General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Chapter 17, Problem 17.136EP

(a)

Interpretation Introduction

Interpretation:

Structure of nitrogen-containing compound that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(a)

Expert Solution
Check Mark

Answer to Problem 17.136EP

Nitrogen-containing compound that is required was,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  1

Explanation of Solution

Given structure of compound is,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  2

As the nitrogen atom present in the above amide has two hydrogen atoms bonded to it, the amide is a primary amide.  Primary amide is produced by the reaction of ammonia with carboxylic acid.  The nitrogen-containing compound can be identified as shown below,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  3

Hydrogen atom has to be added to the amine part and OH group has to be added to the acid part in order to obtain the parent molecules.  From this the nitrogen-containing compound that is required to produce the given amide is,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  4

Conclusion

Structure of nitrogen-containing compound that is required to produce the given compound is drawn.

(b)

Interpretation Introduction

Interpretation:

Structure of nitrogen-containing compound that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(b)

Expert Solution
Check Mark

Answer to Problem 17.136EP

Nitrogen-containing compound that is required was,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  5

Explanation of Solution

Given structure of compound is,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  6

As the nitrogen atom present in the above amide has two hydrogen atoms bonded to it, the amide is a primary amide.  Primary amide is produced by the reaction of ammonia with carboxylic acid.  The nitrogen-containing compound can be identified as shown below,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  7

Hydrogen atom has to be added to the amine part and OH group has to be added to the acid part in order to obtain the parent molecules.  From this the nitrogen-containing compound that is required to produce the given amide is,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  8

Conclusion

Structure of nitrogen-containing compound that is required to produce the given compound is drawn.

(c)

Interpretation Introduction

Interpretation:

Structure of nitrogen-containing compound that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(c)

Expert Solution
Check Mark

Answer to Problem 17.136EP

Nitrogen-containing compound that is required was,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  9

Explanation of Solution

Given structure of compound is,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  10

As the nitrogen atom present in the above amide has two hydrogen atoms bonded to it, the amide is a primary amide.  Primary amide is produced by the reaction of ammonia with carboxylic acid.  The nitrogen-containing compound can be identified as shown below,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  11

Hydrogen atom has to be added to the amine part and OH group has to be added to the acid part in order to obtain the parent molecules.  From this the nitrogen-containing compound that is required to produce the given amide is,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  12

Conclusion

Structure of nitrogen-containing compound that is required to produce the given compound is drawn.

(d)

Interpretation Introduction

Interpretation:

Structure of nitrogen-containing compound that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(d)

Expert Solution
Check Mark

Answer to Problem 17.136EP

Nitrogen-containing compound that is required was,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  13

Explanation of Solution

Given structure of compound is,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  14

As the nitrogen atom present in the above amide has two hydrogen atoms bonded to it, the amide is a primary amide.  Primary amide is produced by the reaction of ammonia with carboxylic acid.  The nitrogen-containing compound can be identified as shown below,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  15

Hydrogen atom has to be added to the amine part and OH group has to be added to the acid part in order to obtain the parent molecules.  From this the nitrogen-containing compound that is required to produce the given amide is,

General, Organic, and Biological Chemistry, Chapter 17, Problem 17.136EP , additional homework tip  16

Conclusion

Structure of nitrogen-containing compound that is required to produce the given compound is drawn.

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Chapter 17 Solutions

General, Organic, and Biological Chemistry

Ch. 17.4 - Prob. 1QQCh. 17.4 - Prob. 2QQCh. 17.5 - Prob. 1QQCh. 17.5 - Prob. 2QQCh. 17.5 - Prob. 3QQCh. 17.6 - Prob. 1QQCh. 17.6 - Prob. 2QQCh. 17.6 - Prob. 3QQCh. 17.7 - Prob. 1QQCh. 17.7 - Prob. 2QQCh. 17.7 - Prob. 3QQCh. 17.8 - Prob. 1QQCh. 17.8 - Prob. 2QQCh. 17.8 - Prob. 3QQCh. 17.8 - Prob. 4QQCh. 17.9 - Prob. 1QQCh. 17.9 - Prob. 2QQCh. 17.10 - Prob. 1QQCh. 17.10 - Prob. 2QQCh. 17.10 - Prob. 3QQCh. 17.10 - Prob. 4QQCh. 17.11 - Prob. 1QQCh. 17.11 - Prob. 2QQCh. 17.11 - Prob. 3QQCh. 17.12 - Prob. 1QQCh. 17.12 - Prob. 2QQCh. 17.12 - Prob. 3QQCh. 17.12 - Prob. 4QQCh. 17.13 - Prob. 1QQCh. 17.13 - Prob. 2QQCh. 17.13 - Prob. 3QQCh. 17.13 - Prob. 4QQCh. 17.14 - Prob. 1QQCh. 17.14 - Prob. 2QQCh. 17.14 - Prob. 3QQCh. 17.15 - Prob. 1QQCh. 17.15 - Prob. 2QQCh. 17.16 - Prob. 1QQCh. 17.16 - Prob. 2QQCh. 17.16 - Prob. 3QQCh. 17.17 - Prob. 1QQCh. 17.17 - Prob. 2QQCh. 17.17 - Prob. 3QQCh. 17.18 - Prob. 1QQCh. 17.18 - Prob. 2QQCh. 17.18 - Prob. 3QQCh. 17.19 - Prob. 1QQCh. 17.19 - Prob. 2QQCh. 17.19 - Prob. 3QQCh. 17.19 - Prob. 4QQCh. 17 - Prob. 17.1EPCh. 17 - Prob. 17.2EPCh. 17 - Prob. 17.3EPCh. 17 - Prob. 17.4EPCh. 17 - Prob. 17.5EPCh. 17 - Prob. 17.6EPCh. 17 - Indicate whether or not each of the following...Ch. 17 - Indicate whether or not each of the following...Ch. 17 - Prob. 17.9EPCh. 17 - Prob. 17.10EPCh. 17 - Prob. 17.11EPCh. 17 - Prob. 17.12EPCh. 17 - Prob. 17.13EPCh. 17 - Prob. 17.14EPCh. 17 - Prob. 17.15EPCh. 17 - Assign a common name to each of the following...Ch. 17 - Prob. 17.17EPCh. 17 - Prob. 17.18EPCh. 17 - Prob. 17.19EPCh. 17 - Prob. 17.20EPCh. 17 - Prob. 17.21EPCh. 17 - Prob. 17.22EPCh. 17 - Prob. 17.23EPCh. 17 - Prob. 17.24EPCh. 17 - Prob. 17.25EPCh. 17 - Prob. 17.26EPCh. 17 - Prob. 17.27EPCh. 17 - Prob. 17.28EPCh. 17 - Prob. 17.29EPCh. 17 - Prob. 17.30EPCh. 17 - Prob. 17.31EPCh. 17 - Prob. 17.32EPCh. 17 - Prob. 17.33EPCh. 17 - Prob. 17.34EPCh. 17 - Determine the maximum number of hydrogen bonds...Ch. 17 - Prob. 17.36EPCh. 17 - Prob. 17.37EPCh. 17 - Prob. 17.38EPCh. 17 - Prob. 17.39EPCh. 17 - Prob. 17.40EPCh. 17 - Prob. 17.41EPCh. 17 - Prob. 17.42EPCh. 17 - Prob. 17.43EPCh. 17 - Prob. 17.44EPCh. 17 - Prob. 17.45EPCh. 17 - Prob. 17.46EPCh. 17 - Prob. 17.47EPCh. 17 - Prob. 17.48EPCh. 17 - Prob. 17.49EPCh. 17 - Prob. 17.50EPCh. 17 - Prob. 17.51EPCh. 17 - Prob. 17.52EPCh. 17 - Prob. 17.53EPCh. 17 - Prob. 17.54EPCh. 17 - Prob. 17.55EPCh. 17 - Prob. 17.56EPCh. 17 - Prob. 17.57EPCh. 17 - Prob. 17.58EPCh. 17 - Prob. 17.59EPCh. 17 - Prob. 17.60EPCh. 17 - Prob. 17.61EPCh. 17 - Prob. 17.62EPCh. 17 - Prob. 17.63EPCh. 17 - Prob. 17.64EPCh. 17 - Prob. 17.65EPCh. 17 - Prob. 17.66EPCh. 17 - Prob. 17.67EPCh. 17 - Prob. 17.68EPCh. 17 - Prob. 17.69EPCh. 17 - Prob. 17.70EPCh. 17 - Prob. 17.71EPCh. 17 - Prob. 17.72EPCh. 17 - Prob. 17.73EPCh. 17 - Prob. 17.74EPCh. 17 - Prob. 17.75EPCh. 17 - Prob. 17.76EPCh. 17 - Prob. 17.77EPCh. 17 - Prob. 17.78EPCh. 17 - Prob. 17.79EPCh. 17 - Prob. 17.80EPCh. 17 - Prob. 17.81EPCh. 17 - Prob. 17.82EPCh. 17 - Prob. 17.83EPCh. 17 - Prob. 17.84EPCh. 17 - Prob. 17.85EPCh. 17 - Prob. 17.86EPCh. 17 - Prob. 17.87EPCh. 17 - Prob. 17.88EPCh. 17 - Prob. 17.89EPCh. 17 - Prob. 17.90EPCh. 17 - Prob. 17.91EPCh. 17 - Prob. 17.92EPCh. 17 - Prob. 17.93EPCh. 17 - Prob. 17.94EPCh. 17 - Prob. 17.95EPCh. 17 - Prob. 17.96EPCh. 17 - Prob. 17.97EPCh. 17 - Prob. 17.98EPCh. 17 - Indicate whether or not each of the following...Ch. 17 - Indicate whether or not each of the following...Ch. 17 - Classify each of the following amides as...Ch. 17 - Classify each of the following amides as...Ch. 17 - Classify each of the amides in Problem 17-101 as a...Ch. 17 - Prob. 17.104EPCh. 17 - Prob. 17.105EPCh. 17 - Prob. 17.106EPCh. 17 - Prob. 17.107EPCh. 17 - Prob. 17.108EPCh. 17 - Prob. 17.109EPCh. 17 - Prob. 17.110EPCh. 17 - Assign an IUPAC name to each of the following...Ch. 17 - Assign an IUPAC name to each of the following...Ch. 17 - Prob. 17.113EPCh. 17 - Prob. 17.114EPCh. 17 - Prob. 17.115EPCh. 17 - Prob. 17.116EPCh. 17 - Prob. 17.117EPCh. 17 - Prob. 17.118EPCh. 17 - Prob. 17.119EPCh. 17 - What is the relationship between the acronym DEET...Ch. 17 - Prob. 17.121EPCh. 17 - Prob. 17.122EPCh. 17 - Prob. 17.123EPCh. 17 - Prob. 17.124EPCh. 17 - Prob. 17.125EPCh. 17 - Prob. 17.126EPCh. 17 - Prob. 17.127EPCh. 17 - Prob. 17.128EPCh. 17 - Prob. 17.129EPCh. 17 - Prob. 17.130EPCh. 17 - Prob. 17.131EPCh. 17 - Prob. 17.132EPCh. 17 - Prob. 17.133EPCh. 17 - Prob. 17.134EPCh. 17 - Prob. 17.135EPCh. 17 - Prob. 17.136EPCh. 17 - Prob. 17.137EPCh. 17 - Prob. 17.138EPCh. 17 - Prob. 17.139EPCh. 17 - Prob. 17.140EPCh. 17 - Prob. 17.141EPCh. 17 - Prob. 17.142EPCh. 17 - Prob. 17.143EPCh. 17 - Prob. 17.144EPCh. 17 - Prob. 17.145EPCh. 17 - Prob. 17.146EPCh. 17 - Prob. 17.147EPCh. 17 - Prob. 17.148EPCh. 17 - Prob. 17.149EPCh. 17 - Prob. 17.150EPCh. 17 - Prob. 17.151EPCh. 17 - Prob. 17.152EPCh. 17 - Prob. 17.153EPCh. 17 - Prob. 17.154EP
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