On basic hydrolysis of amide, the organic products that are obtained has to be chosen from the given options. Concept Introduction: Amides are derivatives of carboxylic acid . Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes. Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt. Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Question

Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO2 (g) = N2O4(g) AGº = -5.4 kJ Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system: Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to '2' rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. 00 rise ☐ x10 fall yes no ☐ atm G Ar 1

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 6.18, Problem 2QQ

Interpretation Introduction

Interpretation:

On basic hydrolysis of amide, the organic products that are obtained has to be chosen from the given options.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO2 (g) = N2O4(g) AGº = -5.4 kJ Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system: Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to '2' rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. 00 rise ☐ x10 fall yes no ☐ atm G Ar 1

Why do we analyse salt?

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H H CH3OH, H+ H Select to Add Arrows H° 0:0 'H + Q HH ■ Select to Add Arrows CH3OH, H* H. H CH3OH, H+ HH ■ Select to Add Arrows i Please select a drawing or reagent from the question area

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 6.18, Problem 2QQ

Interpretation Introduction

Interpretation:

On basic hydrolysis of amide, the organic products that are obtained has to be chosen from the given options.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 6.18, Problem 2QQ

Interpretation Introduction

Interpretation:

On basic hydrolysis of amide, the organic products that are obtained has to be chosen from the given options.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Expert Solution & Answer

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See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 6.18, Problem 2QQ

Interpretation Introduction