 17.143EPCh. 17 - Prob. 17.144EPCh. 17 - Prob. 17.145EPCh. 17 - Prob. 17.146EPCh. 17 - Prob. 17.147EPCh. 17 - Prob. 17.148EPCh. 17 - Prob. 17.149EPCh. 17 - Prob. 17.150EPCh. 17 - Prob. 17.151EPCh. 17 - Prob. 17.152EPCh. 17 - Prob. 17.153EPCh. 17 - Prob. 17.154EP
Knowledge Booster
Similar questions
- (a) Draw the structures of A and B in the following reaction. (i) NaNH2, NH3(1) A + B (ii) H3O+arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forwardConsider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forward
- In a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forwardGiven the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning

General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning

Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,

World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning

Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning

Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning