Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 16, Problem 16.51AP
Interpretation Introduction

Interpretation:

The reason for the fact that the value λmax values and intensities of the UV absorption of styrene (PhCH=CH2) and phenylacetylene (PhCCH) are almost identical despite of the fact that phenylacetylene contains an additional π bond is to be stated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. Molecules have bonding or non-bonding electrons that can absorb light while promoting electrons from the ground state to an excited state. The light absorbed is usually in the UV or visible region. Conjugation in the molecule also affects the wavelength of light absorbed.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Chapter 16 Solutions

Organic Chemistry Study Guide and Solutions

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