The number of anomeric carbon atoms that are present in the given cyclic form of D − glucose has to be stated. Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon. Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

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Answer 1

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Chapter 18, Problem 18.71EP

(a)

Interpretation Introduction

Interpretation: The number of anomeric carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

(b)

Interpretation Introduction

Interpretation: The number of hemiacetal carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Answer 2

Question

Chapter 18, Problem 18.71EP

(a)

Interpretation Introduction

Interpretation: The number of anomeric carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

(b)

Interpretation Introduction

Interpretation: The number of hemiacetal carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

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Answer 3

Question

Chapter 18, Problem 18.71EP

(a)

Interpretation Introduction

Interpretation: The number of anomeric carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

(b)

Interpretation Introduction

Interpretation: The number of hemiacetal carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

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Answer 4

Question

Chapter 18, Problem 18.71EP

(a)

Interpretation Introduction

Interpretation: The number of anomeric carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

(b)

Interpretation Introduction

Interpretation: The number of hemiacetal carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

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Answer 5

Chapter 18, Problem 18.71EP

(a)

Interpretation Introduction

Interpretation: The number of anomeric carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

(b)

Interpretation Introduction

Interpretation: The number of hemiacetal carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

Answer 6

Chapter 18, Problem 18.71EP

(a)

Interpretation Introduction

Interpretation: The number of anomeric carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

Answer 7

Chapter 18, Problem 18.71EP

(a)

Interpretation Introduction

Interpretation: The number of anomeric carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

Answer 8

(b)

Interpretation Introduction

Interpretation: The number of hemiacetal carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

Answer 9

(b)

Interpretation Introduction

Interpretation: The number of hemiacetal carbon atoms that are present in the given cyclic form of D−glucose has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide.

A compound that possesses a carbon atom which is attached with a hydroxyl group as well as with an alkoxy group is known as hemiacetal compound. This carbon atom that is attached with both hydroxyl group and alkoxy group is known as hemiacetal carbon.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.

Answer 10

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Answer 12

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Answer 13

Ch. 18.1 - In terms of mass percent, which of the following...Ch. 18.1 - Which of the following is the most abundant type...Ch. 18.2 - Which of the following statements concerning the...Ch. 18.2 - Prob. 2QQ Ch. 18.3 - Prob. 1QQ Ch. 18.3 - Prob. 2QQ Ch. 18.3 - Which of the following is not a possible value for...Ch. 18.3 - The complete hydrolysis of a polysaccharide...Ch. 18.4 - Prob. 1QQ Ch. 18.4 - Prob. 2QQ

Solution Summary: The author explains the simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. The number of anomeric carbon atoms that are present in the given cyclic form of

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