Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 1, Problem 1.55E

The Berthelot equation of state for one mole of gas is p =   R T V ¯ - b -   a T V ¯   2 Where a and b are constants determined experimentally. For NH3(g), a = 741.6 atm. L2. K and b = 0.0139 L. Calculate p when V ¯ = 22.41   L and T = 273.15K. How much does the pressure vary from p as predicted by the ideal gas law?

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Physical Chemistry

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