EBK ORGANIC AND BIOLOGICAL CHEMISTRY
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
7th Edition
ISBN: 9780100547742
Author: STOKER
Publisher: YUZU
bartleby

Concept explainers

Lipids
The heterogeneous classes of organic compounds that are not water-soluble but are dissolved in organic solvents that are non-polar in nature are termed lipids. They are a long chain of fatty acids and esters of alcohols. Lipids are generally seen in seve…
Glycerophospholipid
Glycerophospholipid is the most abundantly occuring phospholipids found in the biological membranes. Lipids include a group of organic compounds like fats, hormones, oils, waxes, vitamins etc. They are non-polar molecules and are insoluble in water. Lipi…
Structure Of Camphor
A terpene with the molecular formula of C10H16O is a waxy, white color solid known as camphor. It is flammable. It also possesses a very pungent taste and a strong odor. There are various sources for extracting camphor from natural products such as the …
Glycolipid In Organic Chemistry
Glycolipids are lipids that are an important class of organic compounds in chemistry that have simple to complex applications. They contain carbohydrates, fatty acids, sphingolipids or a glycerol group. In other words, they are the modifications of lipid…
Diterpenoid
The terpenoid class includes diterpenoids, which are chemical compounds with 20 carbon atoms. They are made up of four isoprene units and are derived from geranylgeraniol, a C20 precursor. They have a C20H32 basic structure. These characteristics disting…
bartleby

Videos

Question
Book Icon
Chapter 5, Problem 5.7EP

(a)

Interpretation Introduction

Interpretation:

The “C−Z” bond in the general formula of carboxylic derivative is polar or nonpolar has to be indicated.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.  Aldehydes and ketones possess this carbonyl functional group in it.  The structural representation of a carbonyl group can be given as shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 1

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group.  This can be represented as shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 2

Carboxylic acid derivatives are the ones that are synthesized from or converted to a carboxylic acid.  The generalized structural representation of carboxylic acid derivatives is shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 3

In the carboxylic acid derivatives, if the carbonyl carbon atom is bonded to a more electronegative atom means, then the bond will be polar and is it is bonded to carbon atom means then it will be nonpolar.

(a)

Expert Solution
Check Mark

Answer to Problem 5.7EP

The “C−Z bond is polar.

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 4

Explanation of Solution

The general structure of carboxylic acid derivatives is,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 5

The atom in entity Z that is bonded to the carbonyl carbon atom is not a carbon atom.  It is a nitrogen atom.  As there is a polarity difference between carbon and nitrogen atom, the bond between carbon and nitrogen will be polar.  This can be shown as given below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 6

Conclusion

The “C−Z” bond is polar or not is indicated.

(b)

Interpretation Introduction

Interpretation:

The “C−Z” bond in the general formula of carboxylic derivative is polar or nonpolar has to be indicated.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.  Aldehydes and ketones possess this carbonyl functional group in it.  The structural representation of a carbonyl group can be given as shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 7

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group.  This can be represented as shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 8

Carboxylic acid derivatives are the ones that are synthesized from or converted to a carboxylic acid.  The generalized structural representation of carboxylic acid derivatives is shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 9

In the carboxylic acid derivatives, if the carbonyl carbon atom is bonded to a more electronegative atom means, then the bond will be polar and is it is bonded to carbon atom means then it will be nonpolar.

(b)

Expert Solution
Check Mark

Answer to Problem 5.7EP

The “C−Z bond is nonpolar.

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 10

Explanation of Solution

The general structure of carboxylic acid derivatives is,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 11

The atom in entity Z that is bonded to the carbonyl carbon atom is a carbon atom.  As there is no polarity difference between carbon and carbon atom, the bond between carbon and carbon will be nonpolar.  This can be shown as given below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 12

Conclusion

The “C−Z” bond is polar or not is indicated.

(c)

Interpretation Introduction

Interpretation:

The “C−Z” bond in the general formula of carboxylic derivative is polar or nonpolar has to be indicated.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.  Aldehydes and ketones possess this carbonyl functional group in it.  The structural representation of a carbonyl group can be given as shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 13

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group.  This can be represented as shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 14

Carboxylic acid derivatives are the ones that are synthesized from or converted to a carboxylic acid.  The generalized structural representation of carboxylic acid derivatives is shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 15

In the carboxylic acid derivatives, if the carbonyl carbon atom is bonded to a more electronegative atom means, then the bond will be polar and is it is bonded to carbon atom means then it will be nonpolar.

(c)

Expert Solution
Check Mark

Answer to Problem 5.7EP

The “C−Z bond is polar.

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 16

Explanation of Solution

The general structure of carboxylic acid derivatives is,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 17

The atom in entity Z that is bonded to the carbonyl carbon atom is an oxygen atom.  As there is a polarity difference between carbon and oxygen atom, the bond between carbon and oxygen will be polar.  This can be shown as given below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 18

Conclusion

The “C−Z” bond is polar or not is indicated.

(d)

Interpretation Introduction

Interpretation:

The “C−Z” bond in the general formula of carboxylic derivative is polar or nonpolar has to be indicated.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.  Aldehydes and ketones possess this carbonyl functional group in it.  The structural representation of a carbonyl group can be given as shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 19

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group.  This can be represented as shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 20

Carboxylic acid derivatives are the ones that are synthesized from or converted to a carboxylic acid.  The generalized structural representation of carboxylic acid derivatives is shown below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 21

In the carboxylic acid derivatives, if the carbonyl carbon atom is bonded to a more electronegative atom means, then the bond will be polar and is it is bonded to carbon atom means then it will be nonpolar.

(d)

Expert Solution
Check Mark

Answer to Problem 5.7EP

The “C−Z bond is polar.

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 22

Explanation of Solution

The general structure of carboxylic acid derivatives is,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 23

The atom in entity Z that is bonded to the carbonyl carbon atom is an oxygen atom.  As there is a polarity difference between carbon and oxygen atom, the bond between carbon and oxygen will be polar.  This can be shown as given below,

EBK ORGANIC AND BIOLOGICAL CHEMISTRY, Chapter 5, Problem 5.7EP , additional homework tip 24

Conclusion

The “C−Z” bond is polar or not is indicated.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Previous
Chapter 5, Problem 5.6EP
Next
Chapter 5, Problem 5.8EP
Students have asked these similar questions
(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.
with full details solution please

Chapter 5 Solutions

EBK ORGANIC AND BIOLOGICAL CHEMISTRY

Ch. 5.1 - Prob. 1QQCh. 5.1 - Prob. 2QQCh. 5.1 - Prob. 3QQCh. 5.1 - Prob. 4QQCh. 5.1 - Prob. 5QQCh. 5.2 - Prob. 1QQCh. 5.2 - Prob. 2QQCh. 5.2 - Prob. 3QQCh. 5.2 - Prob. 4QQCh. 5.2 - Prob. 5QQ
Ch. 5.3 - Prob. 1QQCh. 5.3 - Prob. 2QQCh. 5.3 - Prob. 3QQCh. 5.4 - Prob. 1QQCh. 5.4 - Prob. 2QQCh. 5.4 - Prob. 3QQCh. 5.5 - Prob. 1QQCh. 5.5 - Prob. 2QQCh. 5.5 - Prob. 3QQCh. 5.6 - Prob. 1QQCh. 5.6 - Prob. 2QQCh. 5.7 - Which of the following statements about acid...Ch. 5.7 - Prob. 2QQCh. 5.7 - Prob. 3QQCh. 5.8 - Prob. 1QQCh. 5.8 - Prob. 2QQCh. 5.8 - Prob. 3QQCh. 5.8 - Prob. 4QQCh. 5.9 - Prob. 1QQCh. 5.9 - Prob. 2QQCh. 5.10 - Prob. 1QQCh. 5.10 - Prob. 2QQCh. 5.11 - Prob. 1QQCh. 5.11 - Prob. 2QQCh. 5.11 - Prob. 3QQCh. 5.12 - Prob. 1QQCh. 5.12 - Prob. 2QQCh. 5.12 - Prob. 3QQCh. 5.12 - Prob. 4QQCh. 5.13 - Prob. 1QQCh. 5.13 - Prob. 2QQCh. 5.14 - Prob. 1QQCh. 5.14 - Prob. 2QQCh. 5.14 - Prob. 3QQCh. 5.15 - Prob. 1QQCh. 5.15 - Prob. 2QQCh. 5.15 - Prob. 3QQCh. 5.16 - Prob. 1QQCh. 5.16 - Prob. 2QQCh. 5.16 - Prob. 3QQCh. 5.17 - Prob. 1QQCh. 5.17 - Prob. 2QQCh. 5.18 - Prob. 1QQCh. 5.18 - Prob. 2QQCh. 5.18 - Prob. 3QQCh. 5.19 - Prob. 1QQCh. 5.19 - Prob. 2QQCh. 5.19 - Prob. 3QQCh. 5.19 - Prob. 4QQCh. 5.20 - Prob. 1QQCh. 5.20 - Prob. 2QQCh. 5.20 - Prob. 3QQCh. 5.20 - Prob. 4QQCh. 5 - Prob. 5.1EPCh. 5 - Prob. 5.2EPCh. 5 - Prob. 5.3EPCh. 5 - Indicate whether or not each of the compounds in...Ch. 5 - Prob. 5.5EPCh. 5 - Prob. 5.6EPCh. 5 - Prob. 5.7EPCh. 5 - Prob. 5.8EPCh. 5 - Prob. 5.9EPCh. 5 - Prob. 5.10EPCh. 5 - Prob. 5.11EPCh. 5 - Prob. 5.12EPCh. 5 - Prob. 5.13EPCh. 5 - Prob. 5.14EPCh. 5 - Prob. 5.15EPCh. 5 - Assign an IUPAC name to each of the following...Ch. 5 - Prob. 5.17EPCh. 5 - Prob. 5.18EPCh. 5 - Prob. 5.19EPCh. 5 - Prob. 5.20EPCh. 5 - Prob. 5.21EPCh. 5 - Prob. 5.22EPCh. 5 - Prob. 5.23EPCh. 5 - Prob. 5.24EPCh. 5 - Prob. 5.25EPCh. 5 - Prob. 5.26EPCh. 5 - Prob. 5.27EPCh. 5 - Prob. 5.28EPCh. 5 - Prob. 5.29EPCh. 5 - Prob. 5.30EPCh. 5 - Prob. 5.31EPCh. 5 - Prob. 5.32EPCh. 5 - Prob. 5.33EPCh. 5 - Prob. 5.34EPCh. 5 - Prob. 5.35EPCh. 5 - Prob. 5.36EPCh. 5 - Prob. 5.37EPCh. 5 - Prob. 5.38EPCh. 5 - Prob. 5.39EPCh. 5 - Prob. 5.40EPCh. 5 - Determine the maximum number of hydrogen bonds...Ch. 5 - Prob. 5.42EPCh. 5 - Prob. 5.43EPCh. 5 - Prob. 5.44EPCh. 5 - Prob. 5.45EPCh. 5 - Prob. 5.46EPCh. 5 - Prob. 5.47EPCh. 5 - Prob. 5.48EPCh. 5 - Prob. 5.49EPCh. 5 - Prob. 5.50EPCh. 5 - Prob. 5.51EPCh. 5 - Prob. 5.52EPCh. 5 - Prob. 5.53EPCh. 5 - Prob. 5.54EPCh. 5 - Draw structural formulas for the following...Ch. 5 - Prob. 5.56EPCh. 5 - Give the IUPAC name for each of the following...Ch. 5 - Give the IUPAC name for each of the following...Ch. 5 - Prob. 5.59EPCh. 5 - Prob. 5.60EPCh. 5 - Prob. 5.61EPCh. 5 - Prob. 5.62EPCh. 5 - Prob. 5.63EPCh. 5 - Prob. 5.64EPCh. 5 - Prob. 5.65EPCh. 5 - Which three carboxylic acids have salts that are...Ch. 5 - Prob. 5.67EPCh. 5 - Which carboxylic acid has salts that are used to...Ch. 5 - Prob. 5.69EPCh. 5 - Prob. 5.70EPCh. 5 - Prob. 5.71EPCh. 5 - Prob. 5.72EPCh. 5 - Prob. 5.73EPCh. 5 - Prob. 5.74EPCh. 5 - Prob. 5.75EPCh. 5 - Prob. 5.76EPCh. 5 - Prob. 5.77EPCh. 5 - Prob. 5.78EPCh. 5 - Prob. 5.79EPCh. 5 - Prob. 5.80EPCh. 5 - Prob. 5.81EPCh. 5 - Prob. 5.82EPCh. 5 - Prob. 5.83EPCh. 5 - Prob. 5.84EPCh. 5 - Prob. 5.85EPCh. 5 - Prob. 5.86EPCh. 5 - Prob. 5.87EPCh. 5 - Prob. 5.88EPCh. 5 - Prob. 5.89EPCh. 5 - Prob. 5.90EPCh. 5 - Assign common names to each of the esters in...Ch. 5 - Prob. 5.92EPCh. 5 - Prob. 5.93EPCh. 5 - Assign an IUPAC name to each of the following...Ch. 5 - Draw a structural formula for each of the...Ch. 5 - Prob. 5.96EPCh. 5 - Prob. 5.97EPCh. 5 - Prob. 5.98EPCh. 5 - Prob. 5.99EPCh. 5 - Prob. 5.100EPCh. 5 - Prob. 5.101EPCh. 5 - How many carbon atoms are present in a molecule of...Ch. 5 - Prob. 5.103EPCh. 5 - Prob. 5.104EPCh. 5 - Prob. 5.105EPCh. 5 - Prob. 5.106EPCh. 5 - Prob. 5.107EPCh. 5 - Prob. 5.108EPCh. 5 - Prob. 5.109EPCh. 5 - Prob. 5.110EPCh. 5 - Prob. 5.111EPCh. 5 - Prob. 5.112EPCh. 5 - Prob. 5.113EPCh. 5 - Prob. 5.114EPCh. 5 - Prob. 5.115EPCh. 5 - Prob. 5.116EPCh. 5 - Prob. 5.117EPCh. 5 - Prob. 5.118EPCh. 5 - Prob. 5.119EPCh. 5 - Prob. 5.120EPCh. 5 - Prob. 5.121EPCh. 5 - Prob. 5.122EPCh. 5 - Prob. 5.123EPCh. 5 - Prob. 5.124EPCh. 5 - Write the structural formulas of the reaction...Ch. 5 - Prob. 5.126EPCh. 5 - Prob. 5.127EPCh. 5 - Prob. 5.128EPCh. 5 - Prob. 5.129EPCh. 5 - Prob. 5.130EPCh. 5 - Prob. 5.131EPCh. 5 - Prob. 5.132EPCh. 5 - Prob. 5.133EPCh. 5 - Prob. 5.134EPCh. 5 - Prob. 5.135EPCh. 5 - Prob. 5.136EPCh. 5 - Prob. 5.137EPCh. 5 - Prob. 5.138EPCh. 5 - Prob. 5.139EPCh. 5 - Prob. 5.140EPCh. 5 - Prob. 5.141EPCh. 5 - Prob. 5.142EPCh. 5 - Prob. 5.143EPCh. 5 - Prob. 5.144EPCh. 5 - Prob. 5.145EPCh. 5 - Prob. 5.146EPCh. 5 - Prob. 5.147EPCh. 5 - Prob. 5.148EPCh. 5 - Draw a condensed structural formula for the...Ch. 5 - Draw a condensed structural formula for the...Ch. 5 - Prob. 5.151EPCh. 5 - Prob. 5.152EPCh. 5 - Prob. 5.153EPCh. 5 - Prob. 5.154EPCh. 5 - Prob. 5.155EPCh. 5 - Prob. 5.156EPCh. 5 - Prob. 5.157EPCh. 5 - Prob. 5.158EPCh. 5 - Prob. 5.159EPCh. 5 - Prob. 5.160EPCh. 5 - Prob. 5.161EPCh. 5 - Prob. 5.162EPCh. 5 - Prob. 5.163EPCh. 5 - Prob. 5.164EP
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
Text book image
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Text book image
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Text book image
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
Introductory Chemistry For Today
Chemistry
ISBN:9781285644561
Author:Seager
Publisher:Cengage
SEE MORE TEXTBOOKS
Lipids - Fatty Acids, Triglycerides, Phospholipids, Terpenes, Waxes, Eicosanoids; Author: The Organic Chemistry Tutor;https://www.youtube.com/watch?v=7dmoH5dAvpY;License: Standard YouTube License, CC-BY