General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Question
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Chapter 18, Problem 18.63EP

(a)

Interpretation Introduction

Interpretation: The Fischer projection formula for Dglucose has to be drawn.

Concept introduction: The Fischer formula can be drawn by using the following rules.

  • Ø The chiral center is assumed to be in the plane of paper.
  • Ø Two of the bonds are considered pointing towards the page.
  • Ø Two of the bonds are considered pointing outwards of the page.
  • Ø The intersection of horizontal and vertical lines represents the chiral centre.
  • Ø The horizontal lines are the lines pointing outwards of the page.
  • Ø The vertical lines are the lines pointing towards the page.

(a)

Expert Solution
Check Mark

Answer to Problem 18.63EP

The Fischer projection formula for Dglucose is,

General, Organic, and Biological Chemistry, Chapter 18, Problem 18.63EP , additional homework tip  1

Explanation of Solution

The given molecule is Dglucose.  The molecular formula of Dglucose is C6H12O6.  The Fisher projection Dglucose is shown as,

General, Organic, and Biological Chemistry, Chapter 18, Problem 18.63EP , additional homework tip  2

The monosaccharide, Dglucose contains a backbone of six carbon atoms with an aldehyde as a functional group.

(b)

Interpretation Introduction

Interpretation: The Fischer projection formula for Dglyceraldehyde has to be drawn.

Concept introduction: The Fischer formula can be drawn by using the following rules.

  • Ø The chiral center is assumed to be in the plane of paper.
  • Ø Two of the bonds are considered pointing towards the page.
  • Ø Two of the bonds are considered pointing outwards of the page.
  • Ø The intersection of horizontal and vertical lines represents the chiral center.
  • Ø The horizontal lines are the lines pointing outwards of the page.
  • Ø The vertical lines are the lines pointing towards the page.

(b)

Expert Solution
Check Mark

Answer to Problem 18.63EP

The Fischer projection formula for Dglyceraldehyde is,

General, Organic, and Biological Chemistry, Chapter 18, Problem 18.63EP , additional homework tip  3

Explanation of Solution

The given molecule is Dglyceraldehyde.  The molecular formula of Dglyceraldehyde is C3H6O3.  The Fisher projection Dglyceraldehyde is shown as,

General, Organic, and Biological Chemistry, Chapter 18, Problem 18.63EP , additional homework tip  4

The monosaccharide, Dglyceraldehyde contains a backbone of three carbon atoms with an aldehyde as a functional group.

(c)

Interpretation Introduction

Interpretation: The Fischer projection formula for Dfructose has to be drawn.

Concept introduction: The Fischer formula can be drawn by using the following rules.

  • Ø The chiral center is assumed to be in the plane of paper.
  • Ø Two of the bonds are considered pointing towards the page.
  • Ø Two of the bonds are considered pointing outwards of the page.
  • Ø The intersection of horizontal and vertical lines represents the chiral center.
  • Ø The horizontal lines are the lines pointing outwards of the page.
  • Ø The vertical lines are the lines pointing towards the page.

(c)

Expert Solution
Check Mark

Answer to Problem 18.63EP

The Fischer projection formula for Dfructose is,

General, Organic, and Biological Chemistry, Chapter 18, Problem 18.63EP , additional homework tip  5

Explanation of Solution

The given molecule is Dfructose.  The molecular formula of Dfructose is C6H12O6.  The Fisher projection Dfructose is shown as,

General, Organic, and Biological Chemistry, Chapter 18, Problem 18.63EP , additional homework tip  6

The monosaccharide, Dfructose contains a backbone of six carbon atoms with a ketone as a functional group.

(d)

Interpretation Introduction

Interpretation: The Fischer projection formula for Lgalactose to be drawn.

Concept introduction: The Fischer formula can be drawn by using the following rules.

  • Ø The chiral center is assumed to be in the plane of paper.
  • Ø Two of the bonds are considered pointing towards the page.
  • Ø Two of the bonds are considered pointing outwards of the page.
  • Ø The intersection of horizontal and vertical lines represents the chiral center.
  • Ø The horizontal lines are the lines pointing outwards of the page.
  • Ø The vertical lines are the lines pointing towards the page.

(d)

Expert Solution
Check Mark

Answer to Problem 18.63EP

The Fischer projection formula for Lgalactose is,

General, Organic, and Biological Chemistry, Chapter 18, Problem 18.63EP , additional homework tip  7

Explanation of Solution

The given molecule is Lgalactose.  The molecular formula of Lgalactose is C6H12O6.  The Fisher projection Lgalactose is shown as,

General, Organic, and Biological Chemistry, Chapter 18, Problem 18.63EP , additional homework tip  8

The monosaccharide, Lgalactose contains a backbone of six carbon atoms with an aldehyde as a functional group.

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Chapter 18 Solutions

General, Organic, and Biological Chemistry

Ch. 18.4 - Prob. 3QQCh. 18.4 - Prob. 4QQCh. 18.5 - Prob. 1QQCh. 18.5 - Prob. 2QQCh. 18.6 - Prob. 1QQCh. 18.6 - Which of the following Fischer projection formulas...Ch. 18.6 - Prob. 3QQCh. 18.6 - Prob. 4QQCh. 18.7 - Prob. 1QQCh. 18.7 - Prob. 2QQCh. 18.8 - Prob. 1QQCh. 18.8 - Which of the following statements about...Ch. 18.8 - The smallest monosaccharides that can exist are a....Ch. 18.9 - Prob. 1QQCh. 18.9 - Prob. 2QQCh. 18.9 - Prob. 3QQCh. 18.9 - In which of the following pairs of monosaccharides...Ch. 18.9 - In which of the following pairs of monosaccharides...Ch. 18.10 - Prob. 1QQCh. 18.10 - Which of the following structures represents a...Ch. 18.10 - Prob. 3QQCh. 18.10 - Prob. 4QQCh. 18.10 - Prob. 5QQCh. 18.11 - Prob. 1QQCh. 18.11 - Which of the following is the correct Haworth...Ch. 18.12 - Prob. 1QQCh. 18.12 - Prob. 2QQCh. 18.12 - Prob. 3QQCh. 18.12 - Prob. 4QQCh. 18.12 - Prob. 5QQCh. 18.13 - Which of the following disaccharides contains...Ch. 18.13 - Which of the following disaccharides will produce...Ch. 18.13 - In which of the following disaccharides is the...Ch. 18.13 - In which of the following pairs of disaccharides...Ch. 18.13 - Which of the following disaccharides is not a...Ch. 18.13 - The terms milk sugar and table sugar apply,...Ch. 18.14 - Prob. 1QQCh. 18.14 - Prob. 2QQCh. 18.15 - Which of the following statements about...Ch. 18.15 - Prob. 2QQCh. 18.16 - Prob. 1QQCh. 18.16 - Which of the following storage polysaccharides is...Ch. 18.16 - Prob. 3QQCh. 18.16 - Which of the following statements about storage...Ch. 18.17 - Prob. 1QQCh. 18.17 - Which of the following statements about cellulose...Ch. 18.17 - Chitin is a polysaccharide in which the...Ch. 18.18 - Which of the following statements about the...Ch. 18.18 - Prob. 2QQCh. 18.19 - Which of the following is not classified as a...Ch. 18.19 - Prob. 2QQCh. 18.20 - Prob. 1QQCh. 18.20 - Which of the following is not a biochemical...Ch. 18 - Prob. 18.1EPCh. 18 - Prob. 18.2EPCh. 18 - Prob. 18.3EPCh. 18 - Prob. 18.4EPCh. 18 - Prob. 18.5EPCh. 18 - Prob. 18.6EPCh. 18 - Prob. 18.7EPCh. 18 - Prob. 18.8EPCh. 18 - Prob. 18.9EPCh. 18 - Prob. 18.10EPCh. 18 - Prob. 18.11EPCh. 18 - Prob. 18.12EPCh. 18 - Prob. 18.13EPCh. 18 - Prob. 18.14EPCh. 18 - Prob. 18.15EPCh. 18 - Prob. 18.16EPCh. 18 - Prob. 18.17EPCh. 18 - Prob. 18.18EPCh. 18 - Prob. 18.19EPCh. 18 - Prob. 18.20EPCh. 18 - Prob. 18.21EPCh. 18 - Prob. 18.22EPCh. 18 - Prob. 18.23EPCh. 18 - Prob. 18.24EPCh. 18 - Prob. 18.25EPCh. 18 - Prob. 18.26EPCh. 18 - Prob. 18.27EPCh. 18 - Prob. 18.28EPCh. 18 - Prob. 18.29EPCh. 18 - Prob. 18.30EPCh. 18 - Prob. 18.31EPCh. 18 - Prob. 18.32EPCh. 18 - Prob. 18.33EPCh. 18 - Prob. 18.34EPCh. 18 - Draw the Fischer projection formula for each of...Ch. 18 - Prob. 18.36EPCh. 18 - Prob. 18.37EPCh. 18 - Prob. 18.38EPCh. 18 - Prob. 18.39EPCh. 18 - Prob. 18.40EPCh. 18 - Prob. 18.41EPCh. 18 - Prob. 18.42EPCh. 18 - Prob. 18.43EPCh. 18 - Prob. 18.44EPCh. 18 - Prob. 18.45EPCh. 18 - Prob. 18.46EPCh. 18 - Prob. 18.47EPCh. 18 - Prob. 18.48EPCh. 18 - Prob. 18.49EPCh. 18 - Prob. 18.50EPCh. 18 - Prob. 18.51EPCh. 18 - Prob. 18.52EPCh. 18 - Prob. 18.53EPCh. 18 - Prob. 18.54EPCh. 18 - Prob. 18.55EPCh. 18 - Prob. 18.56EPCh. 18 - Prob. 18.57EPCh. 18 - Prob. 18.58EPCh. 18 - Prob. 18.59EPCh. 18 - Prob. 18.60EPCh. 18 - Prob. 18.61EPCh. 18 - Prob. 18.62EPCh. 18 - Prob. 18.63EPCh. 18 - Prob. 18.64EPCh. 18 - Prob. 18.65EPCh. 18 - Prob. 18.66EPCh. 18 - Prob. 18.67EPCh. 18 - Prob. 18.68EPCh. 18 - Prob. 18.69EPCh. 18 - Prob. 18.70EPCh. 18 - Prob. 18.71EPCh. 18 - Prob. 18.72EPCh. 18 - Prob. 18.73EPCh. 18 - Prob. 18.74EPCh. 18 - Prob. 18.75EPCh. 18 - Prob. 18.76EPCh. 18 - Prob. 18.77EPCh. 18 - Prob. 18.78EPCh. 18 - Prob. 18.79EPCh. 18 - Prob. 18.80EPCh. 18 - Prob. 18.81EPCh. 18 - Prob. 18.82EPCh. 18 - Prob. 18.83EPCh. 18 - Prob. 18.84EPCh. 18 - Prob. 18.85EPCh. 18 - Prob. 18.86EPCh. 18 - Prob. 18.87EPCh. 18 - Prob. 18.88EPCh. 18 - Prob. 18.89EPCh. 18 - Prob. 18.90EPCh. 18 - Prob. 18.91EPCh. 18 - Prob. 18.92EPCh. 18 - Prob. 18.93EPCh. 18 - Prob. 18.94EPCh. 18 - Prob. 18.95EPCh. 18 - Prob. 18.96EPCh. 18 - Prob. 18.97EPCh. 18 - Prob. 18.98EPCh. 18 - Prob. 18.99EPCh. 18 - Prob. 18.100EPCh. 18 - Prob. 18.101EPCh. 18 - Prob. 18.102EPCh. 18 - Prob. 18.103EPCh. 18 - Prob. 18.104EPCh. 18 - For each structure in Problem 18-103, identify the...Ch. 18 - For each structure in Problem 18-104, identify the...Ch. 18 - Prob. 18.107EPCh. 18 - Prob. 18.108EPCh. 18 - Prob. 18.109EPCh. 18 - Prob. 18.110EPCh. 18 - Prob. 18.111EPCh. 18 - Prob. 18.112EPCh. 18 - Prob. 18.113EPCh. 18 - Prob. 18.114EPCh. 18 - Prob. 18.115EPCh. 18 - Prob. 18.116EPCh. 18 - Prob. 18.117EPCh. 18 - Prob. 18.118EPCh. 18 - Prob. 18.119EPCh. 18 - Prob. 18.120EPCh. 18 - Prob. 18.121EPCh. 18 - Prob. 18.122EPCh. 18 - Prob. 18.123EPCh. 18 - Prob. 18.124EPCh. 18 - Prob. 18.125EPCh. 18 - Prob. 18.126EPCh. 18 - Prob. 18.127EPCh. 18 - Prob. 18.128EPCh. 18 - Prob. 18.129EPCh. 18 - Prob. 18.130EPCh. 18 - Prob. 18.131EPCh. 18 - Prob. 18.132EPCh. 18 - Prob. 18.133EPCh. 18 - Prob. 18.134EPCh. 18 - Prob. 18.135EPCh. 18 - Prob. 18.136EPCh. 18 - Prob. 18.137EPCh. 18 - Prob. 18.138EPCh. 18 - Prob. 18.139EPCh. 18 - Prob. 18.140EPCh. 18 - Prob. 18.141EPCh. 18 - Prob. 18.142EPCh. 18 - Prob. 18.143EPCh. 18 - Prob. 18.144EPCh. 18 - Prob. 18.145EPCh. 18 - Prob. 18.146EPCh. 18 - Prob. 18.147EPCh. 18 - Prob. 18.148EPCh. 18 - Prob. 18.149EPCh. 18 - Prob. 18.150EPCh. 18 - Prob. 18.151EPCh. 18 - Prob. 18.152EPCh. 18 - Prob. 18.153EPCh. 18 - Prob. 18.154EPCh. 18 - Prob. 18.155EPCh. 18 - Prob. 18.156EPCh. 18 - Prob. 18.157EPCh. 18 - Prob. 18.158EPCh. 18 - Prob. 18.159EPCh. 18 - Prob. 18.160EPCh. 18 - Prob. 18.161EPCh. 18 - Prob. 18.162EPCh. 18 - Prob. 18.163EPCh. 18 - Prob. 18.164EPCh. 18 - Prob. 18.165EPCh. 18 - Prob. 18.166EPCh. 18 - Prob. 18.167EPCh. 18 - Prob. 18.168EPCh. 18 - Prob. 18.169EPCh. 18 - Prob. 18.170EPCh. 18 - Describe the general features of the cell...Ch. 18 - Prob. 18.172EP
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