Biochemistry
9th Edition
ISBN: 9781305961135
Author: Mary K. Campbell, Shawn O. Farrell, Owen M. McDougal
Publisher: Cengage Learning
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Chapter 15, Problem 4RE
RECALL What conditions are necessary for the free-energy change to be used to predict the spontaneity of a reaction?
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Chapter 15 Solutions
Biochemistry
Ch. 15 - RECALL Is there a connection between the...Ch. 15 - REFLECT AND APPLY What do the following indicators...Ch. 15 - REFLECT AND APPLY Consider the reaction...Ch. 15 - RECALL What conditions are necessary for the...Ch. 15 - REFLECT AND APPLY Why is it important that energy...Ch. 15 - RECALL Why is it necessary to define a modified...Ch. 15 - RECALL Which of the following statements is (are)...Ch. 15 - RECALL How can you tell if the standard Gibbs free...Ch. 15 - RECALL Can the thermodynamic property G be used to...Ch. 15 - MATHEMATICAL Calculate G for the following values...
Ch. 15 - Prob. 11RECh. 15 - MATHEMATICAL Consider the reaction AB+C, where...Ch. 15 - Prob. 13RECh. 15 - MATHEMATICAL The G for the reaction Citrate ...Ch. 15 - MATHEMATICAL If a reaction can be written AB, and...Ch. 15 - Prob. 16RECh. 15 - Prob. 17RECh. 15 - Prob. 18RECh. 15 - RECALL Organize the following words into two...Ch. 15 - Prob. 20RECh. 15 - REFLECT AND APPLY Would you expect the production...Ch. 15 - Prob. 22RECh. 15 - REFLECT AND APPLY Adult humans synthesize large...Ch. 15 - RECALL Identify the molecules oxidized and reduced...Ch. 15 - RECALL For each of the reactions in Question 24,...Ch. 15 - Prob. 26RECh. 15 - RECALL What is the structural difference between...Ch. 15 - RECALL How does the difference between NADH and...Ch. 15 - RECALL Which coenzyme is a reactant in the...Ch. 15 - Prob. 30RECh. 15 - Prob. 31RECh. 15 - Prob. 32RECh. 15 - REFLECT AND APPLY The following half reactions...Ch. 15 - Prob. 34RECh. 15 - REFLECT AND APPLY There is a reaction in...Ch. 15 - REFLECT AND APPLY There is a reaction in which...Ch. 15 - Prob. 37RECh. 15 - Prob. 38RECh. 15 - Prob. 39RECh. 15 - Prob. 40RECh. 15 - MATHEMATICAL Using the data in Table 15.1,...Ch. 15 - Prob. 42RECh. 15 - Prob. 43RECh. 15 - MATHEMATICAL The standard free-energy change for...Ch. 15 - Prob. 45RECh. 15 - Prob. 46RECh. 15 - Prob. 47RECh. 15 - REFLECT AND APPLY Would you expect an increase or...Ch. 15 - REFLECT AND APPLY Explain and show why...Ch. 15 - Prob. 50RECh. 15 - Prob. 51RECh. 15 - Prob. 52RECh. 15 - Prob. 53RECh. 15 - REFLECT AND APPLY Why are thioesters considered...Ch. 15 - Prob. 55RECh. 15 - REFLECT AND APPLY This is a conjectural question:...
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- REFLECT AND APPLY Would nature rely on the same enzyme to catalyze a reaction either way (forward or backward) if the DG were 0.8kcalmol1? If it were 5.3kcalmol1?arrow_forwardRECALL Show graphically how the reaction velocity depends on the enzyme concentration. Can a reaction be saturated with enzyme?arrow_forwardREFLECT AND APPLY Why is it somewhat misleading to study bio- chemical pathways separately?arrow_forward
- REFLECT AND APPLY You are purifying a protein for the first time. You have solubilized it with homogenization in a blender followed by differential centrifugation. You wish to try ammonium sulfate precipitation as the next step. Knowing nothing beforehand about the amount of ammonium sulfate to add, design an experiment to find the proper concentration (% saturation) of ammonium sulfate to use.arrow_forwardREFLECT AND APPLY Why are proteins more effective catalysts than RNA molecules?arrow_forwardREFLECT AND APPLY Why can we say that having a pure non- competitive inhibitor present is similar to just having less enzyme present?arrow_forward
- REFLECT AND APPLY Suggest a reason why heating a solution containing an enzyme markedly decreases its activity. Why is the decrease of activity frequently much less when the solution contains high concentrations of the substrate?arrow_forwardREFLECT AND APPLY Would you expect an irreversible inhibitor of an enzyme to be bound by covalent or by non-covalent interactions? Why?arrow_forwardREFLECT AND APPLY Why is it better, when running a marathon, to drink a beverage with sugar for energy rather than one with amino acids?arrow_forward
- RECALL Define the term reducing sugar.arrow_forwardREFLECT AND APPLY Give two reasons why enzyme catalysts are 103 to 105 more effective than reactions that are catalyzed by, for example, simple H+orOH.arrow_forwardREFLECT AND APPLLY Show that the reaction Glucose2Glycer-aldehyde-3- phosphate is slightly endergonic (G'52.2kJmol1=0.53kcalmol1); that is, it is not too far from equilibrium. Use the data in Table 17.1.arrow_forward
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