General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 6, Problem 6.126CHP
Interpretation Introduction
Interpretation:
Pounds of
Concept Introduction:
- Molecular weight is the sum of atomic weight of all atoms in a molecule.
- The percent composition is the percent by mass of each element in a compound.
- Empirical formula gives the information about the smallest whole number ratio of atoms in a compound.
- Molecular formula gives information about the ratios of different atoms in a compound.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 6 Solutions
General Chemistry: Atoms First
Ch. 6.2 - Sodium chlorate, NaClO3, decomposes when heated to...Ch. 6.2 - Balance the following equations: (a) C6H12O6 ...Ch. 6.2 - Prob. 6.3CPCh. 6.3 - Calculate the formula weight or molecular weight...Ch. 6.3 - Aspirin can be represented by the adjacent...Ch. 6.3 - Aspirin is prepared by reaction of salicylic acid...Ch. 6.4 - Ethyl alcohol is prepared industrially by the...Ch. 6.4 - Dichloromethane (CH2Cl2), used as a solvent in the...Ch. 6.5 - Lithium oxide was used aboard the space shuttle to...Ch. 6.5 - After lithium hydroxide is produced aboard the...
Ch. 6.5 - The following diagram represents the reaction of A...Ch. 6.6 - What is the empirical formula and what is the...Ch. 6.6 - What is the empirical formula of the ingredient in...Ch. 6.6 - What is the percent composition of citric acid, an...Ch. 6.7 - Prob. 6.15PCh. 6.7 - Ribose, a sugar present in the cells of all living...Ch. 6.7 - Convert the following percent compositions into...Ch. 6.8 - How many moles of solute are present in the...Ch. 6.8 - How many grams of solute would you use to prepare...Ch. 6.8 - Prob. 6.20PCh. 6.8 - The concentration of cholesterol (C27H46O) in...Ch. 6.9 - What is the final concentration if 75.0 mL of a...Ch. 6.9 - Sulfuric acid is normally purchased at a...Ch. 6.10 - What volume of 0.250 M H2SO4 is needed to react...Ch. 6.10 - What is the molarity of an HNO3 solution if 68.5...Ch. 6.11 - A 25.0 mL sample of vinegar (dilute acetic acid,...Ch. 6.11 - Prob. 6.27CPCh. 6.11 - What do you think are the main sources of error in...Ch. 6.11 - Recalculate Avogadros number assuming that the oil...Ch. 6 - Box (a) represents 1.0 mL of a solution of...Ch. 6 - Prob. 6.31CPCh. 6 - Prob. 6.32CPCh. 6 - Prob. 6.33CPCh. 6 - Fluoxetine, marketed as an antidepressant under...Ch. 6 - Prob. 6.35CPCh. 6 - Prob. 6.36CPCh. 6 - Prob. 6.37CPCh. 6 - Prob. 6.38SPCh. 6 - Prob. 6.39SPCh. 6 - Prob. 6.40SPCh. 6 - Prob. 6.41SPCh. 6 - Prob. 6.42SPCh. 6 - Prob. 6.43SPCh. 6 - Prob. 6.44SPCh. 6 - Prob. 6.45SPCh. 6 - Prob. 6.46SPCh. 6 - Prob. 6.47SPCh. 6 - How many grams are in a mole of each of the...Ch. 6 - Prob. 6.49SPCh. 6 - How many moles of ions are in 27.5 g of MgCl2?Ch. 6 - Prob. 6.51SPCh. 6 - Prob. 6.52SPCh. 6 - Prob. 6.53SPCh. 6 - Prob. 6.54SPCh. 6 - Prob. 6.55SPCh. 6 - Prob. 6.56SPCh. 6 - Prob. 6.57SPCh. 6 - Prob. 6.58SPCh. 6 - A sample that weighs 107.75 g is a mixture of 30%...Ch. 6 - Prob. 6.60SPCh. 6 - Prob. 6.61SPCh. 6 - Prob. 6.62SPCh. 6 - Prob. 6.63SPCh. 6 - Prob. 6.64SPCh. 6 - Ethylene gas, C2H4, reacts with water at high...Ch. 6 - Prob. 6.66SPCh. 6 - Prob. 6.67SPCh. 6 - Prob. 6.68SPCh. 6 - Prob. 6.69SPCh. 6 - Prob. 6.70SPCh. 6 - Prob. 6.71SPCh. 6 - Prob. 6.72SPCh. 6 - Prob. 6.73SPCh. 6 - Prob. 6.74SPCh. 6 - How many grams of each product result from the...Ch. 6 - Nickel(II) sulfate, used for nickel plating, is...Ch. 6 - Hydrazine, N2H4, once used as a rocket propellant,...Ch. 6 - Prob. 6.78SPCh. 6 - Prob. 6.79SPCh. 6 - Acetic acid (CH3CO2H) reacts with isopentyl...Ch. 6 - Prob. 6.81SPCh. 6 - If 1.87 g of acetic acid reacts with 2.31 g of...Ch. 6 - Prob. 6.83SPCh. 6 - Prob. 6.84SPCh. 6 - Prob. 6.85SPCh. 6 - Prob. 6.86SPCh. 6 - Prob. 6.87SPCh. 6 - Prob. 6.88SPCh. 6 - What are the empirical formulas of each of the...Ch. 6 - Prob. 6.90SPCh. 6 - Prob. 6.91SPCh. 6 - Prob. 6.92SPCh. 6 - Prob. 6.93SPCh. 6 - Prob. 6.94SPCh. 6 - Prob. 6.95SPCh. 6 - Prob. 6.96SPCh. 6 - Prob. 6.97SPCh. 6 - Prob. 6.98SPCh. 6 - Prob. 6.99SPCh. 6 - How many moles of solute are present in each of...Ch. 6 - Prob. 6.101SPCh. 6 - Prob. 6.102SPCh. 6 - Prob. 6.103SPCh. 6 - The sterile saline solution used to rinse contact...Ch. 6 - Prob. 6.105SPCh. 6 - Prob. 6.106SPCh. 6 - Prob. 6.107SPCh. 6 - A bottle of 12.0 M hydrochloric acid has only 35.7...Ch. 6 - Prob. 6.109SPCh. 6 - Prob. 6.110SPCh. 6 - Prob. 6.111SPCh. 6 - Prob. 6.112SPCh. 6 - Prob. 6.113SPCh. 6 - Prob. 6.114CHPCh. 6 - Prob. 6.115CHPCh. 6 - Prob. 6.116CHPCh. 6 - Prob. 6.117CHPCh. 6 - Give the percent composition of each of the...Ch. 6 - What are the empirical formulas of substances with...Ch. 6 - Prob. 6.120CHPCh. 6 - Prob. 6.121CHPCh. 6 - Ferrocene, a substance once proposed for use as a...Ch. 6 - Prob. 6.123CHPCh. 6 - Prob. 6.124CHPCh. 6 - Ethylene glycol, commonly used as automobile...Ch. 6 - Prob. 6.126CHPCh. 6 - Prob. 6.127CHPCh. 6 - Prob. 6.128CHPCh. 6 - Prob. 6.129CHPCh. 6 - Prob. 6.130CHPCh. 6 - Prob. 6.131CHPCh. 6 - Prob. 6.132CHPCh. 6 - Prob. 6.133CHPCh. 6 - Prob. 6.134CHPCh. 6 - Prob. 6.135CHPCh. 6 - Prob. 6.136CHPCh. 6 - Prob. 6.137CHPCh. 6 - A copper wire having a mass of 2.196 g was allowed...Ch. 6 - Prob. 6.139CHPCh. 6 - Prob. 6.140CHPCh. 6 - Window glass is typically made by mixing soda ash...Ch. 6 - Prob. 6.142MPCh. 6 - Prob. 6.143MPCh. 6 - Prob. 6.144MPCh. 6 - A compound with the formula XOCl2 reacts with...Ch. 6 - Element M is prepared industrially by a two-step...
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