(a) Interpretation: The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated. Concept introduction: The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

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Answer 1

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Draw a tripeptide of your choosing at pH 7. Have the N-terminus on the left and the C-terminus on the right. Then: Draw a triangle around the α-carbons. Draw a box around the R-groups. Circle the atoms capable of hydrogen bonding. Highlight the atoms involved in the formation of the peptide bonds. What type of structure have you drawn? (primary, secondary, tertiary or quaternary protein structure). make sure its a tripeptide

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Answer 2

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Answer 3

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Answer 4

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Answer 5

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Answer 6

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 7

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Answer 10

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Answer 13

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author analyzes the ranking of compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction.

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