(a) Interpretation: The structure of the compound is to be drawn with the help of details obtained through the NMR spectra. Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compounds. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy. The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton lesser will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

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Answer 1

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Chapter 16, Problem 16.7P

Interpretation Introduction

(a)

Interpretation:

The structure of the compound is to be drawn with the help of details obtained through the NMR spectra.

Concept introduction:

NMR spectroscopy is a technique used to determine a unique structure of the compounds. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton lesser will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Interpretation Introduction

(b)

Interpretation:

The structure of the compound is to be given with the help of details obtained through the NMR spectra.

Concept introduction:

Many nuclei and electrons have spin; due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field.

In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. The chemical shift value depended upon its surrounded protons. Tetramethylsilane is taken as reference. Also, the spacing between split lines of NMR spectra is known as coupling constant.

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Propose a structure for each of the following two isomers with formula C6H14 given their 1H-NMR spectra. Isomer A: δ = 0.84 (d, 12 H), 1.39 (septet, 2H) ppm Isomer B: δ = 0.84 (t, 3 H), 0.86 (t, 9H), 1.22 (q, 2H) ppm

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Set #1: CHCHCHCH, CHOCHSCHICHI CHCHCHCHCH a b C Shown are 4 isomeric structures with the formula C5H100. Which isomer shows 3 peaks in its ¹³C-NMR spectrum, none of which is very far downfield? Set #2: CH3CH₂CH₂CCH3 CH3CH₂CH₂CH₂CH CH₂=CHCH₂CH₂CH₂OH b C a Shown are 4 isomeric structures with the formula C5H100. Which isomer shows 3 peaks in both its ¹H and 13C NMR spectra? -OH

Answer 2

Question

Chapter 16, Problem 16.7P

Interpretation Introduction

(a)

Interpretation:

The structure of the compound is to be drawn with the help of details obtained through the NMR spectra.

Concept introduction:

NMR spectroscopy is a technique used to determine a unique structure of the compounds. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton lesser will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Interpretation Introduction

(b)

Interpretation:

The structure of the compound is to be given with the help of details obtained through the NMR spectra.

Concept introduction:

Many nuclei and electrons have spin; due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field.

In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. The chemical shift value depended upon its surrounded protons. Tetramethylsilane is taken as reference. Also, the spacing between split lines of NMR spectra is known as coupling constant.

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Answer 3

Question

Chapter 16, Problem 16.7P

Interpretation Introduction

(a)

Interpretation:

The structure of the compound is to be drawn with the help of details obtained through the NMR spectra.

Concept introduction:

NMR spectroscopy is a technique used to determine a unique structure of the compounds. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton lesser will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Interpretation Introduction

(b)

Interpretation:

The structure of the compound is to be given with the help of details obtained through the NMR spectra.

Concept introduction:

Many nuclei and electrons have spin; due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field.

In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. The chemical shift value depended upon its surrounded protons. Tetramethylsilane is taken as reference. Also, the spacing between split lines of NMR spectra is known as coupling constant.

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Answer 4

Question

Chapter 16, Problem 16.7P

Interpretation Introduction

(a)

Interpretation:

The structure of the compound is to be drawn with the help of details obtained through the NMR spectra.

Concept introduction:

NMR spectroscopy is a technique used to determine a unique structure of the compounds. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton lesser will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Interpretation Introduction

(b)

Interpretation:

The structure of the compound is to be given with the help of details obtained through the NMR spectra.

Concept introduction:

Many nuclei and electrons have spin; due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field.

In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. The chemical shift value depended upon its surrounded protons. Tetramethylsilane is taken as reference. Also, the spacing between split lines of NMR spectra is known as coupling constant.

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Answer 5

Chapter 16, Problem 16.7P

Interpretation Introduction

(a)

Interpretation:

The structure of the compound is to be drawn with the help of details obtained through the NMR spectra.

Concept introduction:

NMR spectroscopy is a technique used to determine a unique structure of the compounds. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton lesser will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Interpretation Introduction

(b)

Interpretation:

The structure of the compound is to be given with the help of details obtained through the NMR spectra.

Concept introduction:

Many nuclei and electrons have spin; due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field.

In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. The chemical shift value depended upon its surrounded protons. Tetramethylsilane is taken as reference. Also, the spacing between split lines of NMR spectra is known as coupling constant.

Answer 6

Chapter 16, Problem 16.7P

Interpretation Introduction

(a)

Interpretation:

The structure of the compound is to be drawn with the help of details obtained through the NMR spectra.

Concept introduction:

NMR spectroscopy is a technique used to determine a unique structure of the compounds. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton lesser will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Answer 7

Chapter 16, Problem 16.7P

Interpretation Introduction

(a)

Interpretation:

The structure of the compound is to be drawn with the help of details obtained through the NMR spectra.

Concept introduction:

NMR spectroscopy is a technique used to determine a unique structure of the compounds. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton lesser will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of the compound is to be given with the help of details obtained through the NMR spectra.

Concept introduction:

Many nuclei and electrons have spin; due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field.

In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. The chemical shift value depended upon its surrounded protons. Tetramethylsilane is taken as reference. Also, the spacing between split lines of NMR spectra is known as coupling constant.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of the compound is to be given with the help of details obtained through the NMR spectra.

Concept introduction:

Many nuclei and electrons have spin; due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field.

In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. The chemical shift value depended upon its surrounded protons. Tetramethylsilane is taken as reference. Also, the spacing between split lines of NMR spectra is known as coupling constant.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains how NMR spectroscopy determines the carbon-hydrogen bonding of an organic compound.

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