In aqueous solution, methylethylamine exhibit basic behavior or not has to be indicated. Concept Introduction: Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions. Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 1

Question

Chapter 17, Problem 17.124EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, methylethylamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, butanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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The standard Gibbs energies of formation of CaO(s), CaCO3 (calcite), and CO2 (g) are -604.04, -1128.80, and -394.37 kJ/mol, respectively. Find the value of AG, and Keq for the following reaction: CaCO3 CaO (s) + CO2 (g) [ap A dry mixture containing 1 g of each solid [CaCO3(s) and CaO(s)] is on the lab bench in contact with the atmosphere, which contains a partial pressure of 10-35 bar CO2 (g). What is the total Gibbs free energy of the system containing all three species before any reaction has happened? Does the equilibrium driving force favor conversion of one of the solids into the other, or are the solids equilibrated with one another?

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Answer 2

Question

Chapter 17, Problem 17.124EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, methylethylamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, butanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 3

Question

Chapter 17, Problem 17.124EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, methylethylamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, butanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 4

Question

Chapter 17, Problem 17.124EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, methylethylamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, butanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 5

Chapter 17, Problem 17.124EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, methylethylamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, butanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 6

Chapter 17, Problem 17.124EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, methylethylamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 7

Chapter 17, Problem 17.124EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, methylethylamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 8

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, butanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 9

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, butanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 10

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 11

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 12

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 13

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 17.1 - Prob. 1QQ Ch. 17.1 - Prob. 2QQ Ch. 17.2 - Prob. 1QQ Ch. 17.2 - Prob. 2QQ Ch. 17.2 - Prob. 3QQ Ch. 17.2 - Prob. 4QQ Ch. 17.3 - Prob. 1QQ Ch. 17.3 - Prob. 2QQ Ch. 17.3 - Prob. 3QQ Ch. 17.3 - Prob. 4QQ

Solution Summary: The author explains that methylethylamine exhibits basic behavior or not in aqueous solutions.

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Chapter 17 Solutions