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Interpretation: The given elements should be arranged in the increasing order of their atomic radius using the periodic table.
Concept Introduction:
Periodic Table: The available chemical elements are arranged considering their
In periodic table the horizontal rows are called periods and the vertical column are called group.
There are seven periods and 18 groups present in the table and some of those groups are given special name as follows,
Atomic Number: Atomic number of the element is equal to the number of protons present in the nucleus of the element which is denoted by symbol Z. The superscript presents on the left side of the
Atomic radius: Atomic radius is the distance between the atomic nucleus and outermost electron of an atom. From the atomic radius, the size of atoms can be visualized. But there is no specific distance from nucleus to electron due to electron cloud around the atom does not have well-defined boundary.
The atomic radius follows the specific trend in the periodic table that it gets decreases as we go from left to right of the period due to increased nuclear charge the electrons gets added to the same sub-shell strongly binds resulting to decrease in the size.
It increases as we move from top to bottom of the table due to addition of shell in the element.
To determine: The increasing atomic size order for given elements.
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Chapter 4 Solutions
Chemistry: Atoms First V1
- 1. Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their (2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these orbitals from the two atoms forming a homonuclear л-bond. Which element would have a stronger bond, and why? (4 points)arrow_forwardWrite the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.arrow_forwardNonearrow_forward
- 3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward
- 2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward
- 7. a) Under normal conditions (room temperature & atmospheric pressure) potassium assumes bcc lattice. Atomic radius for 12-coordinate K atom is listed as 235 pm. What is the radius of potassium atom under normal conditions? (3 points) b) Titanium metal crystallyzes in hcp lattice. Under proper conditions nitrogen can be absorbed into the lattice of titanium resulting in an alloy of stoichiometry TiNo.2. Is this compound likely to be a substitutional or an interstitial alloy? (Radius of Ti (12-coordinate) is 147 pm; radius of N atom is 75 pm. (3 points)arrow_forwardcan someone answer the questions and draw out the complete mechanismarrow_forwardPlease help, draw and me the proper mechanisms.arrow_forward
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