Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 15, Problem 15.76P
Interpretation Introduction
Interpretation: The structure of alternating
Concept introduction: The repeated bonding of monomer units lead to the formation of
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When two monomers (X and Y) are polymerized together, a copolymer results. An alternating copolymer is formed when the two monomers X and Y alternate regularly in the polymer chain. Draw the structure of the alternating copolymer formed when the two monomers, CH2 ≡ CCl2 and CH2 = CHC6H5, are polymerized together.
Give the structure of the addition polymer that forms from the following monomer:
CH2=C(CH3)2
Consider the monomers oxalyl chloride and resorcinol, shown below.
Draw the structure for two repeat units of the polymer that forms from these monomers
Chapter 15 Solutions
Organic Chemistry-Package(Custom)
Ch. 15 - Prob. 15.1PCh. 15 - Prob. 15.2PCh. 15 - Draw the product formed when a chlorine atom (Cl)...Ch. 15 - Prob. 15.4PCh. 15 - Prob. 15.5PCh. 15 - Problem 15.6 Using mechanism 15.1 as guide, write...Ch. 15 - Calculate m0 for the two propagation steps in the...Ch. 15 - Prob. 15.8PCh. 15 - Problem 15.8 Which bond in the each compound is...Ch. 15 - Prob. 15.10P
Ch. 15 - Prob. 15.11PCh. 15 - Synthesize each compound from (CH3)3CH. a....Ch. 15 - Prob. 15.13PCh. 15 - Prob. 15.14PCh. 15 - Prob. 15.15PCh. 15 - Prob. 15.16PCh. 15 - Prob. 15.17PCh. 15 - Prob. 15.18PCh. 15 - Draw all constitutional isomers formed when each...Ch. 15 - Draw the structure of the four allylic halides...Ch. 15 - Which compounds can be prepared in good yield by...Ch. 15 - Which CH bond is most readily cleaved in linolenic...Ch. 15 - Prob. 15.23PCh. 15 - Draw the products formed when each alkene is...Ch. 15 - Problem 15.24 When adds to under radical...Ch. 15 - Prob. 15.26PCh. 15 - Draw an energy diagram for the two propagation...Ch. 15 - Prob. 15.28PCh. 15 - Problem 15.27 Draw the steps of the mechanism that...Ch. 15 - Prob. 15.30PCh. 15 - Prob. 15.31PCh. 15 - Prob. 15.32PCh. 15 - Prob. 15.33PCh. 15 - Why is a benzylic CH bond labeled in red unusually...Ch. 15 - Prob. 15.35PCh. 15 - Prob. 15.36PCh. 15 - Prob. 15.37PCh. 15 - Prob. 15.38PCh. 15 - What alkane is needed to make each alkyl halide by...Ch. 15 - Which alkyl halides can be prepared in good yield...Ch. 15 - Prob. 15.41PCh. 15 - 15.40 Explain why radical bromination of p-xylene...Ch. 15 - a. What product(s) (excluding stereoisomers) are...Ch. 15 - Prob. 15.44PCh. 15 - Prob. 15.45PCh. 15 - Prob. 15.46PCh. 15 - 15.44 Draw all constitutional isomers formed when...Ch. 15 - Draw the organic products formed in each reaction....Ch. 15 - Prob. 15.49PCh. 15 - 15.47 Treatment of a hydrocarbon A (molecular...Ch. 15 - Prob. 15.51PCh. 15 - Prob. 15.52PCh. 15 - Prob. 15.53PCh. 15 - Prob. 15.54PCh. 15 - 15.53 Consider the following bromination: .
a....Ch. 15 - 15.54 Draw a stepwise mechanism for the following...Ch. 15 - Prob. 15.57PCh. 15 - An alternative mechanism for the propagation steps...Ch. 15 - Prob. 15.59PCh. 15 - Prob. 15.60PCh. 15 - Devise a synthesis of each compound from...Ch. 15 - Devise a synthesis of each target compound from...Ch. 15 - Devisea synthesis of each target compound from the...Ch. 15 - Devise a synthesis of each compound using CH3CH3...Ch. 15 - Prob. 15.65PCh. 15 - 15.63 As described in Section 9.16, the...Ch. 15 - 15.64 Ethers are oxidized with to form...Ch. 15 - Prob. 15.68PCh. 15 - Prob. 15.69PCh. 15 - 15.67 In cells, vitamin C exists largely as its...Ch. 15 - What monomer is needed to form each...Ch. 15 - Prob. 15.72PCh. 15 - Prob. 15.73PCh. 15 - 15.71 Draw a stepwise mechanism for the following...Ch. 15 - 15.72 As we will learn in Chapter 30, styrene...Ch. 15 - Prob. 15.76PCh. 15 - 15.74 A and B, isomers of molecular formula , are...Ch. 15 - Prob. 15.78PCh. 15 - Radical chlorination of CH3CH3 forms two minor...Ch. 15 - 15.76 Draw a stepwise mechanism for the...Ch. 15 - Prob. 15.81PCh. 15 - Prob. 15.82PCh. 15 - Prob. 15.83P
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- Define polymer and copolymer. Describe alternating copolymer, block copolymer, alternating copolymer, and branched copolymer.arrow_forwardIn the addition polymer, Polyethylene, how many monomer units are in the polyethylene polymer that has a molar mass of 2.8 x 10 g/mol? O 1 monomer unit O 100 monomer units O 1000 monomer units O 10 monomer unitsarrow_forwardGlue guns used in craft projects contain a heating element that melts an adhesive that is a copolymer formed from ethylene and vinyl acetate (CH2=CHOCOCH3). Draw a possible structure of this copolymer, assuming that the copolymer is random and that there are two times as many ethylene monomers as vinyl acetate monomers.arrow_forward
- need help for question number 2arrow_forwardStep-growth, or condensation, polymers are formed from monomers that have more than one functional group. Consider the monomers oxalyl chloride and resorcinol, shown below. Draw the structure for two repeat units of the polymer that forms from these monomersarrow_forwardPolymer: Polystyrene Indicate whether the polymer is a natural polymer or synthetic polymer. Indicate whether the polymer is produced by condensation or addition polymerization. Give the structure of the monomer used to produce the polymer. Discuss how the polymer is produced, its chemical and physical properties, factors that effecting its properties and their major applicationarrow_forward
- The structure shown is an example of a type of macromolecule (carbohydrate, lipid, protein, or nucleic acid) that is an important biological polymer. Identify the type of macromolecule shown, the type of monomer it is made from, how you came to your conclusion and the general types of important biological functions of this type of macromolecule in the cell. 0=210 + OCH₂ NH₂ OH OHarrow_forwardThe molecular formula of n-decane is CH3(CH2)8CH3. Decaneis not considered a polymer, whereas polyethylene is.What is the distinction?arrow_forwardWhich statement is true about addition polymerization but not condensation polymerization? 1.) only one type of monomer is used 2.) many monomers link together to form polymers3.) only one product is formedarrow_forward
- Choose the best definition for the the term monomer. - a large molecule made of repeating subunits - a repeating subunit used to make a polymer - a single‑chain polymer - a molecule with a very high molecular weight Choose the best definition for the term polymer. - a large molecule made of many different elements - a large molecule made of repeating subunits - a molecule with a very high molecular weight - a repeating subunit used to make a monomerarrow_forwardwhich type of polymer is bakelite?arrow_forward
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