Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 1, Problem 1.66E
Interpretation Introduction

Interpretation:

Density is defined as molar mass, M, divided by molar volume:

d=MV¯

(δdδT)p,n for an ideal gas in terms of is to be evaluated.

Concept introduction:

Gaseous systems are used to study M, V¯ and p the thermodynamic properties since; the gaseous systems are well behaved. Intriguingly, the change in the state variables, when a certain state variable is changed can be determined. Thus, the gaseous systems are important in analyzing thermodynamic properties. In this regard, a few partial derivatives can be considered as basic properties of the gas. The two important partial derivatives of having significant interest are; 1) expansion coefficient of a gas (α) 2) isothermal compressibility (κ) of a gas.

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Chapter 1 Solutions

Physical Chemistry

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