Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 16, Problem 16.30P
Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of mbromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of mbromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©
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Chapter 16 Solutions

Organic Chemistry Study Guide and Solutions

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