A sample is a mixture of
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Chemical Principles
- Triiodide ions are generated in solution by the following (unbalanced) reaction in acidic solution: IO3(aq) + I(aq) I3(aq) Triiodide ion concentration is determined by titration with a sodium thiosulfate (Na2S2O3) solution. The products are iodide ion and tetrathionate ion (S4O6). a. Balance the equation for the reaction of IO3 with I ions. b. A sample of 0.6013 g of potassium iodate was dissolved in water. Hydrochloric acid and solid potassium iodide were then added. What is the minimum mass of solid KI and the minimum volume of 3.00 M HQ required to convert all of the IO3 ions to I ions? c. Write and balance the equation for the reaction of S2O32 with I3 in acidic solution. d. A 25.00-mL sample of a 0.0100 M solution of KIO. is reacted with an excess of KI. It requires 32.04 mL of Na2S2O3 solution to titrate the I3 ions present. What is the molarity of the Na2S2O3 solution? e. How would you prepare 500.0 mL of the KIO3 solution in part d using solid KIO3?arrow_forwardCalcium in blood or urine can be determined by precipitation as calcium oxalate, CaC2O4. The precipitate is dissolved in strong acid and titrated with potassium permanganate. The equation for reaction is 2MnO4(aq)+6H+(aq)+5H2C2O4(aq)2Mn2+(aq)+10CO2(g)+8H2O A 24-hour urine sample is collected from an adult patient, reduced to a small volume, and titrated with 26.2 mL of 0.0946 M KMnO4. How many grams of calcium oxalate are in the sample? Normal range for Ca2+ output for an adult is 100 to 300 mg per 24 hour. Is the sample within the normal range?arrow_forwardA 1.345-g sample of a compound of barium and oxygen was dissolved in hydrochloric acid to give a solution of barium ion, which was then precipitated with an excess of potassium chromate to give 2.012 g of barium chromate, BaCrO4. What is the formula of the compound?arrow_forward
- A 300.0-g sample of a solid is made up of a uniform mixture of NaNO3, MgCl2, and BaCl2. A 100.0-g sample of the mixture is dissolved in water and treated with an excess of KOH. The precipitate from the reaction has a mass of 13.47 g. The remaining 200.0-g sample is also dissolved in water and treated with an aqueous solution of AgNO3. The resulting precipitate has a mass of 195.8 g. What are the masses of NaNO3, MgCl2, and BaCl2 in the 300.0-g sample?arrow_forwardOne way of determining blood alcohol levels is by performing a titration on a sample of blood. In this process, the alcohol from the blood is oxidized by dichromate ions (Cr2O72-) according to the following net ionic equation: C2H5OH+2Cr2O72+16H+2CO2+4Cr3++11H2O A 10.00-g sample of blood was drawn from a patient, and 13.77 mL of 0.02538 M K2Cr2O7 was required to titrate the alcohol. What was the patient’s blood alcohol level? (See the previous problem for definition of blood alcohol level. K2Cr2O7 is a strong electrolyte, so it dissociates completely in solution.)arrow_forwardArsenic acid, H3AsO4, is a poisonous acid that has been used in the treatment of wood to prevent insect damage. Arsenic acid has three acidic protons. Say you take a 25.00-mL sample of arsenic acid and prepare it for titration with NaOH by adding 25.00 mL of water. The complete neutralization of this solution requires the addition of 53.07 mL of 0.6441 M NaOH solution. Write the balanced chemical reaction for the titration, and calculate the molarity of the arsenic acid sample.arrow_forward
- A metal, M, was converted to the chloride MCl2. Then a solution of the chloride was treated with silver nitrate to give silver chloride crystals, which were filtered from the solution. MCl2(aq)+2AgNO3(aq)M(NO3)2(aq)+2AgCl(s) If 2.434 g of the metal gave 7.964 g of silver chloride, what is the atomic weight of the metal? What is the metal?arrow_forwardSaccharin (C7H5NO3S) is sometimes dispensed in tablet form. Ten tablets with a total mass of 0.5894 g were dissolved in water. The saccharin was oxidized to convert all the sulfur to sulfate ion, which was precipitated by adding an excess of barium chloride solution. The mass of BaSO4 obtained was 0.5032 g. What is the average mass of saccharin per tablet? What is the average mass percent of saccharin in the tablets?arrow_forwardA 8.50 g sample of KCl is dissolved in 66.0 mL of water. The resulting solution is then added to 72.0 mL of a 0.280 M CaCl2(aq) solution. Assuming that the volumes are additive, calculate the concentrations of each ion present in the final solution.arrow_forward
- Glycerol (C3H8O3) is commonly used as an additive to moisturizers. The amount of glycerol added can be determined by titration with permanganate in basic solution. 14MnO4(aq)+C3H8O3(aq)+20OH(aq)14MnO42(aq)+3CO32(aq)+14H2O How many milliliters of 6.15 M KMnO4 are required to completely react with 7.25 mL of an aqueous solution of glycerol (d=1.144g/mL) that is 51.6% by mass?arrow_forward1. Sometimes a reaction can fall in more than one category. Into what category (or categories) does the reaction of Ba(OH)2(aq) + H+PO4(aq) fit? acid-base and oxidation-reduction oxidation-reduction acid-base and precipitation precipitationarrow_forward4.88 A quality control technician needs to determine the percentage of arsenic (As) in a particular pesticide. The pesticide is dissolved and all of the arsenic present is converted to arsenate ions (AsO43-). Then the amount of AsO43- is determined by titrating with a solution containing silver ions (Ag+). The silver reacts with the arsenate according to the following net ionic equation: 3Ag+(aq)+AsO43(aq)Ag3AsO4(s) When a 1.22-g sample of pesticide was analyzed this way, it required 25.0 mL of 0.102 M Ag+ solution to precipitate all of the AsO43-. What was the mass percentage of arsenic in the pesticide?arrow_forward
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