Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 29.3, Problem 3P
Interpretation Introduction
Interpretation:
To predict the molecules of acetyl CoA are produced by catabolism of the following fatty acids and the pages needed to the β-oxidation pathway.
Concept introduction:
B oxidation of fatty acids degrades the carbon chain as a result of the catabolic breakdown most fatty acids have an even number of carbon atoms, so none, are left over after the β - oxidation it has been found that when → mere is an n-carbon fatty acid chain, the number of acetyl COA molecules obtained as the major end product is n/2 and the number of passages of breakdown is n/2-1 for the given reaction.
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Chapter 29 Solutions
Organic Chemistry
Ch. 29.1 - Prob. 1PCh. 29.3 - Write the equations for the remaining passages of...Ch. 29.3 - Prob. 3PCh. 29.4 - Write a mechanism for the dehydration reaction of...Ch. 29.4 - Evidence for the role of acetate in fatty-acid...Ch. 29.4 - Does the reduction of acetoacetyl ACP in step 6...Ch. 29.5 - Prob. 7PCh. 29.5 - Look at the entire glycolysis pathway, and make a...Ch. 29.6 - Prob. 9PCh. 29.7 - Prob. 10P
Ch. 29.7 - Write mechanisms for step 2 of the citric acid...Ch. 29.7 - Prob. 12PCh. 29.8 - Prob. 13PCh. 29.9 - Write all the steps in the transamination reaction...Ch. 29.9 - What -keto acid is formed on transamination of...Ch. 29.9 - Prob. 16PCh. 29.SE - Prob. 17VCCh. 29.SE - Identify the following intermediate in the citric...Ch. 29.SE - The following compound is an intermediate in the...Ch. 29.SE - Prob. 20VCCh. 29.SE - In the pentose phosphate pathway for degrading...Ch. 29.SE - Prob. 22MPCh. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - Prob. 25MPCh. 29.SE - Prob. 26MPCh. 29.SE - Prob. 27MPCh. 29.SE - Prob. 28MPCh. 29.SE - Prob. 29MPCh. 29.SE - Prob. 30MPCh. 29.SE - Prob. 31MPCh. 29.SE - Prob. 32APCh. 29.SE - Prob. 33APCh. 29.SE - Prob. 34APCh. 29.SE - Prob. 35APCh. 29.SE - Prob. 36APCh. 29.SE - Prob. 37APCh. 29.SE - Prob. 38APCh. 29.SE - Prob. 39APCh. 29.SE - Prob. 40APCh. 29.SE - Prob. 41APCh. 29.SE - Prob. 42APCh. 29.SE - Prob. 43APCh. 29.SE - Prob. 44APCh. 29.SE - Prob. 45APCh. 29.SE - Prob. 46APCh. 29.SE - Prob. 47APCh. 29.SE - Prob. 48APCh. 29.SE - Prob. 49APCh. 29.SE - Prob. 50APCh. 29.SE - In glycerol metabolism, the oxidation of...Ch. 29.SE - Prob. 52APCh. 29.SE - Prob. 53APCh. 29.SE - Prob. 54APCh. 29.SE - In step 7 of fatty-acid biosynthesis (Figure...Ch. 29.SE - Prob. 56AP
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- What role does molecular oxygen, O2, play in fatty acid biosynthesis?arrow_forwardMost fatty acids have an even number of carbons and, therefore, are completely metabolized to acetyl-CoA. A fatty acid with an odd number of carbons is metabolized to acetyl-CoA and one equivalent of propionyl-CoA. The following two reactions convert propionyl-CoA into succinyl-CoA, a citric acid cycle intermediate, so it can be further metabolized. Each of the reactions requires a coenzyme. Identify the coenzyme for each step. From what vitamins are the coenzymes derived?arrow_forwardMost fatty acids have an even number of carbons and, therefore, are completely metabolized to acetyl-CoA. A fatty acid with an odd number of carbons is metabolized to acetyl-CoA and one equivalent of propionyl-CoA. The following two reactions convert propionyl-CoA into succinyl-CoA, a citric acid cycle intermediate, so it can be further metabolized. Each of the reactions requires a coenzyme. Identify the coenzyme for each step. From what vitamins are the coenzymes derived?arrow_forward
- How many molecules of NADH and FADH2 are obtained from the β-oxidation of one molecule of a 16-carbon saturated fatty acyl-CoA?arrow_forwardFatty acids and triglycerides are an important source of nutrition and a dense form of stored energy. Digestion of fats yields more energy per gram than digestion of carbohydrates. Each turn on the B-oxidation spiral results in the formation of a new acetyl COA molecule. This molecule can then be used to generate more energy in A) fatty acid synthesis B) ketolysis C) glycolysis D) tricarboxylic acid cycle E) oxidative phosphorylationarrow_forwardFatty acids cannot be converted into carbohydrates in the body as the following reaction is not possible. (A) Conversion of glucose-6-phosphate into glucose (B) Fructose 1,6-bisphosphate to fructose-6-phosphate O(C) Transformation of acetyl CoA to pyruvate (D) Formation of acetyl CoA from fatty acidsarrow_forward
- What amino acid is obtained from the reductive amination of the following metabolic intermediates in a cell by reductive amination?arrow_forwardA portion of the citric acid cycle is shown below. What are the identities of A and B? citrate → A→isocitrate → B A = cis-aconitate; B = a-ketoglutarate A = malate; B = fumarate A = cis-aconitate; B = oxaloacetate A = a-ketoglutarate; B = succinate A = succinate; B = a-ketoglutaratearrow_forwardStep 7 of the citric acid cycle is shown. Which statement best describes what occurs in this step? CO₂ 1 CH || CH + H₂O CO₂ fumarate CO₂™ fumarase HO C-H CH₂ CO₂ malate A) Fumarate undergoes hydrogenation with hydrogens and electrons provided by the enzyme fumarase. B) Fumarate undergoes hydration with the aid of the enzyme fumarase. C) Fumarate undergoes hydrolysis with the aid of the enzyme fumarase. D) Fumarate undergoes reduction with the aid of the cofactor fumarase.arrow_forward
- One of the steps that occur during the synthesis of ketone bodies is shown below. OH D-beta-hydroxybutyrate Dehydrógenase .coo coo0 H3C cooo Нас acetoacetate D-beta-hydroxybutyrate Does this process require FAD or NAD*, FADH2 or NADH as the reactant coenzyme? Explain your answer in a few words.arrow_forwardHow many molecules of acetyl-CoA are obtained from the beta-oxidation of one molecule of a 16-carbon saturated fatty acyl-CoA?arrow_forwardConsider the docosanoic acid, C21H43CO2H Label the alpha and beta Carbons. Draw each acyl CoA derived from this fatty acid. How many acetyl Co A molecules are formed by complete beta-oxidation? How many cycles of beta-oxidation are needed for complete oxidation? How many molecules of ATP are formed from the complete catabolism of this fatty acid? Show the complete computation. How many moles of ATP per gram of fatty acid is formed from the complete catabolism of the given fatty acid? What is the molar mass of the given fatty acid?arrow_forward
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