The classification of the given monosaccharide as an aldose or ketose has to be predicted. Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Question

Q2: Ranking Acidity a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly explain the ranking. Use Table 2.2 as reference. Ha Нь HC H-N Ha OHe b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is more acidic? Explain. (Hint: use resonance structures to help) Name the functional groups on atenolol. H H-N atenolol Ν H-N OH Н

Answer 1

Question

Chapter 18, Problem 18.51EP

(a)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(b)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(c)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(d)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

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Q2: Ranking Acidity a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly explain the ranking. Use Table 2.2 as reference. Ha Нь HC H-N Ha OHe b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is more acidic? Explain. (Hint: use resonance structures to help) Name the functional groups on atenolol. H H-N atenolol Ν H-N OH Н

Answer d, e, and f

If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1

Answer 2

Question

Chapter 18, Problem 18.51EP

(a)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(b)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(c)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(d)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

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Answer 3

Question

Chapter 18, Problem 18.51EP

(a)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(b)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(c)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(d)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

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Answer 4

Question

Chapter 18, Problem 18.51EP

(a)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(b)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(c)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(d)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

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Answer 5

Chapter 18, Problem 18.51EP

(a)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(b)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(c)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

(d)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Answer 6

Chapter 18, Problem 18.51EP

(a)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Answer 7

Chapter 18, Problem 18.51EP

(a)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Answer 8

(b)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Answer 9

(b)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Answer 10

(c)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Answer 11

(c)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Answer 12

(d)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Answer 13

(d)

Interpretation Introduction

Interpretation: The classification of the given monosaccharide as an aldose or ketose has to be predicted.

Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Answer 14

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Answer 25

Ch. 18.1 - In terms of mass percent, which of the following...Ch. 18.1 - Which of the following is the most abundant type...Ch. 18.2 - Which of the following statements concerning the...Ch. 18.2 - Prob. 2QQ Ch. 18.3 - Prob. 1QQ Ch. 18.3 - Prob. 2QQ Ch. 18.3 - Which of the following is not a possible value for...Ch. 18.3 - The complete hydrolysis of a polysaccharide...Ch. 18.4 - Prob. 1QQ Ch. 18.4 - Prob. 2QQ

The classification of the given monosaccharide as an aldose or ketose has to be predicted. Concept introduction: Monosaccharide is categorized into two types: aldoses and ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Solution Summary: The author explains the classification of the given monosaccharide as an aldose or ketose has to be predicted.

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Chapter 18 Solutions