(a)
Interpretation:
The expected ground-state electron configuration of
Concept Introduction:
The fundamental principles that are followed to write an electronic configuration include three rules as follows:
Electron in a
Hund’s rule suggests electrons are not allowed to be paired up until each degenerate set of orbital has got at least one electron.
Pauli Exclusion Principle states two electrons within the same orbital cannot possess same set for four possible quantum numbers.
In
The convention followed to remove or add electrons is electrons of largest principal quantum number are lost first. In case of subshells of the same
(b)
Interpretation:
The expected ground-state electron configuration of
Concept Introduction:
Refer to part (a).
(c)
Interpretation:
The expected ground-state electron configuration of
Concept Introduction:
Refer to part (a).
(d)
Interpretation:
The ground-state electronic configuration of
Concept Introduction:
Refer to part (a).

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Chapter 2 Solutions
ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
- (c) (4pts) Mechanism: heat (E1) CH3OH + 1.5pts each _E1 _ (1pt) Br CH3OH (d) (4pts) Mechanism: SN1 (1pt) (e) (3pts) 1111 I H 10 Ill!! H LDA THF (solvent) Mechanism: E2 (1pt) NC (f) Bri!!!!! CH3 NaCN (3pts) acetone Mechanism: SN2 (1pt) (SN1) -OCH3 OCH3 1.5pts each 2pts for either product 1pt if incorrect stereochemistry H Br (g) “,、 (3pts) H CH3OH +21 Mechanism: SN2 (1pt) H CH3 2pts 1pt if incorrect stereochemistry H 2pts 1pt if incorrect stereochemistryarrow_forwardA mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixturearrow_forwardQ5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R Harrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
