Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 1, Problem 1.34E
Interpretation Introduction

Interpretation:

A derivative with respect to the same variable can be taken more than once:

δδx(δFδx)=δ2FδF2

and is called the second derivative of F. The following expressions are to be evaluated, assuming the ideal gas law applies.

(a)(δ2Vδp2)n,T(b)(δ2pδT2)n,V

Concept introduction:

Slope of a line is defined as both direction and the steepness of the line. The value of slope is denoted by the letter ‘m’. In a straight-line equation y = mx + c, the slope is ‘m’. Generally, the slope of a line is calculated by finding the ratio of the vertical change to the horizontal change between two distinct points. The ideal gas law or general gas equation is the equation of state of a hypothetical ideal gas. The term was first coined by Emile Clapeyron in the year of 1834 as combination of other laws. The ideal gas law can be written as PV = nRT.

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Chapter 1 Solutions

Physical Chemistry

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