The mechanism of the reaction given is to be shown. Concept introduction: The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation To show: The mechanism of the reaction given.

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Chapter 21.SE, Problem 37MP

Interpretation Introduction

Interpretation:

The mechanism of the reaction given is to be shown.

Concept introduction:

The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation

To show:

The mechanism of the reaction given.

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5)A certain aerobic organism is able to metabolize the followingglycolipid CH,OH H H OH H HO OH A.Draw the 2 resulting structures that would occur upon initial hydrolysis of the O-glycosidic bond.

rivatives: Nucleophilic Acyl Substitution Reactions - EOC O C-O [References] One step in the gluconeogenesis pathway for the biosynthesis of glucose is the partial reduction of 3-phosphoglycerate to give glyceraldehyde 3-phosphate. The process occurs by phosphorylation with ATP to give 1,3-bisphosphoglycerate, reaction with a thiol group on the enzyme to give an enzyme-bound thioester, and reduction with NADH. H-C-OH ATP ADP CH₂OPO32- 3-phosphoglycerate 0= OPO32- C H-C-OH CH₂OPO32 1,3-bisphosphoglycerate Enz-SH PO43- O= C S-Enz H-C-OH CH₂OPO3² (Enzyme-bound thioester) NADH/H+ O=C NAD*, Enz-SH H H-C-OH CH₂OPO3²- glyceraldehyde 3-phosphate Propose a structure for the first intermediate in the reaction of the enzyme-bound thioester with NADH to form glyceraldehyde 3-phosphate. To simplify the drawing process, substitute the structure below for the enzyme-bound thioester. S-CH3 substitute for the CH2CH3 enzyme-bound thioester You do not have to consider stereochemistry. • You do not have…

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Answer 2

Question

Chapter 21.SE, Problem 37MP

Interpretation Introduction

Interpretation:

The mechanism of the reaction given is to be shown.

Concept introduction:

The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation

To show:

The mechanism of the reaction given.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Chapter 21.SE, Problem 37MP

Interpretation Introduction

Interpretation:

The mechanism of the reaction given is to be shown.

Concept introduction:

The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation

To show:

The mechanism of the reaction given.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 21.SE, Problem 37MP

Interpretation Introduction

Interpretation:

The mechanism of the reaction given is to be shown.

Concept introduction:

The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation

To show:

The mechanism of the reaction given.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 21.SE, Problem 37MP

Interpretation Introduction

Interpretation:

The mechanism of the reaction given is to be shown.

Concept introduction:

The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation

To show:

The mechanism of the reaction given.

Answer 6

Chapter 21.SE, Problem 37MP

Interpretation Introduction

Interpretation:

The mechanism of the reaction given is to be shown.

Concept introduction:

The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation

To show:

The mechanism of the reaction given.

Answer 7

Chapter 21.SE, Problem 37MP

Interpretation Introduction

Interpretation:

The mechanism of the reaction given is to be shown.

Concept introduction:

The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation

To show:

The mechanism of the reaction given.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

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Answer 11

Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3P Ch. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6P Ch. 21.3 - Prob. 7P Ch. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P

The mechanism of the reaction given is to be shown. Concept introduction: The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation To show: The mechanism of the reaction given.

Solution Summary: The author explains the steps involved in the reaction, including nucleophilic attack, loss of –SCoA, and deprotonation.

Concept explainers

Interpretation:

The mechanism of the reaction given is to be shown.

Concept introduction:

The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation

To show:

The mechanism of the reaction given.

Want to see the full answer?

Chapter 21 Solutions

The mechanism of the reaction given is to be shown. Concept introduction: The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation To show: The mechanism of the reaction given.

Solution Summary: The author explains the steps involved in the reaction, including nucleophilic attack, loss of –SCoA, and deprotonation.

Concept explainers

Interpretation: The mechanism of the reaction given is to be shown. Concept introduction: The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation To show: The mechanism of the reaction given.

Want to see the full answer?

Chapter 21 Solutions

Interpretation:

The mechanism of the reaction given is to be shown.

Concept introduction:

The steps involved in the reaction are i) Nucleophilic attack of a nucleophile on fatty-acyl CoA ii) Loss of â€“SCoA iii) Deprotonation

To show:

The mechanism of the reaction given.