Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Textbook Question
Chapter 29.3, Problem 2P
Write the equations for the remaining passages of the β-oxidation pathway following those shown in Figure 29-4.
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For a given acid HA, it was determined that at pH 6.0 the concentration of the conjugate base [A]
was 0.075 M and the acid [HA] was 0.025 M.
What percent of this acid is ionized at pH 6.0?
What is the pKa of this acid?
What pH would this acid be 50% lonized?
The enzyme that catalyzes reaction below can be classified as:
NAD*
NADH + H*
Но-
H-Ć-
Н—с—н
H-
malate
dehydrogenase
Oxaloacetate
Malate
Describeenergy consumed vs released in reactions. Differentiate between endergonic vs exergonic reactions, anabolism vs catabolism, and coupled reactions.
Chapter 29 Solutions
Organic Chemistry
Ch. 29.1 - Prob. 1PCh. 29.3 - Write the equations for the remaining passages of...Ch. 29.3 - Prob. 3PCh. 29.4 - Write a mechanism for the dehydration reaction of...Ch. 29.4 - Evidence for the role of acetate in fatty-acid...Ch. 29.4 - Does the reduction of acetoacetyl ACP in step 6...Ch. 29.5 - Prob. 7PCh. 29.5 - Look at the entire glycolysis pathway, and make a...Ch. 29.6 - Prob. 9PCh. 29.7 - Prob. 10P
Ch. 29.7 - Write mechanisms for step 2 of the citric acid...Ch. 29.7 - Prob. 12PCh. 29.8 - Prob. 13PCh. 29.9 - Write all the steps in the transamination reaction...Ch. 29.9 - What -keto acid is formed on transamination of...Ch. 29.9 - Prob. 16PCh. 29.SE - Prob. 17VCCh. 29.SE - Identify the following intermediate in the citric...Ch. 29.SE - The following compound is an intermediate in the...Ch. 29.SE - Prob. 20VCCh. 29.SE - In the pentose phosphate pathway for degrading...Ch. 29.SE - Prob. 22MPCh. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - Prob. 25MPCh. 29.SE - Prob. 26MPCh. 29.SE - Prob. 27MPCh. 29.SE - Prob. 28MPCh. 29.SE - Prob. 29MPCh. 29.SE - Prob. 30MPCh. 29.SE - Prob. 31MPCh. 29.SE - Prob. 32APCh. 29.SE - Prob. 33APCh. 29.SE - Prob. 34APCh. 29.SE - Prob. 35APCh. 29.SE - Prob. 36APCh. 29.SE - Prob. 37APCh. 29.SE - Prob. 38APCh. 29.SE - Prob. 39APCh. 29.SE - Prob. 40APCh. 29.SE - Prob. 41APCh. 29.SE - Prob. 42APCh. 29.SE - Prob. 43APCh. 29.SE - Prob. 44APCh. 29.SE - Prob. 45APCh. 29.SE - Prob. 46APCh. 29.SE - Prob. 47APCh. 29.SE - Prob. 48APCh. 29.SE - Prob. 49APCh. 29.SE - Prob. 50APCh. 29.SE - In glycerol metabolism, the oxidation of...Ch. 29.SE - Prob. 52APCh. 29.SE - Prob. 53APCh. 29.SE - Prob. 54APCh. 29.SE - In step 7 of fatty-acid biosynthesis (Figure...Ch. 29.SE - Prob. 56AP
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- The first step of the metabolic process known as glycolysis is the conversion of glucose to glucose- 6-phosphate. This process has a positive value for rG' Glucose + Pi Glucose-6-phosphate + H2O rG' = +13.8 kJ/mol-rxn This reaction is coupled to the hydrolysis of ATP ATP + H2O ADP + Pi rG' = -30.5 kJ/mol-rxn What is the sum of these two equations and the value of rG' for the coupled reaction? Is the coupled reaction product-favored at equilibrium?arrow_forwardATP Synthase in plants has the same basic structure and function as the ATP Synthase in humans. O True O Falsearrow_forwardFor each step of the metabolic pathway shown give the name of the most likely enzyme to catalyse the reaction and state whether it is a Phase 1 or Phase 2 metabolic enzyme. Draw the missing structure. OH ΝΗ HO poolt OH Į -OH 200th"300" OH HO. HO. OH NH₂arrow_forward
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- Which of the following refers to oxidation reaction (O), and which refers to reduction reaction (R)? Further, in each equation circle the oxidized form and box the reduced form. R NAD+ 2H + 2e →NADH+ H+ Fe+2 →Fe+3 gain of electrons FADH2 →→FAD + 2H+ + 2e NADH+H NAD+ 2H + 2e NADP+ 2H* + 2e- →NADPH + H+ loss of electrons FAD+ 2H + 2e FADH2 releases energy NADPH + H+ →→ NADP+ + 2H + 2e¯ Fe+3 →→Fe+2 absorbs energy TAarrow_forwardTo learn more about the role of the electron transport chain in generating energy during respiration in this organism, you use two drugs. These drugs can each pick up electrons from specific intermediates in the pathway as shown above. You treat cells carrying out respiration with either a saturating dose of drug A or B, so that all the electrons which would normally continue along the pathway are captured by the drug in question. Complete the following table. In the presence of drug A, will the rate of ATP synthesis increase, decrease, or stay the same? Explain your reasoning. In the presence of drug B, will the rate of ATP synthesis increase, decrease, or stay the same? Explain your reasoning.arrow_forwardhys 19-58 A food package label lists an oil as “partially hydrogen- ated." What does this mean? will regct with one moleculearrow_forward
- Oxaloacetate + ADP + Pi + H+ ---> Pyruvate + ATP + HCO3- ΔGo’ = 13.91 kJ/mol Lactate + NAD+ ---> Pyruvate + NADH + H+ ΔGo’ = 25.12 kJ/mol Oxaloacetate + GTP ---> Phosphoenolpyruvate + GDP + CO2 ΔGo’ = -28.40 kJ/mol HCO3- + H+ ---> CO2 + H2O ΔGo’ = -41.45 kJ/mol GDP + ATP ---> GTP + ADP ΔGo’ = -0.003 kJ/mol _________________________________________________________________________________________________________________ Lactate + NAD+ + 2ATP + H2O ---> Phosphoenolpyruvate + NADH + 2ADP + Pi + 3H+ From the above information, calculate theΔGo’ for the overall reaction shown…arrow_forwardOxaloacetate + ADP + Pi + H+ ---> Pyruvate + ATP + HCO3- ΔGo’ = 13.91 kJ/mol Lactate + NAD+ ---> Pyruvate + NADH + H+ ΔGo’ = 25.12 kJ/mol Oxaloacetate + GTP ---> Phosphoenolpyruvate + GDP + CO2 ΔGo’ = -28.40 kJ/mol HCO3- + H+ ---> CO2 + H2O ΔGo’ = -41.45 kJ/mol GDP + ATP ---> GTP + ADP ΔGo’ = -0.003 kJ/mol _________________________________________________________________________________________________________________ Lactate + NAD+ + 2ATP + H2O ---> Phosphoenolpyruvate + NADH + 2ADP + Pi + 3H+ From the above information, calculate the Keq’ for the overall reaction shown…arrow_forwardModify the given molecule to show the product of the oxidation reaction using NAD+ as the oxidizing agent. Include the appropriate hydrogen atoms and charges. OH O .lari. -CH₂- NAD+ Select Draw Rings More / ||| ||| C 0 H 44 H 4 Erase +NADH- ho given molecule to show the product of the oxidation reaction using FAD as the oxidizing agent. Include thearrow_forward
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