Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
Question
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Chapter 16, Problem 16.23P
Interpretation Introduction

(a)

Interpretation:

The directing effect of the phenyl group in the given question is to be stated.

Concept introduction:

The reaction between acyl chloride with benzene in presence of AlCl3 is a friedal craft acylation reaction. In friedal craft acylation reaction, AlCl3 acts as a lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Interpretation Introduction

(b)

Interpretation:

The explanation of the directing effect of the phenyl group is to be stated.

Concept introduction:

The reaction between acyl chloride with benzene in presence of AlCl3 is a friedal craft acylation reaction. In friedal craft acylation reaction, AlCl3 acts as a lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Chapter 16 Solutions

Organic Chemistry Study Guide and Solutions

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