IUPAC name of the given compound has to be chosen from the given options. Concept Introduction: IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine. Longest carbon chain has to be identified that is attached to nitrogen atom. Suffix “-e” in name of the parent chain alkane is replaced by “-amine”. Numbering of the carbon chain is done from the end that is near the nitrogen atom. Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name. In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name. If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N -substituted primary amines. Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Question

22.7 Predict the monoalkylated products of the following reactions with benzene. (a) AlCl3 Ya (b) AlCl3 (c) H3PO4 (d) 22.8 Think-Pair-Share AICI3 The reaction below is a common electrophilic aromatic substitution. SO3 H₂SO4 SO₂H (a) Draw the reaction mechanism for this reaction using HSO,+ as the electrophile. (b) Sketch the reaction coordinate diagram, where the product is lower in energy than the starting reactant. (c) Which step in the reaction mechanism is highest in energy? Explain. (d) Which of the following reaction conditions could be used in an electrophilic aro- matic substitution with benzene to provide substituted phenyl derivatives? (i) AICI3 HNO3 H₂SO4 K2Cr2O7 (iii) H₂SO4 (iv) H₂PO₁

Answer 1

Question

Chapter 6.3, Problem 1QQ

Interpretation Introduction

Interpretation:

IUPAC name of the given compound has to be chosen from the given options.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

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22.7 Predict the monoalkylated products of the following reactions with benzene. (a) AlCl3 Ya (b) AlCl3 (c) H3PO4 (d) 22.8 Think-Pair-Share AICI3 The reaction below is a common electrophilic aromatic substitution. SO3 H₂SO4 SO₂H (a) Draw the reaction mechanism for this reaction using HSO,+ as the electrophile. (b) Sketch the reaction coordinate diagram, where the product is lower in energy than the starting reactant. (c) Which step in the reaction mechanism is highest in energy? Explain. (d) Which of the following reaction conditions could be used in an electrophilic aro- matic substitution with benzene to provide substituted phenyl derivatives? (i) AICI3 HNO3 H₂SO4 K2Cr2O7 (iii) H₂SO4 (iv) H₂PO₁

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