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(a)
Interpretation:
Structural formula of the organic product formed when butanal undergoes Tollen’s test has to be drawn.
Concept Introduction:
In
In organic chemistry, reduction reaction is referred to the number
Alcohols undergo
Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.
Tollen’s test:
This is also known as silver mirror test. The reagent that is used in Tollen’s test is silver nitrate and ammonia in water. Aldehyde reacts with Tollen’s reagent, where the silver ion is reduced to silver metal and the aldehyde is oxidized to carboxylic acid.
Ketone does not undergo Tollen’s test to deposit silver metal.
Benedict’s test:
This test is also similar to Tollen’s test. In this test,
(a)
![Check Mark](/static/check-mark.png)
Answer to Problem 15.77EP
The structure of organic product obtained is,
Explanation of Solution
Aldehydes undergo Tollen’s test. The product formed when aldehyde undergo oxidation is a carboxylic acid. The general oxidation reaction for aldehyde can be given as,
Given aldehyde is butanal and the structure can be given as shown below,
This on reaction with Tollen’s reagent gives carboxylic acid as the product. The structure of the organic product formed and the complete reaction can be given as shown below,
1-butanoic acid is formed from butanal when it undergoes Tollen’s test.
The structure of the organic product formed is drawn.
(b)
Interpretation:
Structural formula of the organic product formed when 2-butanone undergoes Tollen’s test has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.
Tollen’s test:
This is also known as silver mirror test. The reagent that is used in Tollen’s test is silver nitrate and ammonia in water. Aldehyde reacts with Tollen’s reagent, where the silver ion is reduced to silver metal and the aldehyde is oxidized to carboxylic acid.
Ketone does not undergo Tollen’s test to deposit silver metal.
Benedict’s test:
This test is also similar to Tollen’s test. In this test,
(b)
![Check Mark](/static/check-mark.png)
Answer to Problem 15.77EP
2-butanone does not undergo Tollen’s test.
Explanation of Solution
Aldehydes undergo Tollen’s test. The product formed when aldehyde undergo oxidation is a carboxylic acid. The general oxidation reaction for aldehyde can be given as,
Given compound is a ketone that is 2-butanone and the structure can be given as shown below,
This on reaction with Tollen’s reagent does not give oxidized product. Therefore, no reaction takes place when 2-butanone reacts with Tollen’s reagent.
2-butanone does not react with Tollen’s reagent.
No reaction takes place when 2-butanone undergoes Tollen’s test.
(c)
Interpretation:
Structural formula of the organic product formed when 3-methylpentanal undergoes Benedict’s test has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.
Tollen’s test:
This is also known as silver mirror test. The reagent that is used in Tollen’s test is silver nitrate and ammonia in water. Aldehyde reacts with Tollen’s reagent, where the silver ion is reduced to silver metal and the aldehyde is oxidized to carboxylic acid.
Ketone does not undergo Tollen’s test to deposit silver metal.
Benedict’s test:
This test is also similar to Tollen’s test. In this test,
(c)
![Check Mark](/static/check-mark.png)
Answer to Problem 15.77EP
The structure of organic product obtained is,
Explanation of Solution
Aldehydes undergo Benedicts’s test. The product formed when aldehyde undergo oxidation is a carboxylic acid. The general oxidation reaction for aldehyde can be given as,
Given aldehyde is 3-methylpentanal and the structure can be given as shown below,
This on reaction with Tollen’s reagent gives carboxylic acid as the product. The structure of the organic product formed and the complete reaction can be given as shown below,
3-methyl-1-pentanoic acid is formed from 3-methylpentanal when it undergoes Benedict’s test.
The structure of the organic product formed is drawn.
(d)
Interpretation:
Structural formula of the organic product formed when 3-pentanone undergoes Benedict’s test has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.
Tollen’s test:
This is also known as silver mirror test. The reagent that is used in Tollen’s test is silver nitrate and ammonia in water. Aldehyde reacts with Tollen’s reagent, where the silver ion is reduced to silver metal and the aldehyde is oxidized to carboxylic acid.
Ketone does not undergo Tollen’s test to deposit silver metal.
Benedict’s test:
This test is also similar to Tollen’s test. In this test,
(d)
![Check Mark](/static/check-mark.png)
Answer to Problem 15.77EP
3-pentanone does not undergo Benedict’s test.
Explanation of Solution
Aldehydes undergo Benedict’s test. The product formed when aldehyde undergo oxidation is a carboxylic acid. The general oxidation reaction for aldehyde can be given as,
Given compound is a ketone. The name of ketone is 3-pentanone and the structure can be given as shown below,
This on reaction with Benedict’s reagent does not give oxidized product. Therefore, no reaction takes place when 3-pentanone undergoes Benedict’s test.
3-pentanone does not undergo Benedict’s test.
No reaction takes place when 3-pentanone undergoes Benedict’s test.
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Chapter 15 Solutions
GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
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