Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 12, Problem 31P
Interpretation Introduction

Interpretation:

A retrosynthetic analysis and a synthetic reaction that could be used to prepare Meparfynol from four carbon atoms are to be written.

Concept introduction:

Retrosynthetic analysis is a method of solving problems related to the preparation of organic synthesis. This is also called the disconnection approach.

In this, a target molecule is transferred into simple precursor structures without assuming the starting materials.

A reaction in which multiple reactants combine to form a single product is called a synthetic reaction.

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b) The Wolf-Kishner reduction is a reaction used in Organic Chemistry to convert carbonyl functionalities into methylene group. The reaction was used to convert an aldehyde or ketone to an alkane using hydrazine, base and thermal conditions. The mechanism begins with the attack of hydrazine of the aldehyde or ketone. Stage 1: The reaction of aldehyde/ketone with hydrazine to produce hydrazine Stage 2: Reaction with the base and heat to convert hydrozone to alkane Write the mechanism of the reaction.
4) Write the reaction between cyclohexanecarboxylic acid and thionyl chloride showing all three products (two gaseous and one liquid). Take the liquid product and treat it with 2 moles of dimethylamine in benzene as the solvent. You get two products. What are they? Draw their formulae and write their names.
Suggest possible synthetic route for following transformations. Show the reagents, intermediates and products.

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