(a)
Interpretation:
The number of ions that is present in one formula unit of the given salt of
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
If the negative ion contains two carboxylate groups in it then it is a dicarboxylate. The parent acid of this has to be dicarboxylic acid. If the negative ion contains one carboxylate group in it then it is a monocarboxylate. The parent acid of this has to be monocarboxylic acid.
This can also be found from the name of the salt given. If the IUPAC name contains suffix “-ate” alone means it is a salt of monocarboxylic acid. If the IUPAC name contains prefix “di-” that is preceded by “-ate” in the ending means it is a salt dicarboxylic acid.
Total number of ions in one formula unit of carboxylic acid salt is found by counting the number of discrete ions present in the structure.
(b)
Interpretation:
The number of ions that is present in one formula unit of the given salt of carboxylic acid has to be given.
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
If the negative ion contains two carboxylate groups in it then it is a dicarboxylate. The parent acid of this has to be dicarboxylic acid. If the negative ion contains one carboxylate group in it then it is a monocarboxylate. The parent acid of this has to be monocarboxylic acid.
This can also be found from the name of the salt given. If the IUPAC name contains suffix “-ate” alone means it is a salt of monocarboxylic acid. If the IUPAC name contains prefix “di-” that is preceded by “-ate” in the ending means it is a salt dicarboxylic acid.
Total number of ions in one formula unit of carboxylic acid salt is found by counting the number of discrete ions present in the structure.
(c)
Interpretation:
The number of ions that is present in one formula unit of the given salt of carboxylic acid has to be given.
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
If the negative ion contains two carboxylate groups in it then it is a dicarboxylate. The parent acid of this has to be dicarboxylic acid. If the negative ion contains one carboxylate group in it then it is a monocarboxylate. The parent acid of this has to be monocarboxylic acid.
This can also be found from the name of the salt given. If the IUPAC name contains suffix “-ate” alone means it is a salt of monocarboxylic acid. If the IUPAC name contains prefix “di-” that is preceded by “-ate” in the ending means it is a salt dicarboxylic acid.
Total number of ions in one formula unit of carboxylic acid salt is found by counting the number of discrete ions present in the structure.
(d)
Interpretation:
The number of ions that is present in one formula unit of the given salt of carboxylic acid has to be given.
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
If the negative ion contains two carboxylate groups in it then it is a dicarboxylate. The parent acid of this has to be dicarboxylic acid. If the negative ion contains one carboxylate group in it then it is a monocarboxylate. The parent acid of this has to be monocarboxylic acid.
This can also be found from the name of the salt given. If the IUPAC name contains suffix “-ate” alone means it is a salt of monocarboxylic acid. If the IUPAC name contains prefix “di-” that is preceded by “-ate” in the ending means it is a salt dicarboxylic acid.
Total number of ions in one formula unit of carboxylic acid salt is found by counting the number of discrete ions present in the structure.
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Chapter 5 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
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- TRANSMITTANCE เบบ Please identify the one structure below that is consistent with the 'H NMR and IR spectra shown and draw its complete structure in the box below with the protons alphabetically labeled as shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by the arrows. D 4000 OH LOH H₂C CH3 OH H₂C OCH3 CH3 OH 3000 2000 1500 HAVENUMBERI-11 1000 LOCH3 Draw your structure below and label its equivalent protons according to the peak labeling that is used in the NMR spectrum in order to assign the peaks. Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet 8 3Hb s m 1Hd s 3Hf m 2Hcd 2Had 1He 鄙视 m 7 7 6 5 4 3 22 500 T 1 0arrow_forwardRelative Transmittance 0.995 0.99 0.985 0.98 Please draw the structure that is consistent with all the spectral data below in the box and alphabetically label the equivalent protons in the structure (Ha, Hb, Hc ....) in order to assign all the proton NMR peaks. Label the absorption bands in the IR spectrum indicated by the arrows. INFRARED SPECTRUM 1 0.975 3000 2000 Wavenumber (cm-1) 1000 Structure with assigned H peaks 1 3 180 160 140 120 100 f1 (ppm) 80 60 40 20 0 C-13 NMR note that there are 4 peaks between 120-140ppm Integral values equal the number of equivalent protons 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 fl (ppm)arrow_forwardCalculate the pH of 0.0025 M phenol.arrow_forward
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