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Concept explainers
(a)
Interpretation:
IUPAC name of the given compound has to be assigned.
Concept Introduction:
Amides are derivatives of
IUPAC rules for naming an amide:
- The end in name of the carboxylic acid is changed from “-ic acid” or “-oic acid” to “-amide”.
- The groups attached to the nitrogen are appended to front of base name by using N-prefix as locator.
For amides, IUPAC name and common names are given using the same rules.
(b)
Interpretation:
IUPAC name of the given compound has to be assigned.
Concept Introduction:
Amides are derivatives of carboxylic acid. This is the reason that their names are completely based on the parent carboxylic acid.
IUPAC rules for naming an amide:
- The end in name of the carboxylic acid is changed from “-ic acid” or “-oic acid” to “-amide”.
- The groups attached to the nitrogen are appended to front of base name by using N-prefix as locator.
For amides, IUPAC name and common names are given using the same rules.
(c)
Interpretation:
IUPAC name of the given compound has to be assigned.
Concept Introduction:
Amides are derivatives of carboxylic acid. This is the reason that their names are completely based on the parent carboxylic acid.
IUPAC rules for naming an amide:
- The end in name of the carboxylic acid is changed from “-ic acid” or “-oic acid” to “-amide”.
- The groups attached to the nitrogen are appended to front of base name by using N-prefix as locator.
For amides, IUPAC name and common names are given using the same rules.
(d)
Interpretation:
IUPAC name of the given compound has to be assigned.
Concept Introduction:
Amides are derivatives of carboxylic acid. This is the reason that their names are completely based on the parent carboxylic acid.
IUPAC rules for naming an amide:
- The end in name of the carboxylic acid is changed from “-ic acid” or “-oic acid” to “-amide”.
- The groups attached to the nitrogen are appended to front of base name by using N-prefix as locator.
For amides, IUPAC name and common names are given using the same rules.
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Chapter 17 Solutions
General, Organic, and Biological Chemistry
- Nonearrow_forwardQ1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? H Br H Br (S) CH3 (R) CH3 H3C (S) H3C H Br Br H A C enantiomers H Br H Br (R) CH3 H3C (R) (S) CH3 H3C H Br Br H B D identicalarrow_forward2. Histamine (below structure) is a signal molecule involved in immune response and is a neurotransmitter. Histamine features imidazole ring which is an aromatic heterocycle. Please answer the following questions regarding Histamine. b a HN =N C NH2 a. Determine hybridization of each N atom (s, p, sp, sp², sp³, etc.) in histamine N-a hybridization: N-b hybridization: N-c hybridization: b. Determine what atomic orbitals (s, p, sp, sp², sp³, etc.) of the lone pair of each N atom resided in N-a hybridization: N-b hybridization: N-c hybridization:arrow_forward
- Nonearrow_forward29. Use frontier orbital analysis (HOMO-LUMO interactions) to decide whether the following dimerization is 1) thermally allowed or forbidden and 2) photochemically allowed or forbidden. +arrow_forward30.0 mL of 0.10 mol/L iron sulfate and 20.0 mL of 0.05 mol/L of silver nitrate solutions are mixed together. Justify if any precipitate would formarrow_forward
- Does the carbonyl group first react with the ethylene glycol, in an intermolecular reaction, or with the end alcohol, in an intramolecular reaction, to form a hemiacetal? Why does it react with the alcohol it does first rather than the other one? Please do not use an AI answer.arrow_forwardThe number of noncyclic isomers that have the composition C4H8Owith the O as part of an OH group, counting a pair of stereoisomers as1, is A. 8; B. 6; C. 9; D. 5; E. None of the other answers is correct.arrow_forwardNonearrow_forward
- The number of carbon skeletons that have 8 carbons, one of which istertiary is A. 7; B. More than 7; C. 6; D. 5; E. 4arrow_forwardThe azide ion is N3^-. In addition to the ionic charge, it’s three mostimportant contributing structures also have formal charges. The totalnumber of π bonds in these three contributing structures isA. 6; B. 12; C. 3; D. 9; E. None of the other answers is correct.arrow_forwardThe sum of the numerals in the name of the compoundis A. None of the other answers is correct.; B. 11;C. 6; D. 8; E. 5.arrow_forward
- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
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