Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Textbook Question
Chapter 21.SE, Problem 47AP
Draw and name compounds that meet the following descriptions:
(a) Three acid chlorides having the formula C6H9ClO
(b) Three amides having the formula C7H11NO
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Draw structural formulas for each of the following:
(a) The four primary (1°) amines with the molecular formula C4H11N.
(b) The three secondary (2°) amines with the molecular formula C4H11N.
(c) The one tertiary (3°) amine with the molecular formula C4H11N.
Draw and name compounds that meet these descriptions:(a) Three different amides with the formula C5H11NO(b) Three different esters with the formula C6H12O2
five different benzenoid compounds with molecular formula C9H11NO2 which illustrate the functional groups: (i) alcohol (ii) amine (iii) ester (iv) phenol (v) amide
Chapter 21 Solutions
Organic Chemistry
Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3PCh. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6PCh. 21.3 - Prob. 7PCh. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P
Ch. 21.4 - Prob. 11PCh. 21.4 - Prob. 12PCh. 21.4 - Prob. 13PCh. 21.5 - Prob. 14PCh. 21.5 - What product would you expect from reaction of one...Ch. 21.6 - Prob. 16PCh. 21.6 - Prob. 17PCh. 21.6 - Show the products you would obtain by reduction of...Ch. 21.6 - What ester and what Grignard reagent might you...Ch. 21.7 - Prob. 20PCh. 21.7 - How would you use the reaction of an amide with...Ch. 21.8 - Write the mechanism of the reaction shown in...Ch. 21.9 - Prob. 23PCh. 21.9 - Prob. 24PCh. 21.10 - Prob. 25PCh. 21.10 - Prob. 26PCh. 21.SE - Name the following compounds:Ch. 21.SE - Prob. 28VCCh. 21.SE - Prob. 29VCCh. 21.SE - Prob. 30VCCh. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the mechanism...Ch. 21.SE - Predict the product(s) and provide the complete...Ch. 21.SE - Prob. 35MPCh. 21.SE - When 4-dimethylaminopyridine (DMAP) is added in...Ch. 21.SE - Prob. 37MPCh. 21.SE - Prob. 38MPCh. 21.SE - Prob. 39MPCh. 21.SE - The hydrolysis of a biological thioester to the...Ch. 21.SE - Prob. 41MPCh. 21.SE - Prob. 42MPCh. 21.SE - Prob. 43MPCh. 21.SE - In the iodoform reaction, a triiodomethyl ketone...Ch. 21.SE - Give IUPAC names for the following compounds:Ch. 21.SE - Prob. 46APCh. 21.SE - Draw and name compounds that meet the following...Ch. 21.SE - Predict the product, if any, of reaction between...Ch. 21.SE - Prob. 49APCh. 21.SE - Prob. 50APCh. 21.SE - What product would you expect to obtain from...Ch. 21.SE - Prob. 52APCh. 21.SE - Prob. 53APCh. 21.SE - The following reactivity order has been found for...Ch. 21.SE - Prob. 55APCh. 21.SE - Outline methods for the preparation of...Ch. 21.SE - Prob. 57APCh. 21.SE - When ethyl benzoate is heated in methanol...Ch. 21.SE - tert-Butoxycarbonyl azide, a reagent used in...Ch. 21.SE - Prob. 60APCh. 21.SE - Prob. 61APCh. 21.SE - What is the structure of the polymer produced by...Ch. 21.SE - Polyimides with the structure shown are used as...Ch. 21.SE - Prob. 64APCh. 21.SE - Propose a structure for a compound, C4H7ClO2, that...Ch. 21.SE - Assign structures to compounds with the following...Ch. 21.SE - Prob. 67APCh. 21.SE - When a carboxylic acid is dissolved in...Ch. 21.SE - Prob. 69APCh. 21.SE - Prob. 70APCh. 21.SE - Prob. 71APCh. 21.SE - Phenyl 4-aminosalicylate is a drug used in the...Ch. 21.SE - N,N-Diethyl-m-toluamide (DEET) is the active...Ch. 21.SE - Tranexamic acid, a drug useful against blood...Ch. 21.SE - One frequently used method for preparing methyl...Ch. 21.SE - Prob. 76APCh. 21.SE - Assign structures to compounds with the following...Ch. 21.SE - Propose structures for compounds with the...Ch. 21.SE - Propose a structure for the compound with the...Ch. 21.SE - Draw the structure of the compound that produced...Ch. 21.SE - Prob. 81APCh. 21.SE - Epoxy adhesives are prepared in two steps. SN2...
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- TRUE OR FALSE (a) There are three amines with the molecular formula C3H9N. (b) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (c) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (d) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (e) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (f) The molecular formula of the smallest carboxylic acid is C2H4O2.arrow_forwardGive the chemical tests to distinguish between the following pairs of compounds :(i) Ethyl amine and Aniline(ii) Aniline and Benzylaminearrow_forwardPropose structures for amines that fit these descriptions:(a) A secondary amine with formula C5H13N(b) A tertiary amine with formula C6H13N(c) A cyclic quaternary amine that has the formula C6H14N+arrow_forward
- (a) Compound Z is a tertiary aromatic amine with the formula, C8H11N. Provide a chemical structure for compound Z. (b)nDraw the structure of the product formed exclusively when nitrous acid reacts with Z.arrow_forwardClassify each compound (a)–(f) as one of the following: (i) amide, (ii) ester, or(iii) carboxylic acid. (a) CH3COOCH3 (b) RCONHR (c) C6H5COOHarrow_forward3. Draw structures for the following: (a) an acid and an ester having the formula C 2 H 4O 2 (b) 2-alkenes having the formula C 5H 10 (3 isomers) (c) 1° amines having the formula C 4 H 11 N (4 isomers)arrow_forward
- (a) Draw the structures for the eight constitutional isomers of molecular formula C 4H 11N. (b) Give the systematic name for each amine. (c) Identify the chirality center present in one of the amines.arrow_forward(b) Draw the structural formula for each of the following compounds. Lukiskan formula struktur bagi setiap sebatian berikut. (i) 2-iodo-4-methylpentan-3-amine (ii) 1,1-dibromo-2-chloro-2-methylbutane (iii) 2-ethyl-6-fluorophenolarrow_forwardWrite down the distinguishing features among the following: (a) primary,secondary,tertiary Alcohols (b)primary, secondary, tertiary amines (c) carboxylic acid,ester and amide (d)Alkenes Alkynesarrow_forward
- Draw structures corresponding to the following names:(a) 2,2,3-Trifluorobutanoic acid(b) 3-Hydroxybutanoic acid(c) 3,3-Dimethyl-4-phenylpentanoic acidarrow_forwardQ21arrow_forwardIdentify which of the statements is/are correct. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic acid is C2H4O2.arrow_forward
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