Concept explainers
(a)
Interpretation:
The preparation for given compound has to be identified by using
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds and donates its electrons to electrophilic compounds that results in bond formation.
Nucleophilic nature of a molecule depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Addition Reaction: It is defined as
Electrophilic addition: It is a type of addition reaction in which the pi bond present in the molecule breaks as the electrophile approaches the molecule and results in the formation of product with sigma bond.
Acid Catalyzed Hydration Reaction: The reaction involves breaking of phi bonds between carbon-carbon multiple bonds present in a molecule and addition of alcohol to more substituted position of carbon in the molecule.
For example consider Acid Catalyzed Hydration Reaction of alkene. First step is acid donates proton to alkene which leads to the formation of more stable carbo cation.
Then, the water is added to the given alkene through acid catalyzed reaction. Here the water gets added to the carbo cation and finally one proton gets removed from oxonium ion (oxygen with one positive charge) using water results in the formation of product.
Carbocation: It is carbon ion that bears a positive charge on it.
(b)
Interpretation:
The preparation for given compound has to be identified by using alkene as starting material.
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds and donates its electrons to electrophilic compounds that results in bond formation.
Nucleophilic nature of a molecule depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
Electrophilic addition: It is a type of addition reaction in which the pi bond present in the molecule breaks as the electrophile approaches the molecule and results in the formation of product with sigma bond.
Acid Catalyzed Hydration Reaction: The reaction involves breaking of phi bonds between carbon-carbon multiple bonds present in a molecule and addition of alcohol to more substituted position of carbon in the molecule.
For example consider Acid Catalyzed Hydration Reaction of alkene. First step is acid donates proton to alkene which leads to the formation of more stable carbo cation.
Then, the water is added to the given alkene through acid catalyzed reaction. Here the water gets added to the carbo cation and finally one proton gets removed from oxonium ion (oxygen with one positive charge) using water results in the formation of product.
Carbocation: It is carbon ion that bears a positive charge on it.
(c)
Interpretation:
The preparation for given compound has to be identified by using alkene as starting material.
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds and donates its electrons to electrophilic compounds that results in bond formation.
Nucleophilic nature of a molecule depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
Electrophilic addition: It is a type of addition reaction in which the pi bond present in the molecule breaks as the electrophile approaches the molecule and results in the formation of product with sigma bond.
Acid Catalyzed Hydration Reaction: The reaction involves breaking of phi bonds between carbon-carbon multiple bonds present in a molecule and addition of alcohol to more substituted position of carbon in the molecule.
For example consider Acid Catalyzed Hydration Reaction of alkene. First step is acid donates proton to alkene which leads to the formation of more stable carbo cation.
Then, the water is added to the given alkene through acid catalyzed reaction. Here the water gets added to the carbo cation and finally one proton gets removed from oxonium ion (oxygen with one positive charge) using water results in the formation of product.
Carbocation: It is carbon ion that bears a positive charge on it.
(d)
Interpretation:
The preparation for given compound has to be identified by using alkene as starting material.
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds and donates its electrons to electrophilic compounds that results in bond formation.
Nucleophilic nature of a molecule depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
Electrophilic addition: It is a type of addition reaction in which the pi bond present in the molecule breaks as the electrophile approaches the molecule and results in the formation of product with sigma bond.
Acid Catalyzed Hydration Reaction: The reaction involves breaking of phi bonds between carbon-carbon multiple bonds present in a molecule and addition of alcohol to more substituted position of carbon in the molecule.
For example consider Acid Catalyzed Hydration Reaction of alkene. First step is acid donates proton to alkene which leads to the formation of more stable carbo cation.
Then, the water is added to the given alkene through acid catalyzed reaction. Here the water gets added to the carbo cation and finally one proton gets removed from oxonium ion (oxygen with one positive charge) using water results in the formation of product.
Carbocation: It is carbon ion that bears a positive charge on it.
Want to see the full answer?
Check out a sample textbook solutionChapter 6 Solutions
Essential Organic Chemistry, Global Edition
- NH2 1. CH3–MgCl 2. H3O+ ? As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new C - C bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new C - C bond. Х ☐: Carrow_forwardPredict the major products of this organic reaction. If there will be no major products, check the box under the drawing area instead. No reaction. : + Х è OH K Cr O 2 27 2 4' 2 Click and drag to start drawing a structure.arrow_forwardLaminar compounds are characterized by havinga) a high value of the internal surface of the solid.b) a high adsorption potential.arrow_forward
- Intercalation compounds have their sheetsa) negatively charged.b) positively charged.arrow_forwardIndicate whether the following two statements are correct or not:- Polythiazine, formed by N and S, does not conduct electricity- Carbon can have a specific surface area of 3000 m2/garrow_forwardIndicate whether the following two statements are correct or not:- The S8 heterocycle is the origin of a family of compounds- Most of the elements that give rise to stable heterocycles belong to group d.arrow_forward
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning