The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written. Concept Introduction: Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification. Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis. Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Question

Q5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R H

Answer 1

Question

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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Q5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R H

Calculate the proton and carbon chemical shifts for this structure

A. B. b. Now consider the two bicyclic molecules A. and B. Note that A. is a dianion and B. is a neutral molecule. One of these molecules is a highly reactive compound first characterized in frozen noble gas matrices, that self-reacts rapidly at temperatures above liquid nitrogen temperature. The other compound was isolated at room temperature in the early 1960s, and is a stable ligand used in organometallic chemistry. Which molecule is the more stable molecule, and why?

Answer 2

Question

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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Answer 3

Question

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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Answer 4

Question

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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Answer 5

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 6

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 7

Chapter 5, Problem 5.131EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when given ester undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 14

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Answer 25

Ch. 5.1 - Prob. 1QQ Ch. 5.1 - Prob. 2QQ Ch. 5.1 - Prob. 3QQ Ch. 5.1 - Prob. 4QQ Ch. 5.1 - Prob. 5QQ Ch. 5.2 - Prob. 1QQ Ch. 5.2 - Prob. 2QQ Ch. 5.2 - Prob. 3QQ Ch. 5.2 - Prob. 4QQ Ch. 5.2 - Prob. 5QQ

Solution Summary: The author explains that the IUPAC name of reaction products when given ester undergoes estr hydrolysis under acidic conditions has to be written.

Chapter 5 Solutions