General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Chapter 18, Problem 18.14EP
Interpretation Introduction
Interpretation: The meaning for the term non-superimposable has to be stated.
Concept introduction: To understand the molecules, the concept of mirror images was introduced. The reflection formed by an object is called its mirror image. The mirror images can be of two types, superimposable mirror images and non-superimposable mirror images.
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Propose syntheses of the following compounds starting with benzene or toluene. Assume ortho and
isomers can be separated.
a.
b.
O₂N-
Cl
COOH
para
0. Propose syntheses to carry out each of the following conversions. Assume ortho and para isomers can
be separated
a.
Br
b.
COOH
CH3
NH₂
PABA
(active ingredient in some sunscreens)
H3C
H
C=C
CH3
H
m-chloroperoxybenzoic acid
CH2Cl2, rt
C-C--.
H3CH2CC
H
H3C CH3
Cl₂
H₂O
NaOH
H₂O
D.
S-
E.
CH3
H₂O₂, H₂O
It
CH₂O Na
+
CHI
F.
HI, H₂O
heat
G.
4
OH
CH3CHCH3 + ICH2CH3
1. NaH
(CH3)3COH
(CH3)3 COCHCH2CH3
2.
CH3
5. Show how the ether below could be prepared from toluene and any other necessary reagents. Show all
reagents and all intermediate structures.
H3C-
H3C-
CI
OCH2CH3
Chapter 18 Solutions
General, Organic, and Biological Chemistry
Ch. 18.1 - In terms of mass percent, which of the following...Ch. 18.1 - Which of the following is the most abundant type...Ch. 18.2 - Which of the following statements concerning the...Ch. 18.2 - Prob. 2QQCh. 18.3 - Prob. 1QQCh. 18.3 - Prob. 2QQCh. 18.3 - Which of the following is not a possible value for...Ch. 18.3 - The complete hydrolysis of a polysaccharide...Ch. 18.4 - Prob. 1QQCh. 18.4 - Prob. 2QQ
Ch. 18.4 - Prob. 3QQCh. 18.4 - Prob. 4QQCh. 18.5 - Prob. 1QQCh. 18.5 - Prob. 2QQCh. 18.6 - Prob. 1QQCh. 18.6 - Which of the following Fischer projection formulas...Ch. 18.6 - Prob. 3QQCh. 18.6 - Prob. 4QQCh. 18.7 - Prob. 1QQCh. 18.7 - Prob. 2QQCh. 18.8 - Prob. 1QQCh. 18.8 - Which of the following statements about...Ch. 18.8 - The smallest monosaccharides that can exist are a....Ch. 18.9 - Prob. 1QQCh. 18.9 - Prob. 2QQCh. 18.9 - Prob. 3QQCh. 18.9 - In which of the following pairs of monosaccharides...Ch. 18.9 - In which of the following pairs of monosaccharides...Ch. 18.10 - Prob. 1QQCh. 18.10 - Which of the following structures represents a...Ch. 18.10 - Prob. 3QQCh. 18.10 - Prob. 4QQCh. 18.10 - Prob. 5QQCh. 18.11 - Prob. 1QQCh. 18.11 - Which of the following is the correct Haworth...Ch. 18.12 - Prob. 1QQCh. 18.12 - Prob. 2QQCh. 18.12 - Prob. 3QQCh. 18.12 - Prob. 4QQCh. 18.12 - Prob. 5QQCh. 18.13 - Which of the following disaccharides contains...Ch. 18.13 - Which of the following disaccharides will produce...Ch. 18.13 - In which of the following disaccharides is the...Ch. 18.13 - In which of the following pairs of disaccharides...Ch. 18.13 - Which of the following disaccharides is not a...Ch. 18.13 - The terms milk sugar and table sugar apply,...Ch. 18.14 - Prob. 1QQCh. 18.14 - Prob. 2QQCh. 18.15 - Which of the following statements about...Ch. 18.15 - Prob. 2QQCh. 18.16 - Prob. 1QQCh. 18.16 - Which of the following storage polysaccharides is...Ch. 18.16 - Prob. 3QQCh. 18.16 - Which of the following statements about storage...Ch. 18.17 - Prob. 1QQCh. 18.17 - Which of the following statements about cellulose...Ch. 18.17 - Chitin is a polysaccharide in which the...Ch. 18.18 - Which of the following statements about the...Ch. 18.18 - Prob. 2QQCh. 18.19 - Which of the following is not classified as a...Ch. 18.19 - Prob. 2QQCh. 18.20 - Prob. 1QQCh. 18.20 - Which of the following is not a biochemical...Ch. 18 - Prob. 18.1EPCh. 18 - Prob. 18.2EPCh. 18 - Prob. 18.3EPCh. 18 - Prob. 18.4EPCh. 18 - Prob. 18.5EPCh. 18 - Prob. 18.6EPCh. 18 - Prob. 18.7EPCh. 18 - Prob. 18.8EPCh. 18 - Prob. 18.9EPCh. 18 - Prob. 18.10EPCh. 18 - Prob. 18.11EPCh. 18 - Prob. 18.12EPCh. 18 - Prob. 18.13EPCh. 18 - Prob. 18.14EPCh. 18 - Prob. 18.15EPCh. 18 - Prob. 18.16EPCh. 18 - Prob. 18.17EPCh. 18 - Prob. 18.18EPCh. 18 - Prob. 18.19EPCh. 18 - Prob. 18.20EPCh. 18 - Prob. 18.21EPCh. 18 - Prob. 18.22EPCh. 18 - Prob. 18.23EPCh. 18 - Prob. 18.24EPCh. 18 - Prob. 18.25EPCh. 18 - Prob. 18.26EPCh. 18 - Prob. 18.27EPCh. 18 - Prob. 18.28EPCh. 18 - Prob. 18.29EPCh. 18 - Prob. 18.30EPCh. 18 - Prob. 18.31EPCh. 18 - Prob. 18.32EPCh. 18 - Prob. 18.33EPCh. 18 - Prob. 18.34EPCh. 18 - Draw the Fischer projection formula for each of...Ch. 18 - Prob. 18.36EPCh. 18 - Prob. 18.37EPCh. 18 - Prob. 18.38EPCh. 18 - Prob. 18.39EPCh. 18 - Prob. 18.40EPCh. 18 - Prob. 18.41EPCh. 18 - Prob. 18.42EPCh. 18 - Prob. 18.43EPCh. 18 - Prob. 18.44EPCh. 18 - Prob. 18.45EPCh. 18 - Prob. 18.46EPCh. 18 - Prob. 18.47EPCh. 18 - Prob. 18.48EPCh. 18 - Prob. 18.49EPCh. 18 - Prob. 18.50EPCh. 18 - Prob. 18.51EPCh. 18 - Prob. 18.52EPCh. 18 - Prob. 18.53EPCh. 18 - Prob. 18.54EPCh. 18 - Prob. 18.55EPCh. 18 - Prob. 18.56EPCh. 18 - Prob. 18.57EPCh. 18 - Prob. 18.58EPCh. 18 - Prob. 18.59EPCh. 18 - Prob. 18.60EPCh. 18 - Prob. 18.61EPCh. 18 - Prob. 18.62EPCh. 18 - Prob. 18.63EPCh. 18 - Prob. 18.64EPCh. 18 - Prob. 18.65EPCh. 18 - Prob. 18.66EPCh. 18 - Prob. 18.67EPCh. 18 - Prob. 18.68EPCh. 18 - Prob. 18.69EPCh. 18 - Prob. 18.70EPCh. 18 - Prob. 18.71EPCh. 18 - Prob. 18.72EPCh. 18 - Prob. 18.73EPCh. 18 - Prob. 18.74EPCh. 18 - Prob. 18.75EPCh. 18 - Prob. 18.76EPCh. 18 - Prob. 18.77EPCh. 18 - Prob. 18.78EPCh. 18 - Prob. 18.79EPCh. 18 - Prob. 18.80EPCh. 18 - Prob. 18.81EPCh. 18 - Prob. 18.82EPCh. 18 - Prob. 18.83EPCh. 18 - Prob. 18.84EPCh. 18 - Prob. 18.85EPCh. 18 - Prob. 18.86EPCh. 18 - Prob. 18.87EPCh. 18 - Prob. 18.88EPCh. 18 - Prob. 18.89EPCh. 18 - Prob. 18.90EPCh. 18 - Prob. 18.91EPCh. 18 - Prob. 18.92EPCh. 18 - Prob. 18.93EPCh. 18 - Prob. 18.94EPCh. 18 - Prob. 18.95EPCh. 18 - Prob. 18.96EPCh. 18 - Prob. 18.97EPCh. 18 - Prob. 18.98EPCh. 18 - Prob. 18.99EPCh. 18 - Prob. 18.100EPCh. 18 - Prob. 18.101EPCh. 18 - Prob. 18.102EPCh. 18 - Prob. 18.103EPCh. 18 - Prob. 18.104EPCh. 18 - For each structure in Problem 18-103, identify the...Ch. 18 - For each structure in Problem 18-104, identify the...Ch. 18 - Prob. 18.107EPCh. 18 - Prob. 18.108EPCh. 18 - Prob. 18.109EPCh. 18 - Prob. 18.110EPCh. 18 - Prob. 18.111EPCh. 18 - Prob. 18.112EPCh. 18 - Prob. 18.113EPCh. 18 - Prob. 18.114EPCh. 18 - Prob. 18.115EPCh. 18 - Prob. 18.116EPCh. 18 - Prob. 18.117EPCh. 18 - Prob. 18.118EPCh. 18 - Prob. 18.119EPCh. 18 - Prob. 18.120EPCh. 18 - Prob. 18.121EPCh. 18 - Prob. 18.122EPCh. 18 - Prob. 18.123EPCh. 18 - Prob. 18.124EPCh. 18 - Prob. 18.125EPCh. 18 - Prob. 18.126EPCh. 18 - Prob. 18.127EPCh. 18 - Prob. 18.128EPCh. 18 - Prob. 18.129EPCh. 18 - Prob. 18.130EPCh. 18 - Prob. 18.131EPCh. 18 - Prob. 18.132EPCh. 18 - Prob. 18.133EPCh. 18 - Prob. 18.134EPCh. 18 - Prob. 18.135EPCh. 18 - Prob. 18.136EPCh. 18 - Prob. 18.137EPCh. 18 - Prob. 18.138EPCh. 18 - Prob. 18.139EPCh. 18 - Prob. 18.140EPCh. 18 - Prob. 18.141EPCh. 18 - Prob. 18.142EPCh. 18 - Prob. 18.143EPCh. 18 - Prob. 18.144EPCh. 18 - Prob. 18.145EPCh. 18 - Prob. 18.146EPCh. 18 - Prob. 18.147EPCh. 18 - Prob. 18.148EPCh. 18 - Prob. 18.149EPCh. 18 - Prob. 18.150EPCh. 18 - Prob. 18.151EPCh. 18 - Prob. 18.152EPCh. 18 - Prob. 18.153EPCh. 18 - Prob. 18.154EPCh. 18 - Prob. 18.155EPCh. 18 - Prob. 18.156EPCh. 18 - Prob. 18.157EPCh. 18 - Prob. 18.158EPCh. 18 - Prob. 18.159EPCh. 18 - Prob. 18.160EPCh. 18 - Prob. 18.161EPCh. 18 - Prob. 18.162EPCh. 18 - Prob. 18.163EPCh. 18 - Prob. 18.164EPCh. 18 - Prob. 18.165EPCh. 18 - Prob. 18.166EPCh. 18 - Prob. 18.167EPCh. 18 - Prob. 18.168EPCh. 18 - Prob. 18.169EPCh. 18 - Prob. 18.170EPCh. 18 - Describe the general features of the cell...Ch. 18 - Prob. 18.172EP
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