Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 12, Problem 7PP

Practice Problem 12.7

Provide retrosynthetic analyses and syntheses for each of the following alcohols, starting with appropriate alkyl or aryl halides.

(a)

Chapter 12, Problem 7PP, Practice Problem 12.7
Provide retrosynthetic analyses and syntheses for each of the following , example  1

(b)

Chapter 12, Problem 7PP, Practice Problem 12.7
Provide retrosynthetic analyses and syntheses for each of the following , example  2

(c)

Chapter 12, Problem 7PP, Practice Problem 12.7
Provide retrosynthetic analyses and syntheses for each of the following , example  3

(d)

Chapter 12, Problem 7PP, Practice Problem 12.7
Provide retrosynthetic analyses and syntheses for each of the following , example  4

(e)

Chapter 12, Problem 7PP, Practice Problem 12.7
Provide retrosynthetic analyses and syntheses for each of the following , example  5

(f)

Chapter 12, Problem 7PP, Practice Problem 12.7
Provide retrosynthetic analyses and syntheses for each of the following , example  6

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(c) Answer each of the questions below that relate to acetophenone: Xo (i) (ii) (iii) Draw the structure of the enol form of acetophenone. Give a stepwise mechanism for the conversion of acetophenone into its enol form. Show how each of the three compounds A, B and C below can be prepared from acetophenone. Explain clearly what reactants/reagents would be required in each case. odocor A B Br C
Practice Problem 13.36b Problem 13.34 outlines a general method for the preparation of cis- or trans-disubstituted epoxides. Using that method, identify what reagents you would use to prepare the following epoxide from acetylene: H" 'Et The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A B C D DMP or PCC На, Pt EtBr PHCH2BR E F H H2SO4, H20, HgSO4 МСРВА (RCO3зН) Na, NH3 (/) H2, Lindlar's cat. I K TSCI, py PhBr NANH2 1) EtMgBr; 2) H30+
Propose suitable reagents to accomplish the following transformations.

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