Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
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Textbook Question
Chapter 21, Problem 21.45AP
What does it mean when we say that two reactions are coupled?
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When AG > 0, the reaction is BOTH product-favored (spontaneous) AND exergonic.
When AG > 0, the reaction is BOTH reactant-favored (nonspontaneous) AND exergonic.
When AG < 0, the reaction is BOTH reactant-favored (nonspontaneous) AND exergonic.
What do the following indicators tell you about whether a reaction can proceed as written? (a) The standard free-energy change is positive. (b) The free-energy change is positive. (c) The reaction is exergonic
Chapter 21 Solutions
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
Ch. 21.1 - In a cell, glucose can be oxidized via metabolic...Ch. 21.1 - Prob. 21.2KCPCh. 21.1 - Prob. 21.1CIAPCh. 21.1 - Prob. 21.2CIAPCh. 21.1 - Prob. 21.3CIAPCh. 21.1 - Prob. 21.4CIAPCh. 21.3 - Prob. 21.3PCh. 21.4 - Prob. 21.4PCh. 21.4 - Prob. 21.5PCh. 21.4 - Prob. 21.5CIAP
Ch. 21.4 - How does a cell disarm each of the ROS in CIA...Ch. 21.5 - One of the steps in lipid metabolism is the...Ch. 21.5 - Prob. 21.7PCh. 21.5 - Prob. 21.7CIAPCh. 21.5 - Prob. 21.8CIAPCh. 21.5 - Prob. 21.9CIAPCh. 21.5 - Prob. 21.10CIAPCh. 21.5 - Prob. 21.8PCh. 21.6 - Prob. 21.9PCh. 21.6 - Prob. 21.10PCh. 21.7 - Prob. 21.11PCh. 21.7 - Prob. 21.13PCh. 21.7 - Identify the participants in the citric acid cycle...Ch. 21.7 - Prob. 21.15PCh. 21.7 - Prob. 21.16KCPCh. 21.8 - Within the mitochondrion, is the pH higher in the...Ch. 21.8 - Prob. 21.18PCh. 21.8 - Prob. 21.19KCPCh. 21.8 - Prob. 21.11CIAPCh. 21.8 - Prob. 21.12CIAPCh. 21.8 - Prob. 21.13CIAPCh. 21 - Prob. 21.20UKCCh. 21 - Each of these reactions is involved in one of the...Ch. 21 - Prob. 21.22UKCCh. 21 - Prob. 21.23UKCCh. 21 - The reaction that follows is catalyzed by...Ch. 21 - Prob. 21.25UKCCh. 21 - The electron-transport chain uses several...Ch. 21 - Prob. 21.27APCh. 21 - What is the difference between an endergonic...Ch. 21 - Prob. 21.29APCh. 21 - Prob. 21.30APCh. 21 - Prob. 21.31APCh. 21 - Prob. 21.32APCh. 21 - Which of the following organisms are prokaryotes,...Ch. 21 - Label each of the following as a characteristic of...Ch. 21 - Prob. 21.35APCh. 21 - Prob. 21.36APCh. 21 - Describe in general terms the structural makeup of...Ch. 21 - Prob. 21.38APCh. 21 - Prob. 21.39APCh. 21 - Prob. 21.40APCh. 21 - Prob. 21.41APCh. 21 - Prob. 21.42APCh. 21 - Prob. 21.43APCh. 21 - Prob. 21.44APCh. 21 - What does it mean when we say that two reactions...Ch. 21 - Prob. 21.46APCh. 21 - Prob. 21.47APCh. 21 - Prob. 21.48APCh. 21 - Prob. 21.49APCh. 21 - Prob. 21.50APCh. 21 - Prob. 21.51APCh. 21 - Prob. 21.52APCh. 21 - Prob. 21.53APCh. 21 - Prob. 21.54APCh. 21 - Prob. 21.55APCh. 21 - Prob. 21.56APCh. 21 - Prob. 21.57APCh. 21 - Prob. 21.58APCh. 21 - Prob. 21.59APCh. 21 - Prob. 21.60APCh. 21 - Prob. 21.61APCh. 21 - Prob. 21.62APCh. 21 - Prob. 21.63APCh. 21 - Prob. 21.64APCh. 21 - Prob. 21.65APCh. 21 - Prob. 21.66APCh. 21 - Prob. 21.67APCh. 21 - Prob. 21.68APCh. 21 - What does the term oxidative phosphorylation mean?...Ch. 21 - Prob. 21.70APCh. 21 - Prob. 21.71APCh. 21 - Prob. 21.72APCh. 21 - Prob. 21.73APCh. 21 - Prob. 21.74APCh. 21 - Prob. 21.75APCh. 21 - Prob. 21.76APCh. 21 - Prob. 21.77CPCh. 21 - Fumarate produced in step 6 of the citric acid...Ch. 21 - With what class of enzymes are the coenzymes NAD+...Ch. 21 - Prob. 21.80CPCh. 21 - Prob. 21.81CPCh. 21 - Prob. 21.82CPCh. 21 - The mitochondrion pumps H+ from the matrix into...Ch. 21 - Prob. 21.84CPCh. 21 - Prob. 21.85CPCh. 21 - Prob. 21.86CPCh. 21 - Prob. 21.87GPCh. 21 - Prob. 21.88GPCh. 21 - Prob. 21.89GP
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- What are the Determinants of Reaction Rates?arrow_forwardWhy do we refer to the conversion of six molecules of carbon dioxide (six carbon atoms) to one molecule of glucose (also six carbon atoms) as a net reaction?arrow_forwardGive an example of each Irreversible and Reversible Reactions?arrow_forward
- An enzyme has a single active site at which it can bind and hydrolyze either X or Y; however, the enzyme cannot bind X and Y at the same time. Answer the following questions regarding the Km and Vmax of this enzyme. (a) Will the Km for X be affected if Y is present in the reaction mixture? Explain. (b) Will Vmax for X be affected if Y is present in the reaction mixture? Explain. (a) No, X competes with Y for binding, so the apparent Km for X will stay the same. (b) Yes, the Vmax for X will decrease in the presence of Y. (a) No, Y does not compete with X for binding, so the apparent Km for X will stay the same. (b) No, the Vmax for X will be unaffected by the presence of Y.arrow_forwardHow do endergonic and exergonic reactions differ?arrow_forwardFor the following reactions, name both the enzyme that catalyzes the reaction and the required coenzyme:arrow_forward
- What is an example of an anabolic reaction? An catabolic reaction? An endergonic reaction? An exergonic reaction?arrow_forwardAn exergonic reaction has which of the following properties? A) The △G is negative and the reaction is spontaneous. B) The △G is negative and the reaction is non-spontaneous. C) The △G is positive and the reaction is spontaneous.arrow_forwarda) What is the Steady State assumption; how does steady state differ from equilibrium? b) Transition state; what are two ways that enzymes can decrease the transition state energy?arrow_forward
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