Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Question
Chapter 21.9, Problem 24P
Interpretation Introduction
Interpretation:
Polyamides and polyesters form by Nucleophilic acyl substitution reactions.
Concept introduction:
When an
In a similar way, the reaction of a
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Chapter 21 Solutions
Organic Chemistry
Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3PCh. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6PCh. 21.3 - Prob. 7PCh. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P
Ch. 21.4 - Prob. 11PCh. 21.4 - Prob. 12PCh. 21.4 - Prob. 13PCh. 21.5 - Prob. 14PCh. 21.5 - What product would you expect from reaction of one...Ch. 21.6 - Prob. 16PCh. 21.6 - Prob. 17PCh. 21.6 - Show the products you would obtain by reduction of...Ch. 21.6 - What ester and what Grignard reagent might you...Ch. 21.7 - Prob. 20PCh. 21.7 - How would you use the reaction of an amide with...Ch. 21.8 - Write the mechanism of the reaction shown in...Ch. 21.9 - Prob. 23PCh. 21.9 - Prob. 24PCh. 21.10 - Prob. 25PCh. 21.10 - Prob. 26PCh. 21.SE - Name the following compounds:Ch. 21.SE - Prob. 28VCCh. 21.SE - Prob. 29VCCh. 21.SE - Prob. 30VCCh. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the complete...Ch. 21.SE - Prob. 35MPCh. 21.SE - When 4-dimethylaminopyridine (DMAP) is added in...Ch. 21.SE - Prob. 37MPCh. 21.SE - Prob. 38MPCh. 21.SE - Prob. 39MPCh. 21.SE - The hydrolysis of a biological thioester to the...Ch. 21.SE - Prob. 41MPCh. 21.SE - Prob. 42MPCh. 21.SE - Prob. 43MPCh. 21.SE - In the iodoform reaction, a triiodomethyl ketone...Ch. 21.SE - Give IUPAC names for the following compounds:Ch. 21.SE - Prob. 46APCh. 21.SE - Draw and name compounds that meet the following...Ch. 21.SE - Predict the product, if any, of reaction between...Ch. 21.SE - Prob. 49APCh. 21.SE - Prob. 50APCh. 21.SE - What product would you expect to obtain from...Ch. 21.SE - Prob. 52APCh. 21.SE - Prob. 53APCh. 21.SE - The following reactivity order has been found for...Ch. 21.SE - Prob. 55APCh. 21.SE - Outline methods for the preparation of...Ch. 21.SE - Prob. 57APCh. 21.SE - When ethyl benzoate is heated in methanol...Ch. 21.SE - tert-Butoxycarbonyl azide, a reagent used in...Ch. 21.SE - Prob. 60APCh. 21.SE - Prob. 61APCh. 21.SE - What is the structure of the polymer produced by...Ch. 21.SE - Polyimides with the structure shown are used as...Ch. 21.SE - Prob. 64APCh. 21.SE - Propose a structure for a compound, C4H7ClO2, that...Ch. 21.SE - Assign structures to compounds with the following...Ch. 21.SE - Prob. 67APCh. 21.SE - When a carboxylic acid is dissolved in...Ch. 21.SE - Prob. 69APCh. 21.SE - Prob. 70APCh. 21.SE - Prob. 71APCh. 21.SE - Phenyl 4-aminosalicylate is a drug used in the...Ch. 21.SE - N,N-Diethyl-m-toluamide (DEET) is the active...Ch. 21.SE - Tranexamic acid, a drug useful against blood...Ch. 21.SE - One frequently used method for preparing methyl...Ch. 21.SE - Prob. 76APCh. 21.SE - Assign structures to compounds with the following...Ch. 21.SE - Propose structures for compounds with the...Ch. 21.SE - Propose a structure for the compound with the...Ch. 21.SE - Draw the structure of the compound that produced...Ch. 21.SE - Prob. 81APCh. 21.SE - Epoxy adhesives are prepared in two steps. SN2...
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- Glyptal® resin makes a strong, solid polymer matrix for electronic parts. Glyptal is made from terephthalic acid and glycerol. Draw the structure of Glyptal, and explain its remarkable strength and rigidity.arrow_forwardNomex®, a strong fire-resistant fabric, is a polyamide made from meta-phthalic acid and meta-diaminobenzene. Draw the structure of Nomex.arrow_forwardPoly(lactic acid) (PLA) has received much recent attention because the lactic acid monomer [CH3CH(OH)COOH] from which it is made can be obtained from carbohydrates rather than petroleum. This makes PLA a more “environmentally friendly” polyester. (A more in-depth discussion of green polymer synthesis is presented in Chapter 30.) Draw the structure of PLA.arrow_forward
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- In addition to glycolic and lactic acids (Section 31.6B), dissolving sutures can also be prepared from each of the following lactone monomers. Draw the structure of the polymer formed from each monomer. a. polycaprolactone b. polydioxanone E-caprolactone p-dioxanonearrow_forwardDraw out the basic repeating unit of sodium alginate polymer.arrow_forwardA thermosetting material called polyester is made when a carboxylic acid reacts with dialcohol. Write the condensation polymerization with byproduct. The monomers of carboxylic acid and dialcohol are respectively: HO-C -C-OH HO-CH,CH,-OHarrow_forward
- What is polymer? and polymerize lactic acidarrow_forwardThe plastic known as PETE (polyethyleneterephthalate) is used to make plastic soft drink bottles and containers for salad dressing, shampoos, and dishwashing liquids. PETE is a polymer of terephthalic acid and ethylene glycol. Today, PETE is the most widely recycled of all the plastics. After it is separated from other plastics, PETE can be used in polyester fabric, door mats, and tennis ball containers. In 2015, 1.84×109 lb1.84×109 lb of PETE bottles were recycled in the U.S. The density of PETE is 1.38 g/mLg/mL. What volume, in liters, of PETE bottles were recycled in 2015 in the U.S.? Express your answer to three significant figures.arrow_forwardThe plastic known as PETE (polyethyleneterephthalate) is used to make plastic soft drink bottles and containers for salad dressing, shampoos, and dishwashing liquids. PETE is a polymer of terephthalic acid and ethylene glycol. Today, PETE is the most widely recycled of all the plastics. After it is separated from other plastics, PETE can be used in polyester fabric, door mats, and tennis ball containers. In 2015, 1.84×109 lb1.84×109 lb of PETE bottles were recycled in the U.S. The density of PETE is 1.38 g/mLg/mL. Suppose a landfill holds 2.6×107 L2.6×107 L of recycled PETE. If all the PETE bottles recycled in 2015 in the U.S. were placed instead in landfills, how many landfills would be needed? Express your answer as an integer.arrow_forward
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