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Concept explainers
(a)
Interpretation:
The structure of carbonyl-containing compound that is obtained when the given amide undergoes basic hydrolysis has to be drawn.
Concept Introduction:
Amides are derivatives of
Acidic hydrolysis of amides gives the product as carboxylic acid and
Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.
(b)
Interpretation:
The structure of carbonyl-containing compound that is obtained when the given amide undergoes basic hydrolysis has to be drawn.
Concept Introduction:
Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.
Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.
Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.
(c)
Interpretation:
The structure of carbonyl-containing compound that is obtained when the given amide undergoes basic hydrolysis has to be drawn.
Concept Introduction:
Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.
Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.
Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.
(d)
Interpretation:
The structure of carbonyl-containing compound that is obtained when the given amide undergoes basic hydrolysis has to be drawn.
Concept Introduction:
Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.
Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.
Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.
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Chapter 17 Solutions
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
- Draw the mechanism of aspirin synthesis in an basic medium and in a neutral medium, showing the attacks and the process for the formation of the product.arrow_forwardNa :S f. F NO2arrow_forwardQ1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. + CI OH woཡི།༠w Br H مه D CI ပ။ Br H, Br Br H₂N OMe R IN Ill N S H CI Br CI CI D OH H 1/111arrow_forward
- Question 7 (10 points) Identify the carboxylic acid present in each of the following items and draw their structures: Food Vinegar Oranges Yogurt Sour Milk Pickles Acid Structure Paragraph ✓ BI UAE 0118 + v Task: 1. Identify the carboxylic acid 2. Provide Name 3. Draw structure 4. Take a picture of your table and insert Add a File Record Audio Record Video 11.arrow_forwardCheck the box under each structure in the table that is an enantiomer of the molecule shown below. If none of them are, check the none of the above box under the table. Molecule 1 Molecule 2 IZ IN Molecule 4 Molecule 5 ZI none of the above ☐ Molecule 3 Х IN www Molecule 6 NH Garrow_forwardHighlight each chiral center in the following molecule. If there are none, then check the box under the drawing area. There are no chiral centers. Cl Cl Highlightarrow_forward
- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
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