Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 16.5, Problem 23P
(a)
Interpretation Introduction
Interpretation:
A method has to be suggested for the preparation of the given compound from N-benzylbenzamide.
(b)
Interpretation Introduction
Interpretation:
A method has to be suggested for the preparation of the given compound from N-benzylbenzamide.
(c)
Interpretation Introduction
Interpretation:
A method has to be suggested for the preparation of the given compound from N-benzylbenzamide.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
What reagents would you use to convert methyl propanoate to the following compounds? a. isopropyl propanoate b. sodium propanoate c. N-ethylpropanamide d. propanoic acid
Esters and amides are most easily made by nucleophilic acyl substitution reactions on…
A. alcohols
B. acid chlorides
C. acid anhydrides
D. carboxylates
E. carboxylic acids
What are the products of the following reactions? (A trace amount of acid is present in each case.)
a. cyclopentanone + ethylamine c. acetophenone + hexylamine
b. cyclopentanone + diethylamine d. acetophenone + cyclohexylamine
Chapter 16 Solutions
Organic Chemistry (8th Edition)
Ch. 16.1 - Give two names for each of the following:Ch. 16.1 - Prob. 2PCh. 16.1 - Name the following:Ch. 16.2 - Prob. 4PCh. 16.4 - What products are formed when the following...Ch. 16.4 - We saw on the previous page that...Ch. 16.4 - a. How many stereoisomers are obtained from the...Ch. 16.4 - Prob. 9PCh. 16.4 - Write the mechanism for the reaction of acetyl...Ch. 16.4 - Prob. 11P
Ch. 16.4 - Show how the following compounds can be...Ch. 16.4 - Prob. 13PCh. 16.4 - Prob. 14PCh. 16.4 - In the mechanism for cyanohydrin formation, why is...Ch. 16.4 - Prob. 16PCh. 16.4 - Prob. 17PCh. 16.4 - Show two ways to convert an alkyl halide into a...Ch. 16.5 - Prob. 20PCh. 16.5 - Prob. 21PCh. 16.5 - Prob. 22PCh. 16.5 - Prob. 23PCh. 16.6 - Prob. 24PCh. 16.7 - What reducing agents should be used to obtain the...Ch. 16.7 - Prob. 26PCh. 16.8 - Prob. 27PCh. 16.8 - Prob. 28PCh. 16.8 - Prob. 29PCh. 16.8 - The pKa of protonated acetone is about 7.5. and...Ch. 16.8 - Prob. 31PCh. 16.8 - Prob. 32PCh. 16.8 - Prob. 33PCh. 16.8 - Excess ammonia must be used when a primary amine...Ch. 16.8 - The compounds commonly known as amino acids are...Ch. 16.9 - Hydration of an aldehyde is also catalyzed by...Ch. 16.9 - Which ketone forms the most hydrate in an aqueous...Ch. 16.9 - When trichloroacetaldehyde is dissolved in water,...Ch. 16.9 - Which of the following are a. hermiacetals? b....Ch. 16.9 - Prob. 40PCh. 16.9 - Explain why an acetal can be isolated but most...Ch. 16.10 - Prob. 42PCh. 16.10 - Prob. 43PCh. 16.10 - What products would be formed from the proceedings...Ch. 16.10 - a. In a six-step synthesis, what is the yield of...Ch. 16.10 - Show how each of the following compounds could be...Ch. 16.12 - Prob. 47PCh. 16.13 - Prob. 49PCh. 16.14 - Prob. 50PCh. 16.15 - Prob. 51PCh. 16.16 - Prob. 52PCh. 16 - Draw the structure for each of the following: a....Ch. 16 - Prob. 54PCh. 16 - Prob. 55PCh. 16 - Prob. 56PCh. 16 - a. Show the reagents required to form the primary...Ch. 16 - Prob. 58PCh. 16 - Prob. 59PCh. 16 - Using cyclohexanone as the starting material,...Ch. 16 - Propose a mechanism for each of the following...Ch. 16 - Show how each of the following compounds can be...Ch. 16 - Fill in the boxes:Ch. 16 - Prob. 64PCh. 16 - Identify A through O:Ch. 16 - Prob. 66PCh. 16 - Prob. 67PCh. 16 - Prob. 68PCh. 16 - How many signals would the product of the...Ch. 16 - Prob. 70PCh. 16 - Prob. 71PCh. 16 - Prob. 72PCh. 16 - Prob. 73PCh. 16 - Prob. 74PCh. 16 - Prob. 75PCh. 16 - Prob. 76PCh. 16 - Prob. 77PCh. 16 - Prob. 78PCh. 16 - Draw structure for A-D for each of the following:Ch. 16 - Prob. 80PCh. 16 - a. Propose a mechanism for the following reaction:...Ch. 16 - Prob. 82PCh. 16 - A compound gives the following IR spectrum. Upon...Ch. 16 - How can be following compounds be prepared from...Ch. 16 - Prob. 85PCh. 16 - Prob. 86PCh. 16 - Prob. 87PCh. 16 - In the presence of an acid catalyst, acetaldehyde...Ch. 16 - Prob. 89PCh. 16 - Prob. 90PCh. 16 - Prob. 91PCh. 16 - A compound reacts with methylmagnesium bromide...Ch. 16 - Show how each of the following compounds can be...Ch. 16 - Prob. 94PCh. 16 - The pKa values of the carboxylic acid groups of...Ch. 16 - The Baylis-Hillman reaction is a DABCO...Ch. 16 - Prob. 97PCh. 16 - Prob. 98P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Given that your mixture containing benzoic acid and aminobenzene dissolved in n-hexane solvent. Suggest a method on how to separate these two substances. Available reagents: A. Hydrochloric acid B. Sodium hydroxide C. Distilled water D. n-hexanearrow_forwardInstructions: DRAW a structure corresponding to each name a. 3-hexanamine b. N-methylpentylamine c. p-nitroaniline d. N-methylpiperidine e. N,N-dimethylethylamine f. 2-aminocyclohexanone g. 1-propylcyclohexanamine h. N-propylanilinearrow_forwardHow would you make the following compounds from N-benzylbenzamide? a. dibenzylamine b. benzoic acid c. benzyl alcoholarrow_forward
- Which of the following products could you not create using malonic acid ethyl ester as a starting material? A. diethyl-2,2-dialkylmalonate B. maleic acid C. Carboxylic acid D. 2,2-dialkylmalonic acid E. diethyl 2-alkyl malonatearrow_forwardHow would you separate butanoic acid and 1-butanamine by an extraction procedure ?arrow_forwardInstructions: Give an acceptable name for eachester. A. CH, CH2)CO,CH, B. COCHỊCH, C. CH₂CH₂CH₂CH₂COOCH₂CH₂CH₂ Instructions: Give the structure corresponding to each name. a. propyl propanoate b. butyl acetate c. ethyl hexanoate d. methyl benzoate Instructions: Give an acceptable name for each amide A. CH₂CH₂CH₂CH₂ NH₂ Instructions: Draw the structure of each amide. A. N,N-dimethylacetamidearrow_forward
- How would you synthesize triphenylmethanol starting from the following class of compound? Draw the structure of the starting compound and list the other reagent(s) used for the reaction. a. Ester b. Ketone c. Aldehyde eduction dd H IT More "0" Oxidiz strong leak Reduarrow_forwardDraw a structure corresponding to each name. a. 2,4-dimethyl-3-hexanamine b. N-methylpentylamine c. N-isopropyl-p-nitroaniline d. N-methylpiperidine e. N,N-dimethylethylamine f. 2-aminocyclohexanone g. N-methylaniline h. m-ethylanilinearrow_forwardWhich is False a.Reaction of an anhydride with an amine will produce an amide b.Reaction of carboxylic acid with an acid chloride in the presence of a base will produce an anhydride c.Reaction of an alcohol with an amide will produce an ester d.Reaction of carboxylic acid with thionyl chloride will produce an acyl chloridearrow_forward
- Describe the reaction when a. Formaldehyde mixed with a fainty pink solution of potassium permanganate with a few drops of sulfuric acid. b. Acetaldehyde mixed with a fainty pink solution of potassium permanganate with a few drops of sulfuric acid. c. Benzaldehyde mixed with a fainty pink solution of potassium permanganate with a few drops of sulfuric acid.arrow_forwardQUESTION 1 Which of the following compounds has an activating group? A. Benzoic acid B. None in the answer C. Bromobenzene D. Diphenylamine QUESTION 2 Which of the following compounds has a deactivating group attached to the benzene ring? A. Toluene B. Acetanilide C. Phenol D. Salicyclic Acidarrow_forwardTyramine is an alkaloid found in mistletoe and ripe cheese. Dopamine is a neurotransmitter involved in the regulation of the central nervous system. a. How can tyramine be prepared from β-phenylethylamine?b. How can dopamine be prepared from tyramine?c. Give two ways to prepare β-phenylethylamine from β-phenylethyl chloride.d. How can β-phenylethylamine be prepared from benzyl chloride?e. How can β-phenylethylamine be prepared from benzaldehyde?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning