
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Question
Chapter 6, Problem 6.55SP
Interpretation Introduction
Interpretation:
The number of carbon atoms in the period has to be calculated.
Concept Introduction:
Number of moles:
One mole is the equal to
Number of moles can be calculated as:
Number of moles =
Number of atoms=
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5 (a). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 6
5 (b). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 7
6. Are there any differences between the spectra you obtained
in Beyond Labz and the predicted spectra? If so, what were
the differences?
<
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Chapter 6 Solutions
General Chemistry: Atoms First
Ch. 6.2 - Sodium chlorate, NaClO3, decomposes when heated to...Ch. 6.2 - Balance the following equations: (a) C6H12O6 ...Ch. 6.2 - Prob. 6.3CPCh. 6.3 - Calculate the formula weight or molecular weight...Ch. 6.3 - Aspirin can be represented by the adjacent...Ch. 6.3 - Aspirin is prepared by reaction of salicylic acid...Ch. 6.4 - Ethyl alcohol is prepared industrially by the...Ch. 6.4 - Dichloromethane (CH2Cl2), used as a solvent in the...Ch. 6.5 - Lithium oxide was used aboard the space shuttle to...Ch. 6.5 - After lithium hydroxide is produced aboard the...
Ch. 6.5 - The following diagram represents the reaction of A...Ch. 6.6 - What is the empirical formula and what is the...Ch. 6.6 - What is the empirical formula of the ingredient in...Ch. 6.6 - What is the percent composition of citric acid, an...Ch. 6.7 - Prob. 6.15PCh. 6.7 - Ribose, a sugar present in the cells of all living...Ch. 6.7 - Convert the following percent compositions into...Ch. 6.8 - How many moles of solute are present in the...Ch. 6.8 - How many grams of solute would you use to prepare...Ch. 6.8 - Prob. 6.20PCh. 6.8 - The concentration of cholesterol (C27H46O) in...Ch. 6.9 - What is the final concentration if 75.0 mL of a...Ch. 6.9 - Sulfuric acid is normally purchased at a...Ch. 6.10 - What volume of 0.250 M H2SO4 is needed to react...Ch. 6.10 - What is the molarity of an HNO3 solution if 68.5...Ch. 6.11 - A 25.0 mL sample of vinegar (dilute acetic acid,...Ch. 6.11 - Prob. 6.27CPCh. 6.11 - What do you think are the main sources of error in...Ch. 6.11 - Recalculate Avogadros number assuming that the oil...Ch. 6 - Box (a) represents 1.0 mL of a solution of...Ch. 6 - Prob. 6.31CPCh. 6 - Prob. 6.32CPCh. 6 - Prob. 6.33CPCh. 6 - Fluoxetine, marketed as an antidepressant under...Ch. 6 - Prob. 6.35CPCh. 6 - Prob. 6.36CPCh. 6 - Prob. 6.37CPCh. 6 - Prob. 6.38SPCh. 6 - Prob. 6.39SPCh. 6 - Prob. 6.40SPCh. 6 - Prob. 6.41SPCh. 6 - Prob. 6.42SPCh. 6 - Prob. 6.43SPCh. 6 - Prob. 6.44SPCh. 6 - Prob. 6.45SPCh. 6 - Prob. 6.46SPCh. 6 - Prob. 6.47SPCh. 6 - How many grams are in a mole of each of the...Ch. 6 - Prob. 6.49SPCh. 6 - How many moles of ions are in 27.5 g of MgCl2?Ch. 6 - Prob. 6.51SPCh. 6 - Prob. 6.52SPCh. 6 - Prob. 6.53SPCh. 6 - Prob. 6.54SPCh. 6 - Prob. 6.55SPCh. 6 - Prob. 6.56SPCh. 6 - Prob. 6.57SPCh. 6 - Prob. 6.58SPCh. 6 - A sample that weighs 107.75 g is a mixture of 30%...Ch. 6 - Prob. 6.60SPCh. 6 - Prob. 6.61SPCh. 6 - Prob. 6.62SPCh. 6 - Prob. 6.63SPCh. 6 - Prob. 6.64SPCh. 6 - Ethylene gas, C2H4, reacts with water at high...Ch. 6 - Prob. 6.66SPCh. 6 - Prob. 6.67SPCh. 6 - Prob. 6.68SPCh. 6 - Prob. 6.69SPCh. 6 - Prob. 6.70SPCh. 6 - Prob. 6.71SPCh. 6 - Prob. 6.72SPCh. 6 - Prob. 6.73SPCh. 6 - Prob. 6.74SPCh. 6 - How many grams of each product result from the...Ch. 6 - Nickel(II) sulfate, used for nickel plating, is...Ch. 6 - Hydrazine, N2H4, once used as a rocket propellant,...Ch. 6 - Prob. 6.78SPCh. 6 - Prob. 6.79SPCh. 6 - Acetic acid (CH3CO2H) reacts with isopentyl...Ch. 6 - Prob. 6.81SPCh. 6 - If 1.87 g of acetic acid reacts with 2.31 g of...Ch. 6 - Prob. 6.83SPCh. 6 - Prob. 6.84SPCh. 6 - Prob. 6.85SPCh. 6 - Prob. 6.86SPCh. 6 - Prob. 6.87SPCh. 6 - Prob. 6.88SPCh. 6 - What are the empirical formulas of each of the...Ch. 6 - Prob. 6.90SPCh. 6 - Prob. 6.91SPCh. 6 - Prob. 6.92SPCh. 6 - Prob. 6.93SPCh. 6 - Prob. 6.94SPCh. 6 - Prob. 6.95SPCh. 6 - Prob. 6.96SPCh. 6 - Prob. 6.97SPCh. 6 - Prob. 6.98SPCh. 6 - Prob. 6.99SPCh. 6 - How many moles of solute are present in each of...Ch. 6 - Prob. 6.101SPCh. 6 - Prob. 6.102SPCh. 6 - Prob. 6.103SPCh. 6 - The sterile saline solution used to rinse contact...Ch. 6 - Prob. 6.105SPCh. 6 - Prob. 6.106SPCh. 6 - Prob. 6.107SPCh. 6 - A bottle of 12.0 M hydrochloric acid has only 35.7...Ch. 6 - Prob. 6.109SPCh. 6 - Prob. 6.110SPCh. 6 - Prob. 6.111SPCh. 6 - Prob. 6.112SPCh. 6 - Prob. 6.113SPCh. 6 - Prob. 6.114CHPCh. 6 - Prob. 6.115CHPCh. 6 - Prob. 6.116CHPCh. 6 - Prob. 6.117CHPCh. 6 - Give the percent composition of each of the...Ch. 6 - What are the empirical formulas of substances with...Ch. 6 - Prob. 6.120CHPCh. 6 - Prob. 6.121CHPCh. 6 - Ferrocene, a substance once proposed for use as a...Ch. 6 - Prob. 6.123CHPCh. 6 - Prob. 6.124CHPCh. 6 - Ethylene glycol, commonly used as automobile...Ch. 6 - Prob. 6.126CHPCh. 6 - Prob. 6.127CHPCh. 6 - Prob. 6.128CHPCh. 6 - Prob. 6.129CHPCh. 6 - Prob. 6.130CHPCh. 6 - Prob. 6.131CHPCh. 6 - Prob. 6.132CHPCh. 6 - Prob. 6.133CHPCh. 6 - Prob. 6.134CHPCh. 6 - Prob. 6.135CHPCh. 6 - Prob. 6.136CHPCh. 6 - Prob. 6.137CHPCh. 6 - A copper wire having a mass of 2.196 g was allowed...Ch. 6 - Prob. 6.139CHPCh. 6 - Prob. 6.140CHPCh. 6 - Window glass is typically made by mixing soda ash...Ch. 6 - Prob. 6.142MPCh. 6 - Prob. 6.143MPCh. 6 - Prob. 6.144MPCh. 6 - A compound with the formula XOCl2 reacts with...Ch. 6 - Element M is prepared industrially by a two-step...
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