Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 12, Problem 22P
Interpretation Introduction

Interpretation:

The difference between the reactivities of the given oxygen heterocycles is to be explained.

Concept introduction:

The Grignard reagent is produced when magnesium reacts with alkenyl halides or alkyl halides. They are good nucleophiles. The Grignard reaction is an organometallic chemical reaction. The formation of Grignard reagent is as follows:

Organic Chemistry, Chapter 12, Problem 22P

Tetrahydrofuran is a heterocyclic compound which is a five-membered ring. It is a polar solvent.

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An organic compound A of unknown structure was found to have a molecular formula C8H16. When A was poured in water and heated, compound B having a molecular formula C8H18O was formed. B upon heating with sulfuric acid was converted to C as the major product which is identical to A. Ozonolysis of C gave one molecule each of two different products D and E, both having a molecular formula C4H8O. Write the reactions involved and determine the structure of A,B,C,D and E.
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