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Concept explainers
(i)
Interpretation: The elements that correspond to the given set of electronic configuration should be determined.
Concept Introduction:
Periodic Table: The available chemical elements are arranged considering their
In periodic table the horizontal rows are called periods and the vertical column are called group.
The elements placed on the left of the table are metals which contain its last electron on s-orbital hence considered as s-block elements and the elements placed on the right side of the table contains its last electron in p-orbital which is regarded as p-block elements.
The s and p block elements together are called as main group elements.
The elements with its last electron in d-orbital are called d-block elements also called as
There are seven periods and 18 groups present in the table and some of those groups are given special name as follows,
Atomic Number: Atomic number of the element is equal to the number of protons present in the nucleus of the element which is denoted by symbol Z. The superscript presents on the left side of the
Electronic configuration: It is used to represent the distribution of electrons placed over orbitals that present in the atom.
The rules followed by the electrons are as follows,
The electrons gets distributed strictly following the order starting from lower energy orbital to higher energy orbital(Aufbau principle), pairing of electrons in subshell starts only when all the orbitals in the subshell are singly filled (Hund’s Rule) and finally, no two electrons that have same set of quantum numbers (Pauli’s Exclusion Principle).
To determine: The number of electrons and the valence electrons present in the given element positions in the periodic table.
(ii)
Interpretation: The elements that correspond to the given set of electronic configuration should be determined.
Concept Introduction:
Periodic Table: The available chemical elements are arranged considering their atomic number, the electronic configuration and their properties. The elements placed on the left of the table are metals and non-metals are placed on right side of the table.
In periodic table the horizontal rows are called periods and the vertical column are called group.
The elements placed on the left of the table are metals which contain its last electron on s-orbital hence considered as s-block elements and the elements placed on the right side of the table contains its last electron in p-orbital which is regarded as p-block elements.
The s and p block elements together are called as main group elements.
The elements with its last electron in d-orbital are called d-block elements also called as transition elements and elements with its last electron in f-orbital are called as inner-transition elements which are usually placed at the bottom of the periodic table.
There are seven periods and 18 groups present in the table and some of those groups are given special name as follows,
Atomic Number: Atomic number of the element is equal to the number of protons present in the nucleus of the element which is denoted by symbol Z. The superscript presents on the left side of the symbol of the element.
Electronic configuration: It is used to represent the distribution of electrons placed over orbitals that present in the atom.
The rules followed by the electrons are as follows,
The electrons gets distributed strictly following the order starting from lower energy orbital to higher energy orbital(Aufbau principle), pairing of electrons in subshell starts only when all the orbitals in the subshell are singly filled (Hund’s Rule) and finally, no two electrons that have same set of quantum numbers (Pauli’s Exclusion Principle).
To determine: The number of electrons and the valence electrons present in the given element positions in the periodic table.
(iii)
Interpretation: The elements that correspond to the given set of electronic configuration should be determined.
Concept Introduction:
Periodic Table: The available chemical elements are arranged considering their atomic number, the electronic configuration and their properties. The elements placed on the left of the table are metals and non-metals are placed on right side of the table.
In periodic table the horizontal rows are called periods and the vertical column are called group.
The elements placed on the left of the table are metals which contain its last electron on s-orbital hence considered as s-block elements and the elements placed on the right side of the table contains its last electron in p-orbital which is regarded as p-block elements.
The s and p block elements together are called as main group elements.
The elements with its last electron in d-orbital are called d-block elements also called as transition elements and elements with its last electron in f-orbital are called as inner-transition elements which are usually placed at the bottom of the periodic table.
There are seven periods and 18 groups present in the table and some of those groups are given special name as follows,
Atomic Number: Atomic number of the element is equal to the number of protons present in the nucleus of the element which is denoted by symbol Z. The superscript presents on the left side of the symbol of the element.
Electronic configuration: It is used to represent the distribution of electrons placed over orbitals that present in the atom.
The rules followed by the electrons are as follows,
The electrons gets distributed strictly following the order starting from lower energy orbital to higher energy orbital(Aufbau principle), pairing of electrons in subshell starts only when all the orbitals in the subshell are singly filled (Hund’s Rule) and finally, no two electrons that have same set of quantum numbers (Pauli’s Exclusion Principle).
To determine: The number of electrons and the valence electrons present in the given element positions in the periodic table.
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Chapter 4 Solutions
Chemistry: Atoms First V1
- Nonearrow_forward3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward
- 6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward
- 4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward7. a) Under normal conditions (room temperature & atmospheric pressure) potassium assumes bcc lattice. Atomic radius for 12-coordinate K atom is listed as 235 pm. What is the radius of potassium atom under normal conditions? (3 points) b) Titanium metal crystallyzes in hcp lattice. Under proper conditions nitrogen can be absorbed into the lattice of titanium resulting in an alloy of stoichiometry TiNo.2. Is this compound likely to be a substitutional or an interstitial alloy? (Radius of Ti (12-coordinate) is 147 pm; radius of N atom is 75 pm. (3 points)arrow_forwardcan someone answer the questions and draw out the complete mechanismarrow_forward
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