Interpretation:
The size of the ion is to be compared with the size of the atom from which it is formed.
Concept Introduction :
An ion is formed by gaining or losing electrons by an atom. The number of electrons lost or gained by an atom becomes its charge. If an element loses electrons, it has a positive charge. In the symbol for an ion, the charge is represented as a superscript of the symbol of the atom for that element.
Answer to Problem 21LC
Cations have sizes smaller than that of the corresponding atom whereas anions have sizes greater than that of the corresponding atom.
Explanation of Solution
When an atom loses one or more electrons, a positively charged ion or cation is formed. The cations are smaller in size than the atom from which it is formed. This is because they contain fewer electrons while having the same nuclear charge (no. of protons). The protons in the nucleus are holding the residual electrons more firmly and so, their radii are less than those of the parent atoms.
Anions are formed when an atom gains one or more electrons. Anions are always larger than the parent atom. This is because the number of protons in an atom stays the same, but the number of electrons increases as it forms an anion. The anion's electron cloud spreads and enlarges because of the repulsive force of the electrons becoming stronger than the attraction of the positively charged nucleus.
Chapter 6 Solutions
Chemistry 2012 Student Edition (hard Cover) Grade 11
- The acid-base indicator HX undergoes the following reaction in a dilute aqueous solution: HX (color 1) H+ + X- (color 2). The following absorbance data were obtained for a 0.00035 M solution of HX in 0.1 M NaOH and 0.1 M HCI. Measurements were made at wavelengths of 450 nm and 620 nm using a 1.0 cm glass cuvette. 450 620 A(460 nm) A(630 nm) 0.1 M NaOH 0.1 M HCI 0.065 0.435 0.895 0.150 In the 0.1M NaOH solution, the indicator will be almost 100% in the X- form, while in 0.1M HCI, the indicator will be nearly 100% protonated (HX). Calculate the acid dissociation constant for the indicator if a pH=5 buffer solution containing a very small amount of indicator exhibits an absorbance of 0.567 at 450 nm and 0.395 at 620 nm (measured in a 1 cm glass cuvette).arrow_forwardShow work...give the name of the given compound. Don't give Ai generated solutionarrow_forwardShow work with explanation needed. don't give Ai generated solutionarrow_forward
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