
Concept explainers
Interpretation: The substances which are soluble in water needs to be identified.
Concept Introduction: The ability of the solute, to dissolve in solvent is known as solubility. Solubility rules are proposed for different ions, whether they are soluble or not. According to solubility rule, it will be confirm that given salt solution will form precipitate or remain aqueous.

Explanation of Solution
Reason for correct option:
According to the solubility rule, salts that contain Cl-, Br −or I − ions are generally soluble in water. Also, the salts in which elements from group 1 are present, they are soluble in water.
Thus, potassium chloride − KCl is soluble in water as potassium is a group 1 element.
Now, all the salts containing phosphates are insoluble but if cations are Na+, K+ and NH4+, they become soluble. Also, salts in which elements from group 1 are present, they are soluble in water.
Thus, sodium phosphate Na3PO4- is soluble in water.
The ammonium ion slats are generally soluble also, the salts of most sulphates are soluble thus, (NH4)2SO4-is soluble in water.
Salts containing nitrate ion (NO3-) are generally soluble.
Thus, iron (III) nitrate Fe (NO3)3 is soluble
Reason for incorrect option:
Now, salts in which Cl - , Br − and I − ions are present are generally soluble except with the cations Ag+ , Pb2+ and (Hg2)2+ .
Thus, AgCl is insoluble in water.
Carbonates are frequently insoluble. If the cations are from Group II thus, carbonates (are insoluble.
Thus, CaCO3- is insoluble in water
According to the solubility rule, phosphates such as Ca3(PO4)2 and Ag3PO4 are frequently insoluble.
Thus, chromium (III) Phosphate CrPO4- is insoluble
The hydroxide salts are slightly soluble. But, if cations are from group 1, they are highly soluble.
Since, Pb is not a group 1 element thus, Pb(OH)2 is slightly soluble in water.
Chapter 8 Solutions
World of Chemistry, 3rd edition
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