The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written. Concept Introduction: Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification. Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis. Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Question

5. Propose a Synthesis for the molecule below. You may use any starting materials containing 6 carbons or less (reagents that aren't incorporated into the final molecule such as PhзP do not count towards this total, and the starting material can have whatever non-carbon functional groups you want), and any of the reactions you have learned so far in organic chemistry I, II, and III. Your final answer should show each step separately, with intermediates and conditions clearly drawn. H3C CH3

Answer 1

Question

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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5. Propose a Synthesis for the molecule below. You may use any starting materials containing 6 carbons or less (reagents that aren't incorporated into the final molecule such as PhзP do not count towards this total, and the starting material can have whatever non-carbon functional groups you want), and any of the reactions you have learned so far in organic chemistry I, II, and III. Your final answer should show each step separately, with intermediates and conditions clearly drawn. H3C CH3

State the name and condensed formula of isooxazole obtained by reacting acetylacetone and hydroxylamine.

State the name and condensed formula of the isothiazole obtained by reacting acetylacetone and thiosemicarbazide.

Answer 2

Question

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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Answer 3

Question

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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Answer 4

Question

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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Answer 5

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 6

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 7

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 14

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Answer 25

Ch. 5.1 - Prob. 1QQ Ch. 5.1 - Prob. 2QQ Ch. 5.1 - Prob. 3QQ Ch. 5.1 - Prob. 4QQ Ch. 5.1 - Prob. 5QQ Ch. 5.2 - Prob. 1QQ Ch. 5.2 - Prob. 2QQ Ch. 5.2 - Prob. 3QQ Ch. 5.2 - Prob. 4QQ Ch. 5.2 - Prob. 5QQ

Solution Summary: The author explains that the IUPAC name of reaction products when given ester undergoes estr hydrolysis under acidic conditions has to be written.

Chapter 5 Solutions