Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 21.SE, Problem 68AP
When a
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3) Catalytic hydrogenation of the compound below produced the expected product. However, a
byproduct with molecular formula C10H12O is also formed in small quantities. What is the by product?
What is the ΔHorxn of the reaction?
NaOH(aq) + HCl(aq) → H2O(l) + NaCl(aq)
ΔHorxn 1= ________ kJ/mol
=
+92kJ
ΔΗ
=
+170kJ
Use the following reactions:
2NH3(9) N2(g) + 3H2(g)
→
11/N2(g) + 2H2O (1) → NO2(g) + 2H2(g)
Determine the DH° of this reaction:
NO2(g) + H2(g)
→
2(g) → 2H2O(l) + NH3(9)
ΔΗ
Chapter 21 Solutions
Organic Chemistry
Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3PCh. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6PCh. 21.3 - Prob. 7PCh. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P
Ch. 21.4 - Prob. 11PCh. 21.4 - Prob. 12PCh. 21.4 - Prob. 13PCh. 21.5 - Prob. 14PCh. 21.5 - What product would you expect from reaction of one...Ch. 21.6 - Prob. 16PCh. 21.6 - Prob. 17PCh. 21.6 - Show the products you would obtain by reduction of...Ch. 21.6 - What ester and what Grignard reagent might you...Ch. 21.7 - Prob. 20PCh. 21.7 - How would you use the reaction of an amide with...Ch. 21.8 - Write the mechanism of the reaction shown in...Ch. 21.9 - Prob. 23PCh. 21.9 - Prob. 24PCh. 21.10 - Prob. 25PCh. 21.10 - Prob. 26PCh. 21.SE - Name the following compounds:Ch. 21.SE - Prob. 28VCCh. 21.SE - Prob. 29VCCh. 21.SE - Prob. 30VCCh. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the complete...Ch. 21.SE - Prob. 35MPCh. 21.SE - When 4-dimethylaminopyridine (DMAP) is added in...Ch. 21.SE - Prob. 37MPCh. 21.SE - Prob. 38MPCh. 21.SE - Prob. 39MPCh. 21.SE - The hydrolysis of a biological thioester to the...Ch. 21.SE - Prob. 41MPCh. 21.SE - Prob. 42MPCh. 21.SE - Prob. 43MPCh. 21.SE - In the iodoform reaction, a triiodomethyl ketone...Ch. 21.SE - Give IUPAC names for the following compounds:Ch. 21.SE - Prob. 46APCh. 21.SE - Draw and name compounds that meet the following...Ch. 21.SE - Predict the product, if any, of reaction between...Ch. 21.SE - Prob. 49APCh. 21.SE - Prob. 50APCh. 21.SE - What product would you expect to obtain from...Ch. 21.SE - Prob. 52APCh. 21.SE - Prob. 53APCh. 21.SE - The following reactivity order has been found for...Ch. 21.SE - Prob. 55APCh. 21.SE - Outline methods for the preparation of...Ch. 21.SE - Prob. 57APCh. 21.SE - When ethyl benzoate is heated in methanol...Ch. 21.SE - tert-Butoxycarbonyl azide, a reagent used in...Ch. 21.SE - Prob. 60APCh. 21.SE - Prob. 61APCh. 21.SE - What is the structure of the polymer produced by...Ch. 21.SE - Polyimides with the structure shown are used as...Ch. 21.SE - Prob. 64APCh. 21.SE - Propose a structure for a compound, C4H7ClO2, that...Ch. 21.SE - Assign structures to compounds with the following...Ch. 21.SE - Prob. 67APCh. 21.SE - When a carboxylic acid is dissolved in...Ch. 21.SE - Prob. 69APCh. 21.SE - Prob. 70APCh. 21.SE - Prob. 71APCh. 21.SE - Phenyl 4-aminosalicylate is a drug used in the...Ch. 21.SE - N,N-Diethyl-m-toluamide (DEET) is the active...Ch. 21.SE - Tranexamic acid, a drug useful against blood...Ch. 21.SE - One frequently used method for preparing methyl...Ch. 21.SE - Prob. 76APCh. 21.SE - Assign structures to compounds with the following...Ch. 21.SE - Propose structures for compounds with the...Ch. 21.SE - Propose a structure for the compound with the...Ch. 21.SE - Draw the structure of the compound that produced...Ch. 21.SE - Prob. 81APCh. 21.SE - Epoxy adhesives are prepared in two steps. SN2...
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- Determine the entropy change for the reaction SO2(g) + O2(g) following information: Standard Entropy Values of Various Substance Substance SO2(g) 02(g) SO3(g) So (J/mol K) 248.2 205.0 256.8 → SO3(g) given thearrow_forwardIndicate which one of the following reactions most certainly results in a negative AS sys. O1402(g) + 3NH4NO3 (s) + C10 H22(1) → 3N2(g) + 17H2O(g) + 10CO2(g) ○ CO2(aq) = CO2(g) ○ H₂O(g) = H₂O(s) CaCO3(g) = CaO(s) + CO2(g) O CuSO4.5H2O(s) = CuSO4(s) + 5H2O(g)arrow_forwardEstimate the DH°rxn of the reaction below: H H-C-C=C-H H Н A table of bond energy Bond H Bond Energy (kJ/mol) C-H 413 C-O 360 C=O 743 C-C 348 |C = C 612 O-H 463 H-H 436 + H-H -> H H-C. - H | | 1 HHHarrow_forward
- Show work...don't give Ai generated solutionarrow_forwardGiven the standard enthalpies of formation for the following substances, determine the reaction enthalpy for the following reaction. 3A(g) + 1B (g) 4C (g) + 7D (g) Substance AH in kJ/mol A (g) - 25.07 B (g) - 36.51 C (g) - 90.09 D (g) + 56.11 AHran =?kJarrow_forwardWhat is the change in internal energy (ΔU) when a system is heated with 42.0 J of energy while it does 110.0 J of work?arrow_forward
- Can you help me solve this problem and explain what the answers are?arrow_forwardFor which reaction below does the enthalpy change under standard conditions correspond to a standard enthalpy of formation? (Choose all that applies) SO2(g) + 1/2 O2(g) → SO3(g) 2H2(g) + C(s) → CH4(g) Mg(s) + 1/2 O2(g) → MgO(s) CO(g) + H2O(g) → CO2(g) + H2(g) CO2(g) + H2(g) → CO(g) + H2O(g) 1/2 H2(g) + 1/2 N2(g) + 3/2 O2(g) → HNO3(g) CO2(g) + C(s) 2CO(g) N2(g) + 202(g) → 2NO2(g)arrow_forwardChoose all the molecules with zero standard-enthalpy-of-formation (AH% = 0) Fe(s) FeCl2(s) N2(g) H2O(l) 02(g) C(graphite) K(s) H2O(g)arrow_forward
- 8.5 g of potassium hydroxide (molar mass = 56.1 g/mol) dissolves in 125 g of water and the temperature of the solution increases by 15.58°C. Calculate the AH soln for potassium hydroxide. Assume the specific heat capacity of the solution is 4.2 J.g¨¹.ºC-1. KOH(s) → →K+ K(aq) + OH AH solution = ?kJ/mol (aq)arrow_forwardWhat will be the final temperature of a 8.79 g piece of iron (CP = 25.09 J/(mol · oC)) initially at 25.0oC, if it is supplied with 302.8 J from a stove?arrow_forwardIdentify the set of stoichiometric coefficients that balances the reaction equation for the combustion of the hydrocarbon below: _ C19 H4002 → CO2 + H2Oarrow_forward
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