Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 4, Problem 84E
Interpretation Introduction
Interpretation: The balanced chemical equations for the reaction between steel and nitric acid and then of reaction between obtained solution and periodate ion are to be written.
Concept introduction: The redox reactions involve the change in oxidation state of the reaction species and known as
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A slag sample is known to contain all of its iron in the forms of FeO and Fe2O3. A sample of 1,000 g of the slag was dissolved in hydrochloric acid according to the usual method, then reduced with stannous chloride and finally titrated with a 0.02237 M solution of potassium permanganate, of which 28.59 mL were used. A second aliquot of the slag sample, weighing 1,500, was dissolved in a nitrogen atmosphere to further adjust the oxidation state of the iron, it was immediately titrated with the same potassium permanganate solution. If this second experiment required 15.60 mL of permanganate solution, calculate:
a) The percentage of total iron in the slag.
b) The percentages of the oxide FeO and Fe2O3
World production of chromite (FeCr₂O₄), the main ore ofchromium, was 1.5107metric tons in 2003. To isolate chro-mium, a mixture of chromite and sodium carbonate is heated inair to form sodium chromate, iron(III) oxide, and carbon diox-ide. The sodium chromate is dissolved in water, and this solutionis acidified with sulfuric acid to produce the less soluble sodiumdichromate. The sodium dichromate is filtered out and reduced with carbon to produce chromium(III) oxide, sodium carbonate,and carbon monoxide. The chromium(III) oxide is then reduced to chromium with aluminum metal. (a) Write balanced equations for each step. (b) What mass of chromium (in kg) could be pre-pared from the 2003 world production of chromite?
In acidic solution, sodium oxalate, Na₂C₂O4, is oxidized to CO₂ by MnO4. In the process, MnO, is reduced to Mn² +.
To titrate a 0.855 g sample of Na₂C₂O₁, 43.7 mL of an MnO solution were required. The same MnO solution is then used to
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UO² (aq) → UO *(aq)
Calculate the mass percent of uranium in the sample.
mass percent of uranium:
%
Chapter 4 Solutions
Chemical Principles
Ch. 4 - Prob. 1DQCh. 4 - Prob. 2DQCh. 4 - Prob. 3DQCh. 4 - Prob. 4DQCh. 4 - Prob. 5DQCh. 4 - The exposed electrodes of a light bulb are placed...Ch. 4 - Prob. 7DQCh. 4 - Prob. 8DQCh. 4 - Consider separate aqueous solutions of HCland...Ch. 4 - Prob. 10DQ
Ch. 4 - Prob. 11DQCh. 4 - Characterize strong electrolytes versus weak...Ch. 4 - The figures below are molecular-level...Ch. 4 - Prob. 14ECh. 4 - Differentiate between what happens when the...Ch. 4 - Commercial cold packs and hot packs are available...Ch. 4 - Prob. 17ECh. 4 - Prob. 18ECh. 4 - Prob. 19ECh. 4 - Prob. 20ECh. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - A stock solution containing Mn2+ ions is prepared...Ch. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - List the formulas of three soluble bromide salts...Ch. 4 - Prob. 34ECh. 4 - Prob. 35ECh. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - Prob. 38ECh. 4 - Write the balanced molecular, complete, and net...Ch. 4 - How would you separate the following ions in...Ch. 4 - Prob. 41ECh. 4 - Prob. 42ECh. 4 - Prob. 43ECh. 4 - What volume of 0.100 M Na3PO4 is required to...Ch. 4 - Prob. 45ECh. 4 - Prob. 46ECh. 4 - Prob. 47ECh. 4 - The following drawings represent aqueous...Ch. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Saccharin (C7H5NO3S) is sometimes dispensed in...Ch. 4 - Prob. 54ECh. 4 - A 1.42-g sample of a pure compound with formula...Ch. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Prob. 61ECh. 4 - Prob. 62ECh. 4 - Prob. 63ECh. 4 - Sodium hydroxide solution is usually standardized...Ch. 4 - Prob. 65ECh. 4 - Prob. 66ECh. 4 - Prob. 67ECh. 4 - A student titrates an unknown amount of...Ch. 4 - Prob. 69ECh. 4 - Prob. 70ECh. 4 - Hydrochloric acid (75.0 mL of 0.250 M) is added...Ch. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Prob. 75ECh. 4 - Prob. 76ECh. 4 - Prob. 77ECh. 4 - Prob. 78ECh. 4 - Prob. 79ECh. 4 - Balance each of the following oxidationreduction...Ch. 4 - Prob. 81ECh. 4 - Prob. 82ECh. 4 - Prob. 83ECh. 4 - Prob. 84ECh. 4 - Prob. 85ECh. 4 - Prob. 86ECh. 4 - Prob. 87ECh. 4 - Prob. 88ECh. 4 - Prob. 89ECh. 4 - Prob. 90ECh. 4 - Prob. 91AECh. 4 - Prob. 92AECh. 4 - Consider a 1.50-g mixture of magnesium nitrate...Ch. 4 - Suppose 50.0 mL of 0.250 M CoCl2 solution is added...Ch. 4 - Prob. 95AECh. 4 - A mixture contains only NaCland Fe(NO3)3 . A...Ch. 4 - A mixture contains only sodium chloride and...Ch. 4 - Prob. 98AECh. 4 - A student added 50.0 mL of an NaOH solution...Ch. 4 - In a 1-L beaker, 203 mL of 0.307 M ammonium...Ch. 4 - It took 25.060.05 mL of a sodium hydroxide...Ch. 4 - You wish to prepare 1 L of a 0.02 M potassium...Ch. 4 - Citric acid, which can be obtained from lemon...Ch. 4 - Acetylsalicylic acid is the active ingredient in...Ch. 4 - A 6.50-g sample of a diprotic acid requires 137.5...Ch. 4 - Prob. 106AECh. 4 - Chlorisondamine chloride (C14H20Cl6N2) is a drug...Ch. 4 - Calculate the concentration of all ions present...Ch. 4 - A solution is prepared by dissolving 0.6706 g...Ch. 4 - For the following chemical reactions, determine...Ch. 4 - What volume of 0.100 M NaOH is required to...Ch. 4 - Prob. 112AECh. 4 - A 450.0-mL sample of a 0.257-M solution of silver...Ch. 4 - Prob. 114AECh. 4 - A 50.00-mL sample of aqueous Ca(OH)2 requires34.66...Ch. 4 - When organic compounds containing sulfur are...Ch. 4 - Assign the oxidation state for the element listed...Ch. 4 - The blood alcohol (C2H5OH) level can be determined...Ch. 4 - Zinc and magnesium metal each react with...Ch. 4 - A 10.00-g sample consisting of a mixture of...Ch. 4 - Consider the reaction of 19.0 g of zinc with...Ch. 4 - Consider an experiment in which two burets, Y and...Ch. 4 - A sample is a mixture of KCl and KBr. When 0.1024...Ch. 4 - You made 100.0 mL of a lead(II) nitrate solution...Ch. 4 - Polychlorinated biphenyls (PCBs) have been used...Ch. 4 - Prob. 126CPCh. 4 - Prob. 127CPCh. 4 - Chromium has been investigated as a coating for...Ch. 4 - Prob. 129CPCh. 4 - Three students were asked to find the identity of...Ch. 4 - A sample is a mixture of AgNO3,CuCl2,andFeCl3...Ch. 4 - Prob. 132MPCh. 4 - You have two 500.0-mL aqueous solutions. Solution...
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- Describe the production of metallic aluminum by electrolytic reduction.arrow_forwardBalance the following equations by oxidation-reduction methods; note that three elements change oxidation state.. Co(NO3)2(s)Co2O3(s)+NO2(g)+O2(g)arrow_forwardHow many cubic feet of air at a pressure of 760 torr and 0 C is required per ton of Fe2O3 to convert that Fe2O3 into iron in a blast furnace? For this exercise, assume air is 19% oxygen by volume.arrow_forward
- Basic solutions of Na4XeO6, are powerful oxidants. What mass of Mn(NO3)26H2O reacts with 125.0 mL of a 0.1717 M basic solution of Na4XeO6 that contains an excess of sodium hydroxide if the products include Xe and solution of sodium permanganate?arrow_forwardSodium hypochlorite is produced by the electrolysis of cold sodium chloride solution. How long must a cell operate to produce 1.500103 L of 5.00% NaClO by mass if the cell current is 2.00103 A? Assume that the density of the solution is 1.00 g/cm3.arrow_forwardThe following reactions all occur in a blast furnace. Which of these are redox reactions? (a) 3Fe2O3(s)+CO(g)2Fe3O4(s)+CO2(g) (b) Fe3O4(s)+CO(g)3FeO(s)+CO2(g) (c) FeO(s)+CO(g)Fe(l)+CO2(g) (d) C(s)+O2(g)CO2(g) (e) C(s)+CO2(g)2CO(g) (f) CaCO3(s)CaO(s)+CO2(g) (g) CaO(s)+SiO2(s)CaSiO3(l)arrow_forward
- A potassium permanganate solution is prepared by dissolving 4.68 g KMnO4 in water and diluting to 500 mL. Calculate the volume (mL) of this solution required to react with the iron in 0.500 g of an ore containing 35.6% Fe2O3. The reaction between Fe2+ and MnO4 - is: 5Fe2+ + MnO4 - + 8H+ → 5Fe3+ + Mn2+ + 4H2O [Molar mass of Fe2O3 =159.69 g/mol; KMnO4 =158.034 g/mol]arrow_forwardA 1.1324 g sample of magnetite ore was dissolved in concentrated HCl to give a solution that contained a mixture of Fe2+ and Fe3+. Nitric acid was added and the solution was boiled for a few minutes, which converted all of the iron to Fe3+. The Fe3+ was then precipitated as Fe2O3*xH2O by addition of NH3. After filtration and washing, the residue was ignited at a high temp to give 0.5394 g of pure Fe2O3. What is the percent Fe and the percent Fe3O4 in the sample?arrow_forwardThe common method for extraction of metals from the oxide ore is(a) Reduction with carbon(b) reduction with hydrogen(c) reduction with aluminium (d) electrolytic methodarrow_forward
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