(a)
Interpretation:
Aldehyde must contain an oxygen‑hydrogen single bond or not has to be indicated.
Concept Introduction:
Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.
The groups that is attached to the carbonyl carbon atom can be either hydrogen or carbon atom. If the attached atoms are hydrogen and a carbon atom means then the compound is an aldehyde and if they are two carbon atoms means then the compound is a ketone. If the attached atom is a nitrogen atom to the carbonyl carbon atom means it is a amide. If a hydroxyl group is attached to a carbonyl carbon atom, then it is a
(b)
Interpretation:
Ketone must contain an oxygen‑hydrogen single bond or not has to be indicated.
Concept Introduction:
Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,
The groups that is attached to the carbonyl carbon atom can be either hydrogen or carbon atom. If the attached atoms are hydrogen and a carbon atom means then the compound is an aldehyde and if they are two carbon atoms means then the compound is a ketone. If the attached atom is a nitrogen atom to the carbonyl carbon atom means it is a amide. If a hydroxyl group is attached to a carbonyl carbon atom, then it is a carboxylic acid. If one of the bond in the carbonyl carbon atom is attached to an oxygen atom that is bonded with alkyl, cycloalkyl or aromatic system is known as ester.
(c)
Interpretation:
Ester must contain an oxygen‑hydrogen single bond or not has to be indicated.
Concept Introduction:
Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,
The groups that is attached to the carbonyl carbon atom can be either hydrogen or carbon atom. If the attached atoms are hydrogen and a carbon atom means then the compound is an aldehyde and if they are two carbon atoms means then the compound is a ketone. If the attached atom is a nitrogen atom to the carbonyl carbon atom means it is a amide. If a hydroxyl group is attached to a carbonyl carbon atom, then it is a carboxylic acid. If one of the bond in the carbonyl carbon atom is attached to an oxygen atom that is bonded with alkyl, cycloalkyl or aromatic system is known as ester.
(d)
Interpretation:
Carboxylic acid must contain an oxygen‑hydrogen single bond or not has to be indicated.
Concept Introduction:
Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,
The groups that is attached to the carbonyl carbon atom can be either hydrogen or carbon atom. If the attached atoms are hydrogen and a carbon atom means then the compound is an aldehyde and if they are two carbon atoms means then the compound is a ketone. If the attached atom is a nitrogen atom to the carbonyl carbon atom means it is a amide. If a hydroxyl group is attached to a carbonyl carbon atom, then it is a carboxylic acid. If one of the bonds in the carbonyl carbon atom is attached to an oxygen atom that is bonded with alkyl, cycloalkyl or aromatic system is known as ester.
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Chapter 15 Solutions
GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
- Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction LiNO3arrow_forwardAn unknown weak acid with a concentration of 0.410 M has a pH of 5.600. What is the Ka of the weak acid?arrow_forward(racemic) 19.84 Using your reaction roadmaps as a guide, show how to convert 2-oxepanone and ethanol into 1-cyclopentenecarbaldehyde. You must use 2-oxepanone as the source of all carbon atoms in the target molecule. Show all reagents and all molecules synthesized along the way. & + EtOH H 2-Oxepanone 1-Cyclopentenecarbaldehydearrow_forward
- R₂ R₁ R₁ a R Rg Nu R₂ Rg R₁ R R₁₂ R3 R R Nu enolate forming R₁ R B-Alkylated carbonyl species or amines Cyclic B-Ketoester R₁₁ HOB R R₁B R R₁₂ B-Hydroxy carbonyl R diester R2 R3 R₁ RB OR R₂ 0 aB-Unsaturated carbonyl NaOR Aldol HOR reaction 1) LDA 2) R-X 3) H₂O/H₂O ketone, aldehyde 1) 2°-amine 2) acid chloride 3) H₂O'/H₂O 0 O R₁ R₁ R R₁ R₁₂ Alkylated a-carbon R₁ H.C R₁ H.C Alkylated methyl ketone acetoacetic ester B-Ketoester ester R₁ HO R₂ R B-Dicarbonyl HO Alkylated carboxylic acid malonic ester Write the reagents required to bring about each reaction next to the arrows shown. Next, record any regiochemistry or stereochemistry considerations relevant to the reaction. You should also record any key aspects of the mechanism, such as forma- tion of an important intermediate, as a helpful reminder. You may want to keep track of all reactions that make carbon-carbon bonds, because these help you build large molecules from smaller fragments. This especially applies to the reactions in…arrow_forwardProvide the reasonable steps to achieve the following synthesis.arrow_forwardIdentify which compound is more acidic. Justify your choice.arrow_forward
- Provide the reasonable steps to achieve the following synthesis.arrow_forwardWhen anisole is treated with excess bromine, the reaction gives a product which shows two singlets in 1H NMR. Draw the product.arrow_forward(ii) Draw a reasonable mechanism for the following reaction: CI NaOH heat OH (hint: SNAr Reaction) :arrow_forward
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