Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Textbook Question
Chapter 29.7, Problem 11P
Write mechanisms for step 2 of the citric acid cycle, the dehydration of citrate and the addition of water to aconitate.
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Chapter 29 Solutions
Organic Chemistry
Ch. 29.1 - Prob. 1PCh. 29.3 - Write the equations for the remaining passages of...Ch. 29.3 - Prob. 3PCh. 29.4 - Write a mechanism for the dehydration reaction of...Ch. 29.4 - Evidence for the role of acetate in fatty-acid...Ch. 29.4 - Does the reduction of acetoacetyl ACP in step 6...Ch. 29.5 - Prob. 7PCh. 29.5 - Look at the entire glycolysis pathway, and make a...Ch. 29.6 - Prob. 9PCh. 29.7 - Prob. 10P
Ch. 29.7 - Write mechanisms for step 2 of the citric acid...Ch. 29.7 - Prob. 12PCh. 29.8 - Prob. 13PCh. 29.9 - Write all the steps in the transamination reaction...Ch. 29.9 - What -keto acid is formed on transamination of...Ch. 29.9 - Prob. 16PCh. 29.SE - Prob. 17VCCh. 29.SE - Identify the following intermediate in the citric...Ch. 29.SE - The following compound is an intermediate in the...Ch. 29.SE - Prob. 20VCCh. 29.SE - In the pentose phosphate pathway for degrading...Ch. 29.SE - Prob. 22MPCh. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - Prob. 25MPCh. 29.SE - Prob. 26MPCh. 29.SE - Prob. 27MPCh. 29.SE - Prob. 28MPCh. 29.SE - Prob. 29MPCh. 29.SE - Prob. 30MPCh. 29.SE - Prob. 31MPCh. 29.SE - Prob. 32APCh. 29.SE - Prob. 33APCh. 29.SE - Prob. 34APCh. 29.SE - Prob. 35APCh. 29.SE - Prob. 36APCh. 29.SE - Prob. 37APCh. 29.SE - Prob. 38APCh. 29.SE - Prob. 39APCh. 29.SE - Prob. 40APCh. 29.SE - Prob. 41APCh. 29.SE - Prob. 42APCh. 29.SE - Prob. 43APCh. 29.SE - Prob. 44APCh. 29.SE - Prob. 45APCh. 29.SE - Prob. 46APCh. 29.SE - Prob. 47APCh. 29.SE - Prob. 48APCh. 29.SE - Prob. 49APCh. 29.SE - Prob. 50APCh. 29.SE - In glycerol metabolism, the oxidation of...Ch. 29.SE - Prob. 52APCh. 29.SE - Prob. 53APCh. 29.SE - Prob. 54APCh. 29.SE - In step 7 of fatty-acid biosynthesis (Figure...Ch. 29.SE - Prob. 56AP
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- What role does molecular oxygen, O2, play in fatty acid biosynthesis?arrow_forwardThe citric acid cycle is also called the tricarboxylic acid cycle (or TCA cycle). Which of the citric acid cycle intermediates are tricarboxylic acids?arrow_forwardIf an animal has 5.000 kg of palmitoyl-CoA available for fatty acid oxidation, how many kilograms of water could the animal produce from that palmitoyl-CoA? The chemical formula for palmitoyl-CoA is C37H66N7O17P3S.arrow_forward
- A portion of the citric acid cycle is shown below. What are the identities of A and B? citrate → A→isocitrate → B A = cis-aconitate; B = a-ketoglutarate A = malate; B = fumarate A = cis-aconitate; B = oxaloacetate A = a-ketoglutarate; B = succinate A = succinate; B = a-ketoglutaratearrow_forwardThere are eight chemical reactions that occur in the citric acid cycle process. The reactions of the citric acid cycle are shown in the figure below. You were introduced to several classes of organic reactions. These classes include esterification, decarboxylation, hydration reactions, dehydration of alcohols, oxidation of alcohols, oxidation of aldehydes, reduction of aldehydes, and reduction of ketones. Find at least one of these reaction classes in the citric acid cycle. List the reaction number and the reaction. Write a sentence or two on how you were able to make the classification.arrow_forwardThe process by which cus fatty acids are converted to trans fatty acids occurs during the hydrolysis process. It arises because a small fraction of the products reform alkenes from a reaction reversal. True or False?arrow_forward
- Calcitriol promotes absorption of calcium in the intestines. What substance, which is produced in the body upon sun exposure, is modified into calcitriol? vitamin D vitamin B6 O ascorbic acid niacinarrow_forwardCalculate the ΔGo’ for the following reaction at 37 oC: Glyceraldehyde 3-phosphate → Dihydroxyacetone phosphate K’eq = 21.05arrow_forwardHow much carbon dioxide is produced from the complete aerobic catabolism of one molecule of linoleate (18:2) via catabolic pathways show full workarrow_forward
- Define acetylcholinesterasearrow_forwardWrite the reaction for the oxidation of ascorbic acid catalyzed by ascorbic acid oxidase.arrow_forwardFatty acids and triglycerides are an important source of nutrition and a dense form of stored energy. Digestion of fats yields more energy per gram than digestion of carbohydrates. Each turn on the B-oxidation spiral results in the formation of a new acetyl COA molecule. This molecule can then be used to generate more energy in A) fatty acid synthesis B) ketolysis C) glycolysis D) tricarboxylic acid cycle E) oxidative phosphorylationarrow_forward
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DIGESTER-35 | VITAMINS AND THEIR RELATED COENZYMES| GPAT | NIPER | PHARMACIST| DI; Author: GPAT DISCUSSION CENTER;https://www.youtube.com/watch?v=CGrdNYmho0s;License: Standard YouTube License, CC-BY