Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 4, Problem 10DQ
Interpretation Introduction
Interpretation: The order of the molecules
Concept introduction: Oxidation number depicts the oxidation state of any element in its compound, or molecular form. This is based on the concept that in a covalent bond, more electronegative atom possesses the electron pair completely. The oxidation state calculations are helpful to keep record of electron shifts in
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Part II Calculate λ max of the following compounds using wood ward- Fiecer rules
a)
b)
c)
d)
e)
OH
OH
dissolved in dioxane
Br
Br
dissolved in methanol.
NH₂
OCH 3
OH
6. Match each of the lettered items in the column on
the left with the most appropriate numbered
item(s) in the column on the right. Some of the
numbered items may be used more than once
and some not at all.
a.
Z = 37
1.
b.
Mn
2.
C.
Pr
element in period 5 and group
14
element in period 5 and group
15
d. S
e. [Rn] 7s¹
f.
d block
metal
3. highest metallic character of all
the elements
4. paramagnetic with 5 unpaired
electrons
5. 4f36s2
6. isoelectronic with Ca²+ cation
7.
an alkaline metal
8. an f-block element
Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.
Chapter 4 Solutions
Chemical Principles
Ch. 4 - Prob. 1DQCh. 4 - Prob. 2DQCh. 4 - Prob. 3DQCh. 4 - Prob. 4DQCh. 4 - Prob. 5DQCh. 4 - The exposed electrodes of a light bulb are placed...Ch. 4 - Prob. 7DQCh. 4 - Prob. 8DQCh. 4 - Consider separate aqueous solutions of HCland...Ch. 4 - Prob. 10DQ
Ch. 4 - Prob. 11DQCh. 4 - Characterize strong electrolytes versus weak...Ch. 4 - The figures below are molecular-level...Ch. 4 - Prob. 14ECh. 4 - Differentiate between what happens when the...Ch. 4 - Commercial cold packs and hot packs are available...Ch. 4 - Prob. 17ECh. 4 - Prob. 18ECh. 4 - Prob. 19ECh. 4 - Prob. 20ECh. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - A stock solution containing Mn2+ ions is prepared...Ch. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - List the formulas of three soluble bromide salts...Ch. 4 - Prob. 34ECh. 4 - Prob. 35ECh. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - Prob. 38ECh. 4 - Write the balanced molecular, complete, and net...Ch. 4 - How would you separate the following ions in...Ch. 4 - Prob. 41ECh. 4 - Prob. 42ECh. 4 - Prob. 43ECh. 4 - What volume of 0.100 M Na3PO4 is required to...Ch. 4 - Prob. 45ECh. 4 - Prob. 46ECh. 4 - Prob. 47ECh. 4 - The following drawings represent aqueous...Ch. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Saccharin (C7H5NO3S) is sometimes dispensed in...Ch. 4 - Prob. 54ECh. 4 - A 1.42-g sample of a pure compound with formula...Ch. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Prob. 61ECh. 4 - Prob. 62ECh. 4 - Prob. 63ECh. 4 - Sodium hydroxide solution is usually standardized...Ch. 4 - Prob. 65ECh. 4 - Prob. 66ECh. 4 - Prob. 67ECh. 4 - A student titrates an unknown amount of...Ch. 4 - Prob. 69ECh. 4 - Prob. 70ECh. 4 - Hydrochloric acid (75.0 mL of 0.250 M) is added...Ch. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Prob. 75ECh. 4 - Prob. 76ECh. 4 - Prob. 77ECh. 4 - Prob. 78ECh. 4 - Prob. 79ECh. 4 - Balance each of the following oxidationreduction...Ch. 4 - Prob. 81ECh. 4 - Prob. 82ECh. 4 - Prob. 83ECh. 4 - Prob. 84ECh. 4 - Prob. 85ECh. 4 - Prob. 86ECh. 4 - Prob. 87ECh. 4 - Prob. 88ECh. 4 - Prob. 89ECh. 4 - Prob. 90ECh. 4 - Prob. 91AECh. 4 - Prob. 92AECh. 4 - Consider a 1.50-g mixture of magnesium nitrate...Ch. 4 - Suppose 50.0 mL of 0.250 M CoCl2 solution is added...Ch. 4 - Prob. 95AECh. 4 - A mixture contains only NaCland Fe(NO3)3 . A...Ch. 4 - A mixture contains only sodium chloride and...Ch. 4 - Prob. 98AECh. 4 - A student added 50.0 mL of an NaOH solution...Ch. 4 - In a 1-L beaker, 203 mL of 0.307 M ammonium...Ch. 4 - It took 25.060.05 mL of a sodium hydroxide...Ch. 4 - You wish to prepare 1 L of a 0.02 M potassium...Ch. 4 - Citric acid, which can be obtained from lemon...Ch. 4 - Acetylsalicylic acid is the active ingredient in...Ch. 4 - A 6.50-g sample of a diprotic acid requires 137.5...Ch. 4 - Prob. 106AECh. 4 - Chlorisondamine chloride (C14H20Cl6N2) is a drug...Ch. 4 - Calculate the concentration of all ions present...Ch. 4 - A solution is prepared by dissolving 0.6706 g...Ch. 4 - For the following chemical reactions, determine...Ch. 4 - What volume of 0.100 M NaOH is required to...Ch. 4 - Prob. 112AECh. 4 - A 450.0-mL sample of a 0.257-M solution of silver...Ch. 4 - Prob. 114AECh. 4 - A 50.00-mL sample of aqueous Ca(OH)2 requires34.66...Ch. 4 - When organic compounds containing sulfur are...Ch. 4 - Assign the oxidation state for the element listed...Ch. 4 - The blood alcohol (C2H5OH) level can be determined...Ch. 4 - Zinc and magnesium metal each react with...Ch. 4 - A 10.00-g sample consisting of a mixture of...Ch. 4 - Consider the reaction of 19.0 g of zinc with...Ch. 4 - Consider an experiment in which two burets, Y and...Ch. 4 - A sample is a mixture of KCl and KBr. When 0.1024...Ch. 4 - You made 100.0 mL of a lead(II) nitrate solution...Ch. 4 - Polychlorinated biphenyls (PCBs) have been used...Ch. 4 - Prob. 126CPCh. 4 - Prob. 127CPCh. 4 - Chromium has been investigated as a coating for...Ch. 4 - Prob. 129CPCh. 4 - Three students were asked to find the identity of...Ch. 4 - A sample is a mixture of AgNO3,CuCl2,andFeCl3...Ch. 4 - Prob. 132MPCh. 4 - You have two 500.0-mL aqueous solutions. Solution...
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- Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1arrow_forwardCorrectly name this compound using the IUPAC naming system by sorting the components into the correct order. Br IN Ν Harrow_forwardHow is the radical intermediate for this structure formed? Can you please draw arrows from the first radical to the resonance form that would result in this product? I'm lost.arrow_forwardPart VI. (a) calculate the λ max of the compound using woodward - Fieser rules. (b) what types of electronic transitions are present in the compound? (c) what are the prominent peaks in the IR spectrum of the compound?arrow_forwardDon't used Ai solutionarrow_forwardPlease correct answer and don't used hand raitingarrow_forward↑ 0 Quiz List - RCC430M_RU05 X Aktiv Learning App × Qdraw resonance structure ×Q draw resonance structure xb My Questions | bartleby ×+ https://app.aktiv.com Draw a resonance structure of pyrrole that has the same number of pi bonds as the original structure. Include all lone pairs in your structure. + N H a 5 19°F Cloudy Q Search Problem 12 of 15 Atoms, Bonds and Rings Charges and Lone Pairs myhp हजु Undo Reset Remove Done Submit Drag To Pan 2:15 PM 1/25/2025arrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
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